Hierarchical steganography using novel optimum quantization technique

Security and imperceptibility are fundamental issues for steganography. This paper presents a multi-level steganography system based on concealing and deception. Basically, the secret image is embedded in a cover image, which in turn is embedded in another higher-level cover image. Each steganography level provides additional security, with lower levels implemented using stronger steganography methods. Furthermore, in the event that the higher level steganography is compromised, it would include misleading information to deceive the attacker that he/she is successfully eavesdropping. One challenge of hierarchical system is retaining hidden data in lower level in a higher level stenographic technique. To mitigate this issue, we designed a novel technique which combines discrete cosine transform and least significant bit (LSB). The technique objective is to maximize the capacity and invisibility of the secret image with minimal modification to the cover image (at most k-bits per block). The performance (capacity and peak signal-to-noise ratio) of the proposed method has superior performance compared with LSB since it combines the benefits of 1-bit and 3-bit LSBs. Furthermore, the paper demonstrates that the secret message is successfully embedded and extracted in two-level steganography system with peak signal-to-nose ratio greater than 20 dB.     

Preparation and characterization of conductive polypyrrole/kaolinite composites

Conductive polypyrrole (PPy)/kaolinite clay composites were prepared by in situ chemical polymerization of pyrrole in the presence of kaolinite using FeCl₃ as oxidant. The PPy content and conductivity of the composites reached 32.8% and 8.3×10^?2 S/cm at HCl concentrations of 1.5 M and 0.5 M, respectively. The microhardness of the composites containing different amounts of PPy was higher than that of the PPy and kaolinite components. The highest microhardness observed was 30.17 kg/mm² for the composite containing 9.6% PPy. The electrical resistance of the composites was monitored during heating–cooling cycles over the range 5–120 °C. The change in resistance with temperature was more repeatable for the composite than for PPy. The composites were characterized by Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetric analysis (TGA) and scanning electron microscopy (SEM). The humidity-sensing properties were also examined.     

Effects of carbonate on the electrolytic removal of ammonia and urea from urine with thermally prepared IrO<Subscript>2</Subscript> electrodes

Recent studies have shown that electrolysis can be an efficient process for nitrogen removal from urine. These studies have been conducted with urea solutions or fresh urine, but urine collected in NoMix toilets and urinals has a substantially different composition, because bacteria hydrolyse urea quickly to ammonia and carbonate. In this study, we compared electrochemical removal of nitrogen from synthetic solutions of fresh and stored urine using IrO₂ anodes. We could show that in fresh urine both ammonia and urea are efficiently eliminated, mainly through chlorine-mediated oxidation. However, in stored urine the presence of carbonate, arising from urea hydrolysis, leads to an inhibition of ammonia oxidation. We suggest two parallel mechanisms to explain this effect: the competition between chloride and carbonate oxidation at the anode and the competition between chlorate formation, enhanced by the buffering effect of carbonate, and ammonia oxidation for the consumption of active chlorine in the bulk. However, further experiments are needed to support the latter mechanism. In conclusion, this study highlights the negative consequences of the presence of carbonate in urine solutions, but also in other wastewaters, when subjected to an electrolytic treatment on IrO₂ in alkaline media.     

Effect of muscle,ageing time and modified atmosphere packaging conditions on the colour,oxidative and microbiological stability of packed beef

The objective of this study was to evaluate the influence of two different vacuum ageing times (7 and 14 days) and the impact of the modified atmosphere packaging (MAP) configuration (gas/product ratios: 0.5 and 1 and gas composition: 70% O₂ + 30% CO₂ and 40% O₂ + 30% CO₂ + 30% N₂) on the quality of fresh beef during subsequent storage at 4 °C. For this purpose, three separate experiments were performed. For each experiment, two different muscles (Longissimus dorsi and Biceps femoris) were sampled from four double‐muscled Belgian Blue beef carcasses. Next to colour, also the evolution in microbial load, pH, O₂ and CO₂ in the headspace and lipid oxidation at the meat surface were evaluated. A vacuum ageing for 14 days compared with 7 days resulted in a higher initial microbial load on the day of MAP packaging, which resulted finally in a significantly shorter shelf life. This ageing effect was less pronounced on the colour stability and lipid oxidation of the meat samples. No significant influence of the packaging configuration on any of the analysed parameters (colour, microbial load, pH and lipid oxidation at the meat surface) was observed.     

Hydroxyl Functionalized Methacrylic Terpolymers as Supports for Mn(III) Salen Catalysts and Their Application in Asymmetric Epoxidation

Hydroxyl functionalized gel type resins derived from 2-hydroxyethyl, 2-hydroxypropyl and 2-hydroxy-3-phenoxypropyl methacrylates were applied to covalent immobilization of Mn(salen) complexes via glutarate and carbonate linkers. The obtained catalysts were characterized by FTIR and DR UV–Vis methods and elemental analysis. It was found that the activity of polymeric catalysts obtained in this way depended on both the nature of the functional and cross-linking monomers and the degree of the cross-linking of polymer matrices and the way of complex immobilization. The highest activity was observed for the complexes immobilized on the HEMA resins cross-linked with 3%-mol of diethylene glycol dimethacrylate. For instance, in the presence of the catalysts with (S,S)-salen ligand S-epoxystyrene and (1S, 2R)-epoxyindene could be obtained with 46% and 69% ee, respectively. Attempts have also been made to recycle the selected catalyst. However, a rapid fall off in the activity was observed, although the selectivity was similar in which three cycles.     

Harvesting of river flow energy for wireless sensor network technology

River courses play a vital role in preserving unpolluted ecosystems. On the other hand, networks of sensor nodes can be used to measure characteristic parameters in the environment such as temperature, pressure, humidity or the concentration of pollutants. In the framework of the EU FP7 project “GOLDFISH”, technical competences of a consortium of 11 institutions are hence employed in designing, manufacturing, validating and operating wireless sensors nodes for tracking pollution in remote rivers. The sensor network is composed of sensor clusters located underwater and gateways on the riverbank with long-distance communication links to the central management and monitoring station. Each sensor node is composed of active electronic devices that have to be constantly powered. Batteries can generally be used for this purpose, but problems may occur when they are to be recharged or replaced, especially in the case of large networks placed in scarcely accessible locations. State-of-the-art energy harvesting technologies can hence constitute a viable powering solution. The possibility to use different small-scale river flow energy harvesting principles is thoroughly studied in this work by the University of Rijeka GOLDFISH team: a miniaturized hydro-generator, a ‘piezoelectric eel’ and a hybrid solution of a rotating shaft plucking a piezoelectric beam. The first two concepts are validated experimentally in a flow channel and in real river conditions. The miniaturized hydro-generator with suitable power management electronics is finally embedded into the wireless sensor node deployed into the river, allowing the GSM transmission of collected data to be successfully performed.     

A comprehensive meta-analysis on evidence of Mediterranean diet and cardiovascular disease: Are individual components equal?

Many studies have reported that higher adherence to Mediterranean diet may decrease cardiovascular disease (CVD) incidence and mortality. We performed a meta-analysis to explore the association in prospective studies and randomized control trials (RCTs) between Mediterranean diet adherence and CVD incidence and mortality. The PubMed database was searched up to June 2014. A total of 17 studies were extracted and 11 qualified for the quantitative analysis. Individuals in the highest quantile of adherence to the diet had lower incidence [relative risk (RR): 0.76, 95% confidence intervals (CI): 0.68, 0.83] and mortality (RR: 0.76, 95% CI: 0.68, 0.83) from CVD compared to those least adherent. A significant reduction of risk was found also for coronary heart disease (CHD) (RR: 0.72, 95% CI: 0.60, 0.86), myocardial infarction (MI) (RR: 0.67; 95% CI: 0.54, 0.83), and stroke (RR: 0.76; 95% CI: 0.60, 0.96) incidence. Pooled analyses of individual components of the diet revealed that the protective effects of the diet appear to be most attributable to olive oil, fruits, vegetables, and legumes. An average reduced risk of 40% for the aforementioned outcomes has been retrieved when pooling results of RCTs. A Mediterranean dietary pattern is associated with lower risks of CVD incidence and mortality, including CHD and MI. The relative effects of specific food groups should be further investigated.     

Ultrastructural and developmental toxicity of potato and tomato leaf extracts to beet armyworm,Spodoptera exigua (lepidoptera: noctuidae)

Beet Armyworm, Spodoptera exigua is a herbivorous moth and a serious pest of many economically important plants, which are used as food sources. Because of rigorous standards of food quality, usage of synthetic insecticides in crop protection, against pests, is limited. Solanaceae plant extracts may be a relatively cheap source of efficient natural insecticides that can limit usage of synthetic substances. Their biological activity is not fully known. In particular, ultrastructural studies, using transmission electron microscopy, are not usual. In the present article we describe the effects of sublethal concentrations of tomato and potato leaf extracts against S. exigua. Acute lethal effects were not observed. Both extracts exerted similar effects within midgut and fat body cells. Midgut cells were not significantly altered while fat body cells showed prominent swelling of nuclear envelope and endoplasmic reticulum, vacuolization of mitochondria and fusion of fat droplets. These changes were much more intensive within groups exposed to potato than tomato extracts at highest concentration at least. Light microscopy was used to observe and document developmental alterations of S. exigua exposed to potato and tomato leaf extracts. Potato leaf extracts significantly decreased hatching success and caused morphological malformations of imagoes. Among them, malformations of wings were the most prominent. Interestingly, these effects were not observed within populations exposed to tomato extracts at highest concentration at least.