The accumulation of La,Ce and Y by Lemna minor and Lemna gibba in the Keban gallery water,Elazig Turkey

This study investigated the phytoremediation ability of Lemna minor and Lemna gibba to accumulate lanthanum, cerium and yttrium from gallery water polluted by metals. L. minor and L. gibba were settled in the mining water and adapted to separate reactors. During the experiment, the water and plant samples were daily taken and the temperature, electric conductivity and pH of the water were daily measured in situ. These plants were firstly washed, dried in and then ashed at 300°C for 24 h in an oven. Both water and ashed plant samples were measured by ICP‐MS to detect the concentrations of lanthanum (La), cerium (Ce) and yttrium (Y). Although these elements are at low concentrations in gallery water, they were accumulated at the highest levels in L. gibba and in L. minor. This study showed that both plants have high ability to remove lanthanum, cerium and yttrium in gallery water polluted by different elements.     

Friction and wear behavior of styrene butadiene rubber‐based composites reinforced with microwave‐devulcanized ground tire rubber

In this work, the tribological properties of a new material obtained by revulcanization with styrene butadiene rubber (SBR) and devulcanized ground tire rubber (GTR) were investigated. GTR was devulcanized using the microwave method at a constant power while varying the microwave exposure time. Devulcanized rubber (DV‐R) and untreated GTR were revulcanized by mixing with SBR at different rates (10, 30, 50 phr). To determine friction and wear characteristics of the samples, pin (ball) on disc and abrasion tests were conducted. Scanning electron microscopy (SEM) was employed to observe the worn surfaces of the composites to correlate the experimental test results to the wear mechanisms. All of these tests and experiments were performed on original vulcanized rubber samples for comparison. The composites exhibited different friction and wear behavior due to morphology, dispersion behavior and devulcanization functionalization of ground tire rubber. In general, DV‐R/SBR composites exhibited improvement in both mechanical and tribological properties. However, the enhanced compatibility of DV‐R resulting from the specific chemical coupling of DV‐R with SBR was crucial for the mechanical, friction and wear properties. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42419.     

Fundamental periods of steel eccentrically braced frames

This paper describes formulation of a hand method that can be used to estimate the computed fundamental periods of vibration of building structures in general and steel eccentrically braced frames (EBFs) in particular. The developed method uses the Rayleigh's method as a basis and utilizes the roof drift ratio (RD_R) under seismic forces as a parameter. To obtain RD_R, more than 4000 EBFs were designed by considering the seismic hazard, number of stories, braced bay width and link length to bay width ratio as prime variables. A model was developed to estimate RD_R, which depends on the rigid plastic deformation mechanism for a typical EBF. The method was verified using design data produced as a part of this work as well as data published in literature. The verifications indicate that the proposed formulation is capable of providing acceptable estimates of the computed period. When compared with existing empirical period–height relationships, the proposed formulation offers closer estimates with reduced scatter. The method was further refined to derive new period–height relationships for two different seismicity regions. The accuracy of the relationship for high seismic regions was verified using measured periods of EBF buildings. Copyright © 2014 John Wiley & Sons, Ltd.     

Performance of joint multilevel/AES‐LDPCC‐CPFSK schemes over wireless sensor networks

In wireless sensor networks, data encryption and channel coding are considered together for ensuring secure and robust communication. In order to achieve this purpose, we introduce a new joint scheme, namely ‘Multilevel/Advanced Encryption Standard‐Low Density Parity Check Coded‐Continuous Phase Frequency Shift Keying (ML/AES‐LDPCC‐CPFSK)’. AES algorithm is the most powerful and widely used symmetric key cryptography in providing secure data transmission. LDPC codes have very large Euclidean distance and use iterative decoding algorithms. In this study, we have increased error performance employing multilevel structure to AES and LDPC. In all communications systems, phase discontinuities of modulated signals result in extra bandwidth requirements. CPFSK, which is a special type of continuous phase modulation, is a powerful solution for this problem. In this paper, we simulate error performance of ML/AES‐LDPCC‐CPFSK for regular LDPC codes. Simulation results are drawn for 4CPFSK, 8CPFSK and 16CPFSK over wireless cooperative sensor networks. Using this scheme, we are able to improve bit error performance, channel throughput, security level of communication and reduction in complexity compared with related schemes such as various turbo code structures. Copyright © 2009 John Wiley & Sons, Ltd.     

Antibacterial oil‐based polyurethane films for wound dressing applications

As an alternative to petroleum‐based polyol, hydroxyl containing material was prepared from linseed oil for polyurethane synthesis. Hexamethylene di‐isocyanate (HMDI) and/or 4, 4′‐methylene diphenyl di‐isocyanate (MDI) were used as isocyanate source. The polymerization reaction was carried out without catalyst. Polymer films were prepared by casting‐evaporation technique. The MDI/HMDI‐based polyurethane and its films had higher T_g and better thermal property than that of the HMDI‐based one because of the existence of benzene ring in the polymer chain. Static water contact angle was determined to be 74° and 77.5° for HMDI and MDI/HMDI‐based films, respectively. Water adsorption was found to be around 2.6–3.6% for both films. In vitro degradation of polyurethanes in phosphate buffered saline at 37°C was investigated by gravimetric method. Fourier transform infrared spectroscopy and scanning electron microscopy were used for confirmation of degradation on the polymer surface. The degradation rate of the HMDI‐based polyurethane film was found higher than that of the MDI/HMDI‐based film. Both the direct contact method and the MMT test were applied for determination of cytotoxicity of polymer films, and the polyurethane films investigated here was not cytotoxic. Silver‐containing films were prepared using Biocera A® as filler and were screened for their antibacterial performance against Escherichia coli, Pseudomonas aeruginosa, Staphylococcus aureus, and/or Bacillus subtilis. The films prepared with and without Biocera A® exhibited antibacterial activity. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Determination of dielectric properties of corn seeds from 1 to 100 MHz

The dielectric properties of corn seeds were determined in the ranges of 9.71-21.51% wet basis (w.b.) for moisture content, 772.5-902.2 kg/m³ for bulk density and 1-100 MHz for frequency of applied electric field using a coaxial capacitor sample holder. Effects of the parameters such as moisture content, bulk density and frequency on the dielectric properties were investigated. The dielectric constant, loss factor and loss tangent were greatly affected by the moisture content, frequency and bulk density. The moisture content was the most significant factor affecting the dielectric properties of corn seeds. The dielectric constant, loss factor and loss tangent increased with increasing moisture content and bulk density. The second and third-order polynomial equations were proposed to describe the existing relationship between dielectric properties and moisture content. Dielectric measurements provided new information concerning moisture content and bulk density dependent behaviour of dielectric properties of corn seeds that may be useful in sensing of the moisture content.     

SrO capping effect for La2O3/Ce-silicate gate dielectrics

The chemical bonding states and electrical characteristics of SrO capped La₂O₃/CeO_x gate dielectric have been examined. Angle-resolved X-ray photoelectron spectroscopy measurement has revealed that Sr atoms diffuse into silicate layer to form SrLa-silicate after annealing. Owing to the incorporation of Sr atoms into silicate layer, a transistor operation with an equivalent oxide thickness (EOT) below 0.5 nm has been demonstrated. A strongly degraded effective electron mobility of 78 cm²/V s at 1 MV/cm has been obtained, which fit well with the general trend in small EOT range below 1 nm. Although process optimization is needed to improve the performance of transistors, Sr capping technique can be useful for EOT scaling.     

Antioxidant activity and polyphenol content of Turkish thyme (Thymus vulgaris) monitored by liquid chromatography and tandem mass spectrometry

Like tea, the leaves of Turkish thyme (Thymus vulgaris) can be boiled in water to produce an extract. This is widely used as syrup for the treatment of coughs and bronchitis at alternative medicine clinics in many parts of the world. In the current study, we assessed the phenolic content and antioxidant activity of thyme. The antioxidant activities of both ethanol and aqueous extracts of thyme were determined using various in vitro methods. The total phenolic and total flavonoid contents were determined to be a gallic acid equivalent and a quercetin equivalent, respectively. Finally, the quantities of the phenolic compounds were detected using high-performance liquid chromatography and tandem mass spectrometry. The total phenolic compounds in the aqueous extract and ethanol extracts of Turkish thyme were 256.0 μg gallic acid equivalent/mg dried extract and 158.0 μg gallic acid equivalent/mg dried extract, respectively. Conversely, the total flavonoid compounds in both extracts were 44.2 μg and 36.6 μg quercetin equivalent/mg dried extract, respectively. For the first time, we determined phenolic contents and investigated the antioxidant potential of thyme. The results indicate that Turkish thyme is a good dietary source with phenolic properties.