Determination of color changes of inks on the uncoated paper with the offset printing during drying using artificial neural networks

This study attempts to determinate color changes based on time in inks applied on the surface of wood-free uncoated paper with offset printing during drying. This study consists of two main cases: (1) Experimental analysis: By preparing a test page according to the 12647-2 principle with an offset printing system, test prints were applied to 120 g/m² wood-free uncoated paper using an ECI 2002 CMYK test chart. Each press was measured being subject to process every 15 min in the first 2 h, then hour by hour between 2 and 12 h, then 4–4 h between 12 and 24 h, and then 6–6 h between 24 and 48 h. CIELAB and reflectance values between 380 and 720 nm of the target, 1,485 colors of the test chart were obtained. To see the drying and color changes of the ink on paper, changes were determined by printing on the paper and applying artificial neural network (ANN) to spectrophotometer data at the stated time intervals. (2) Empirical analysis: The use of the ANN has been proposed as numerical approach to get of empirical equations of color changes in inks applied on the surface of wood-free uncoated paper with offset printing during drying. Based on the outputs of the study, ANN model can be used to estimate the effects of digital proofing systems used in color management on print quality with high confidence with the use of the acquired equations without experimental study. In the study, as colors are defined in terms of wave length, in case, all wave lengths are taken into consideration, certain wave length changes have been taken into consideration.     

Reusable water oxidation catalyst with dual active center for enhanced water oxidation: Iridium oxide nanoparticles immobilized on monodisperse-porous Mn5O8 microspheres

A reusable catalyst with dual active center for chemical water oxidation is synthesized for the first time by immobilization of iridium oxide nanoparticles (IrO₂ NPs) on monodisperse-porous manganese oxide microspheres acting both catalytic active center and support. Individual catalytic activity of manganese oxide microspheres is explained by multiple oxidation states of manganese which are capable of forming oxidative oxygen species. Monodisperse-porous microspheres in the form of Mn₅O₈, MnO₂ and Mn₂O₃ are used for synthesis of different catalysts and the highest activity in water oxidation is observed with the catalyst synthesized using Mn₅O₈ microspheres. The catalytic activity is correlated with the total Mn(II) and Mn(III) percentage of manganese oxide type selected for composite catalyst. The oxygen evolution up to 244 μmol is achieved in 30 min with the catalyst synthesized using Mn₅O₈ microspheres. Maximum TON and TOF numbers are obtained as 298 and 557 h^?1 with excellent reusability.     

The influence of nitrogen doping on reduced graphene oxide as highly cyclable Li-ion battery anode with enhanced performance

A straightforward, one-step route has been established to fabricate reduced- (rGO) and nitrogen-doped reduced graphene oxide (NrGO) with remarkable lithium-ion storage properties. The graphene oxide (GO) was synthesized as starting material by improved Hummers’ method. Thereafter, thermally annealing GO with NH₃ at elevated temperature to synthesize NrGO was yielded a more open structure with nitrogen sites suitable for enhanced Li intercalation. NrGO exhibited a reversible capacity of 240 mAhg^?1 at 10 Ag^-1 after 500 cycles with 90% capacity retention, which is the best result achieved among graphene oxide-based anodes at this current density. In contrast to rGO, NrGO cells exhibited a gradually increasing capacity profile, reaching up to 114% of the initial capacity at 0.1, 2, and 10 Ag^-1 current densities. Results showed that high occupancy of pyridinic N within NrGO enhanced battery performance and cell kinetics upon cycling which offers long-time operability at high current density.     

Innovative hydrogen release from sodium borohydride hydrolysis using biocatalyst-like Fe2O3 nanoparticles impregnated on Bacillus simplex bacteria

For the first time in this innovative study, microorganisms such as Bacillus simplex bacteria, mostly used in biological activity studies, are used as a bio-supporter agent of iron to release hydrogen from sodium borohydride hydrolysis at 25.0 ± 0.1 °C. The goal is to investigate thoroughly sodium borohydride hydrolysis catalyzed by Fe₂O₃ nanoparticles impregnated on microorganism such as Bacillus simplex (BS) bacteria (Fe₂O₃@BS NPs) known with strong antibacterial properties, which makes innovative them a candidate for hydrolysis reaction. This study was focused on the preparation, identification, and catalytic use of biocatalyst-like Fe₂O₃@BS NPs for hydrogen release from the sodium borohydride hydrolysis at 25.0 ± 0.1 °C. The characterization results made after and before hydrolysis reaction using by SEM/SEM-EDX, FT-IR, XRD, UV–vis, XPS, DLS, ELS Zeta potential, ESR, and TEM techniques reveal the formation of highly active, stable, durable, and long-lived biocatalysts-like Fe₂O₃@BS NPs.     

Ab-Initio Calculations and Thermodynamic Description of the Yb-Cd and Yb-Sn Systems

The phase diagrams of Yb-Cd and Yb-Sn systems were calculated by coupling the CALPHAD method and ab initio calculations. The enthalpies of formation of nine binary compounds (YbCd, αYbCd₂, Yb₂Sn, αYb₅Sn₃, βYb₅Sn₃, Yb₅Sn₄, YbSn, Yb₃Sn₅ and YbSn₃) were determined via ab initio density functional theory using the VASP code. Based on the available experimental data and the computed enthalpies of formation of the compounds, a thermodynamic assessment was carried out. The liquid phases and the γYb(bcc) and βYb(fcc) solid solutions were described by the Redlich–Kister polynomial model, while all the intermetallic compounds were treated as stoichiometric phases. A set of optimized model parameters were obtained for Yb-Cd and Yb-Sn systems. The calculated phase diagrams of these binary systems and their thermodynamic properties are presented and compared with the experimental data.     

Investigating the effect of production process of ball mill refiner on some physical quality parameters of compound chocolate: response surface methodology approach

Chocolate compound was produced using ball mill refiner, and the effect of agitator shaft speed and refining time on the physical quality parameters (particle size, colour and steady‐state rheology) of compound chocolate was determined using response surface methodology. The shaft speed and refining time range were selected between 40–60 r.p.m. and 10–30 min, respectively. Determination coefficient of the models established for particle size, Newtonian viscosity and colour parameters (brightness, chroma and hue angle) were found to be very close to unity. Increasing shaft speed and time induced a reduction in particle size and an increase in viscosity of the samples. Temperature sweep test was also performed, and the obtained data were successfully fitted to Arrhenius equation to calculate the corresponding parameters representing temperature dependency of the compounds. The results highlighted that the establishment of such models can provide essential information in terms of optimisation of production processes regarding usage purpose of the compound chocolate.     

Lamellar eutectic growth with anisotropic interphase boundaries: Experimental study using the rotating directional solidification method

We report on an experimental study of the effects of interphase boundary anisotropy on eutectic microstructures using a new methodology called rotating directional solidification (RDS), which consists of rotating a thin sample with respect to a fixed unidirectional thermal gradient. The systems used are thin, large eutectic grains of the CBr₄–C₂Cl₆ and In–In₂Bi lamellar eutectic alloys. The shape of the observed RDS lamellar trajectories turns out to be a reproducible eutectic-grain-dependent feature, in agreement with the theoretical prediction that these trajectories are approximately homothetic to the Wulff form of the interphase boundary in the sample plane. We show that different modes of lamellar growth, ranging from quasi-isotropic to (crystallographically) locked, exist in different eutectic grains of the two alloys studied. A detailed characterisation of these modes is given, with particular attention to the as-yet poorly understood aspects of locked lamellar growth.