Surface Modification of Ready-to-Use Hollow Fiber Ultrafiltration Modules for Oil/Water Separation

Reusing wastewater from oil-related industries is becoming increasingly important, especially in water-stressed oil-producing countries. Before oily wastewater can be discharged or reused, it must be properly treated, e.g., by membrane-based processes like ultrafiltration. A major issue of the applied membranes is their high fouling propensity. This paper reports on mitigating fouling inside ready-to-use ultrafiltration hollow-fiber modules used in a polishing step in oil/water separation. For this purpose, in-situ polyzwitterionic hydrogel coating was applied. The membrane performance was tested with oil nano-emulsions using a mini-plant system. The main factors influencing fouling were systematically investigated using statistical design of experiments.     

Synthesis and characterization of photopolymerizable hydrogels based on poly (ethylene glycol) for biomedical applications

Hydrogels are polymeric materials widely used in medicine due to their similarity with the biological components of the body. Hydrogels are biocompatible materials that have the potential to promote cell proliferation and tissue support because of their hydrophilic nature, porous structure, and elastic mechanical properties. In this work, we demonstrate the microwave-assisted synthesis of three molecular weight varieties of poly(ethylene glycol) dimethacrylate (PEGDMA) with different mechanical and thermal properties and the rapid photo of them using 1-hydroxy-cyclohexyl-phenyl-ketone (Irgacure 184) as UV photoinitiator. The effects of the poly(ethylene glycol) molecular weight and degree of acrylation on swelling, mechanical, and rheological properties of hydrogels were investigated. The biodegradability of the PEGDMA hydrogels, as well as the ability to grow and proliferate cells, was examined for its viability as a scaffold in tissue engineering. Altogether, the biomaterial hydrogel properties open the way for applications in the field of regenerative medicine for functional scaffolds and tissues.     

Effect of pH and zeta potential of Pickering stabilizing magnetite nanoparticles on the features of magnetized polystyrene microspheres

Styrene as a monomer was emulsified in water using several magnetite nanoparticles concentration and pH values. Emulsified styrene drops were used as templates for polymerization, in presence of water soluble free radical initiator, and formation of composite particles. Styrene template drops stabilization was verified by light as well as scanning electron microscopy imaging, which ensured the participation of the particles in building up a mechanical barrier to stop oil drops coalescence. Furthermore, the produced polystyrene composites were strongly attracted to an external magnet. The difference in particles size as a function of pH was elucidated using zeta potential measurements, which indicated dominance of pH on the hydrophilicity of the particles and consequently the extent of emulsification, which in turn affected the size of the obtained microspheres. Under some circumstances, capsules were formed instead of particles. Thereby, it can be concluded that the magnetic microspheres are optimally formed at pH 2.3 independently of the magnetite content used.     

Open-cell polyvinylidene fluoride foams as carriers to promote biofilm growth for biological wastewater treatment

This article reports the design and fabrication of open-cell polyvinylidene fluoride (PVDF) foams as carriers that can promote biofilm growth and organic removal efficiency for biological wastewater treatment in attached growth bioreactors. Open-cell PVDF foams were fabricated by a manufacturing approach that integrated compression molding and particulate leaching. PVDF carriers were structured with two governing factors of leaching agent types (e.g., sodium chloride [NaCl] and sodium acetate [NaOAc]) and contents (e.g., 80 and 90 wt%). Open-cell PVDF foams possessed high porosity and high protected surface area (i.e., more than ×10 to ×20 of the areas of commercialized carriers), which promoted biofilm growth in these carriers. As a successful advantage, PVDF carriers used in the moving bed biofilm reactors (MBBR) were entirely covered by biofilm in both interior and exterior parts without clogging. This provides strong evidence of the bacterial compatibility of the fabricated open-cell PVDF foam carriers. Moreover, the specific morphology of the PVDF carriers in this article provided superior biofilm protection from the detachment in MBBR. Experimental results revealed that PVDF open-cell foams fabricated by 80 wt% of NaCl demonstrated higher mechanical strength with an organic removal efficiency of 77% ± 7% in the corresponding bioreactor containing them.     

A study of diamond synthesis by hot filament chemical vapor deposition on Nc coatings

Deposition of diamond films onto various substrates can result in significant technological advantages in terms of functionality and improved life and performance of components. Diamond is hard, wear resistant, chemically inert, and biocompatible. It is considered to be the ideal material for surfaces of cutting tools and biomedical components. However, it is well known that diamond deposition onto technologically important substrates, such as co-cemented carbides and steels, is problematic due to carbon interaction with the substrate, low nucleation densities, and poor adhesion. Several papers previously published in the relevant literature have reported the application of interlayer materials such as metal nitrides and carbides to provide bonding between diamond and hostile substrates. In this study, the chemical vapor deposition (CVD) of polycrystalline diamond on TiN/SiN _x nc (nc) interlayers deposited at relatively low temperatures has been investigated for the first time. The nc layers were deposited at 70 or 400 °C on Si substrates using a dual ion beam deposition system. The results showed that a preliminary seeding pretreatment with diamond suspension was necessary to achieve large diamond nucleation densities and that diamond nucleation was larger on nc films than on bare sc-Si subjected to the same pretreatment and CVD process parameters. TiN/SiN _x layers synthesized at 70 or 400 °C underwent different nanostructure modifications during diamond CVD. The data also showed that TiN/SiN _x films obtained at 400 °C are preferable in so far as their use as interlayers between hostile substrates and CVD diamond is concerned. This paper was presented at the fourth International Surface Engineering Congress and Exposition held August 1–3, 2005 in St. Paul, MN.     

Influence of nickel and molybdenum on the phase stability and mechanical properties of maraging steels

The effect of nickel and molybdenum concentrations on the phase transformation and mechanical properties of conventional 18Ni(350) maraging steel has been investigated. Both of these elements act as strong austenite stabilizers. When the concentration of molybdenum or nickel is greater than 7.5 or 24 wt %, respectively, the austenite phase remains stable up to room temperature. In both molybdenum- and nickel-alloyed steels, the austenite phase could be transformed to martensite by either dipping the material in liquid nitrogen or subjecting it to cold working. When 7.5 wt% Mo and 24 wt% Ni were added in combination, however, the austenite phase obtained at room temperature did not transform to martensite when liquid-nitrogen quenched or even when cold rolled to greater than 95% reduction. The aging response of these materials has also been investigated using optical, scanning electron, and scanning transmission electron microscopy.     

Studying the needed effort for identifying duplicate issues

Many recent software engineering papers have examined duplicate issue reports. Thus far, duplicate reports have been considered a hindrance to developers and a drain on their resources. As a result, prior research in this area focuses on proposing automated approaches to accurately identify duplicate reports. However, there exists no studies that attempt to quantify the actual effort that is spent on identifying duplicate issue reports. In this paper, we empirically examine the effort that is needed for manually identifying duplicate reports in four open source projects, i.e., Firefox, SeaMonkey, Bugzilla and Eclipse-Platform. Our results show that: (i) More than 50 % of the duplicate reports are identified within half a day. Most of the duplicate reports are identified without any discussion and with the involvement of very few people; (ii) A classification model built using a set of factors that are extracted from duplicate issue reports classifies duplicates according to the effort that is needed to identify them with a precision of 0.60 to 0.77, a recall of 0.23 to 0.96, and an ROC area of 0.68 to 0.80; and (iii) Factors that capture the developer awareness of the duplicate issue’s peers (i.e., other duplicates of that issue) and textual similarity of a new report to prior reports are the most influential factors in our models. Our findings highlight the need for effort-aware evaluation of approaches that identify duplicate issue reports, since the identification of a considerable amount of duplicate reports (over 50 %) appear to be a relatively trivial task for developers. To better assist developers, research on identifying duplicate issue reports should put greater emphasis on assisting developers in identifying effort-consuming duplicate issues.     

An empirical study of integration activities in distributions of open source software

Reuse of software components, either closed or open source, is considered to be one of the most important best practices in software engineering, since it reduces development cost and improves software quality. However, since reused components are (by definition) generic, they need to be customized and integrated into a specific system before they can be useful. Since this integration is system-specific, the integration effort is non-negligible and increases maintenance costs, especially if more than one component needs to be integrated. This paper performs an empirical study of multi-component integration in the context of three successful open source distributions (Debian, Ubuntu and FreeBSD). Such distributions integrate thousands of open source components with an operating system kernel to deliver a coherent software product to millions of users worldwide. We empirically identified seven major integration activities performed by the maintainers of these distributions, documented how these activities are being performed by the maintainers, then evaluated and refined the identified activities with input from six maintainers of the three studied distributions. The documented activities provide a common vocabulary for component integration in open source distributions and outline a roadmap for future research on software integration.     

Voice assessments for detecting patients with Parkinson’s diseases using PCA and NPCA

In this study, we wanted to discriminate between two groups of people. The database used in this study contains 20 patients with Parkinson’s disease and 20 healthy people. Three types of sustained vowels (/a/, /o/ and /u/) were recorded from each participant and then the analyses were done on these voice samples. Firstly, an initial feature vector extracted from time, frequency and cepstral domains. Then we used linear and nonlinear feature extraction techniques, principal component analysis (PCA), and nonlinear PCA. These techniques reduce the number of parameters and choose the most effective acoustic features used for classification. Support vector machine with its different kernel was used for classification. We obtained an accuracy up to 87.50 % for discrimination between PD patients and healthy people.