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991.
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993.
    
In this study, the effects of four different direct-vat-set (DVS) commercial starter cultures (CHN11, CHN22, EZAL BT001 and MM100) and storage temperatures (4  ±  1 and −18  ±  2°C) on the oxidative stability and diacetyl production in butter during a 4-month period were investigated. Samples were taken from butter on days 3, 30, 60, 90 and 120. Analyses of titration acidity, peroxide value, free fatty acids and diacetyl contents of the samples taken were carried out. The effects of the starter cultures on the peroxide value and diacetyl contents were found to be significant ( P  < 0.01) while the storage temperatures significantly affected all parameters tested. Interaction between the type of culture and storage temperature was significant for free fatty acids ( P  < 0.05) and diacetyl content ( P  < 0.01).  相似文献   
994.
    
This paper reports for the first time the inhibition of the catecholase activities of mushroom, artichoke (Cynara scolymus L) and Ocimum basilicum L polyphenol oxidase by 2,3‐diaminopropionic acid. Polyphenol oxidases from artichoke and O basilicum L were purified by ammonium sulfate precipitation, dialysis and a Sepharose 4B‐L ‐tyrosine‐p‐aminobenzoic acid‐affinity column. In inhibition studies, 2,3‐diaminopropionic acid showed uncompetitive inhibition for mushroom PPO using catechol and pyrogallol as substrates, competitive inhibition for O basilicum L PPO using catechol as a substrate, and uncompetitive inhibition for artichoke PPO using catechol as a substrate. Furthermore, sodium azide, which is an inhibitor of PPO, was used as an inhibitor for comparison with the inhibition potency of 2,3‐diaminopropionic acid. The highest 2,3‐diaminopropionic acid inhibition observed with O basilicum L (Ki = 0.89 mM ), followed by artichoke (Ki = 1.42 mM ) and mushroom (Ki = 2.47 mM ), respectively. Copyright © 2005 Society of Chemical Industry  相似文献   
995.
    
The synthesis, characterization, and functionalization of polydiacetylene (PDA) networks on solid substrates is presented. A highly transparent and cross‐linked diacetylene film of DCDDA‐bis‐BA on a solid substrate is prepared first by tailoring the monomers with organoboronic acid moieties as pendant side groups and consequent drop‐casting and dehydration steps. Precisely controlled thermal curing plays a key role to obtain properly aligned diacetylene monomers that are closely packed between the boronic acid derived anhydride structures. A second cross‐linking, which occurs by polymerization of the diacetylene monomers with UV irradiation, induces a transparent to blue color shift. Accordingly, colored image patterns are readily available by polymerization through a photomask. The color change that takes place as a response to various organic solvents can be simply detected by naked eyes. The thermofluorescence change of PDA networks is demonstrated to be an effective method by which to obtain the microscale temperature distribution of thermal systems. The ease of film formation and stress‐induced blue‐to‐red color change with a simultaneous fluorescence generation features of the network structure should find a great utility in a wide range of chemical and thermal sensing platforms.  相似文献   
996.
    
Recent efforts have established that thermoplastic elastomer gels (TPEGs) composed of styrenic triblock copolymers swollen with a midblock‐selective solvent exhibit remarkable electromechanical properties as high‐performance dielectric elastomers. This class of electroactive polymers typically requires high electric fields for actuation, and a shortcoming that continues to thwart the widespread commercialization of such materials in general is the need to apply mechanical prestrain prior to electroactuation to decrease film thickness and, thus, the electric potential required to promote actuation. To alleviate this requirement, TPEGs consisting of acrylic triblock copolymers differing in molecular weight and composition, and swollen with a high dielectric, midblock‐selective solvent are investigated. Synchrotron small‐angle x‐ray scattering is used to probe the nanoscale morphologies of the resultant materials, and analysis of quasi‐static and cyclic tensile properties provides additional insight into both blend morphologies and electroactuation efficacy. Actuation strains measured in the absence of mechanical prestrain exceed 100% on an area basis, and electric fields capable of inducing actuation are as low as ~20 kV/mm. Failure occurs by either electromechanical instability or dielectric breakdown, depending on the copolymer and TPEG composition employed. The electromechanical properties of these acrylic‐based TPEGs match or exceed those of skeletal muscle, in which case they constitute an attractive and unexplored alternative to existing dielectric elastomers.  相似文献   
997.
998.
    
Platinum(II) acetylides were incorporated into poly(methyl methacrylate) (PMMA) glasses to obtain solid‐state nonlinear optical devices. We report on device fabrication, structural, chemical, and mechanical properties, as well as the optical limiting capabilities of the final solids. Two different guest‐host systems are presented: 1) Dye molecules functionalized to be readily dispersed in methyl methacrylate (MMA) and subsequent in situ polymerization of the MMA yielding solid PMMA host matrices. 2) Dye molecules functionalized to copolymerize with MMA forming covalent bonds between the guest and the PMMA host matrix. A range of doped organic solids were prepared, reaching concentrations up to 13 wt% of the guest molecule. Raman spectra of the doped solid devices indicate that the chemical structure of the nonlinear dyes remains intact upon the polymerization of the solid matrix. Luminescence spectra confirm that the basic photophysical properties observed for the same solute molecules in THF are maintained also in the solid state. Optical power limiting (OPL) characterization reveal clamping levels for the dyes nonbonded to the solid host being less than 4 µJ at pulse energies up to 110 µJ at 532 nm (f/5 arrangement and 5 ns pulses), which is comparable to the performance of similar dyes in THF solutions. In contrast, the highly crosslinked solid possesses a higher clamping level (8 µJ) at the same nominal concentration.  相似文献   
999.
Relay deployments promise to alleviate the limitations of conventional macrocell networks, such as poor indoor penetration and coverage holes in a cost-efficient way. In this context, the capacity of the wireless relay link between a relay node (RN) and its serving base station has a crucial impact on the end-to-end performance. The deployment flexibility of RNs, which mainly stems from the wireless relay link, compact physical characteristics, and low-power consumption, can be exploited by relay site planning (RSP) to overcome the limitations of the relay link and, thus, enhance the system performance. To this end, RSP is carried out via selecting an RN deployment location from a discrete set of alternatives considering the signal-to-interference-plus-noise ratio (SINR) on the relay link as the selection criterion. In practice, the so-called coarse RSP takes into account only large-scale fading due to shadowing. Nevertheless, as RNs are stationary, the wireless channels pertaining to relay deployments are subject to simultaneous impairments by both shadowing and multi-path fading, i.e., composite fading/shadowing. In this paper, we present the performance of coarse RSP that can be used for planning and dimensioning of two-hop cellular relay networks in composite fading/shadowing environments, where co-channel interference is also present. The relay link is modeled by Nakagami-lognormal distribution while the access link between a mobile terminal and its serving RN is modeled by Rician-lognormal distribution. Further, we provide an accurate analytical framework through closed-form expressions for relay link SINR, link rates, and end-to-end rate. Results show that coarse RSP can still yield high performance improvements in terms of both SINR and rate considering composite fading/shadowing channels. Moreover, coarse RSP is shown to effectively decrease the amount of fading on the relay link and, thus, mitigate the detrimental effects of composite fading/shadowing.  相似文献   
1000.
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