Large-scale hydrogen energy storage in salt caverns

Large-scale energy storage methods can be used to meet energy demand fluctuations and to integrate electricity generation from intermittent renewable wind and solar energy farms into power grids. Pumped hydropower energy storage method is significantly used for grid electricity storage requirements. Alternatives are underground storage of compressed air and hydrogen gas in suitable geological formations. Underground storage of natural gas is widely used to meet both base and peak load demands of gas grids. Salt caverns for natural gas storage can also be suitable for underground compressed hydrogen gas energy storage. In this paper, large quantities underground gas storage methods and design aspects of salt caverns are investigated. A pre-evaluation is made for a salt cavern gas storage field in Turkey. It is concluded that a system of solar-hydrogen and natural gas can be utilised to meet future large-scale energy storage requirements.     

Selective separation of cobalt and nickel by supported liquid membranes

The selective separation of cobalt from acidic media, containing both equimolar and nonequimolar mixtures of cobalt and nickel, was examined by supported liquid membranes using Alamine 336 as mobile carrier dissolved in various diluents. The membrane support was microporous hydrophobic polypropylene Celgard 2500 (25 μm thick, 0.209 × 0.054 μm pore size and 55% porosity). Acetic acid-Na acetate buffer was used for the adjustment of the feed pH which was critical. Various parameters were experimentally studied and the optimum conditions were determined.     

The preparation of core–shell Al2O3/Ni composite powders by electroless plating

Core–shell nanostructured Ni-coated Al₂O₃ composite powders were synthesised by using the electroless plating method. The influence of the chemical components and powder concentration in the Ni coating was investigated by scanning electron microscopy, energy dispersive spectroscopy, and X-ray diffraction techniques. The results show that the concentration of the plating components plays an important role in the formation of core–shell Al₂O₃/Ni composite powders. The nickel content in the composite powders could be effectively controlled by adjusting the nickel chloride content and the concentration of NaH₂PO₂·H₂O in the plating solution. The nanostructure of the crystalline Ni coatings was observed to be very attractive for achieving good bonding between ceramic particles and matrices for composite production.     

Catalytic effect of potassium carbonate on carbothermic production of hexagonal boron nitride

Effect of potassium carbonate addition on the carbothermic formation of hexagonal boron nitride (hBN) was investigated by keeping the K₂CO₃ added B₂O₃+C mixtures in nitrogen atmosphere at 1400 °C for 40–160 min. K₂CO₃ amount was varied in the range of 10–60 wt% of the B₂O₃+C mixture. Products were subjected to XRD and quantitative analyses, SEM and TEM observations, and particle size measurement. Amount of hBN increased considerably with K₂CO₃ addition; also particle size and crystallinity improved. Catalytic role of K₂CO₃ was suggested as forming a potassium borate melt in which hBN particles form, in addition to carbothermic formation reaction. Effect of K₂CO₃ on increasing the hBN amount decreased when it was used over 40%. This was attributed to the rapid evaporation of the formed potassium borate liquid.     

A novel low-clay translucent whiteware based on anorthite

This study was carried out to characterize the properties of a novel low-clay translucent whiteware suitable for daily use. The low-clay whiteware is produced from coarsely and finely milled prefired materials of the same composition plus a small amount of clay. It consists of anorthite (CaO·Al₂O₃·2SiO₂) and mullite (3Al₂O₃·2SiO₂) crystalline phases and a glassy phase with high crystalline to glassy phase ratio. The development of needle shaped long mullite crystals that were forming three dimensional interlocking network had significant effect on the elimination of pyroplastic deformation during glaze firing. Typical flexural strength and fracture toughness values were ∼110 MPa and ∼1.85 MPam^1/2, respectively. The low-clay whiteware had relatively low (4.6 × 10⁻⁶/°C) thermal expansion coefficient which made possible to glaze the whiteware with a typical hard porcelain glaze. A continuous interface layer was produced between the whiteware and the glaze and no crack was present through layer because of expansion mismatch.     

An application of the degree-hours method to estimate the residential heating energy requirement and fuel consumption in Istanbul

Cold season heating energy requirements in buildings can be estimated with the degree-hours method based on human comfort levels and available meteorological temperature records for a given area. Such estimations are especially significant for cities where fossil fuel consumption must be eliminated in favor of clean energy alternatives to reduce air pollution. This paper considers the city of Istanbul in Turkey and presents a detailed account for practical energy requirements and fuel consumption calculations.     

Adaptive three-dimensional cellular genetic algorithm for balancing exploration and exploitation processes

This paper presents a new adaptive algorithm that aims to control the exploration/exploitation trade-off dynamically. The algorithm is designed based on three-dimensional cellular genetic algorithms (3D-cGAs). In this study, our methodology is based on the change in the global selection pressure induced by dynamic tuning of the local selection rate. The parameter tuning of the local selection method is a way to define the global selection pressure. A diversity speed measure is used to guide the algorithm. Therefore, the integration of existing techniques helps in achieving our aims. A benchmark of well-known continuous test functions and real world problems was selected to investigate the effectiveness of the algorithm proposed. In addition, we provide a comparison between the proposed algorithm and other static and dynamic algorithms in order to study the different effects on the performance of the algorithms. Overall, the results show that the proposed algorithm provides the most desirable performance in terms of efficiency, efficacy, and speed for most problems considered. The results also confirm that problems of various characteristics require different selection pressures, which are difficult to be identified.     

Migration behavior of landfill leachate contaminants through alternative composite liners

Four identical pilot-scale landfill reactors with different alternative composite liners were simultaneously operated for a period of about 540 days to investigate and to simulate the migration behaviors of phenolic compounds (phenol, 2-CP, 2-MP, 3-MP, 4-MP, 2-NP, 4-NP, 2,4-DNP, 2,4-DCP, 2,6-DCP, 2,4,5-TCP, 2,4,6-TCP, 2,3,4,6-TeCP, PCP) and heavy metals (Pb, Cu, Zn, Cr, Cd, Ni) from landfill leachate to the groundwater. Alternative landfill liners of four reactors consist of R1: Compacted clay liner (10 cm + 10 cm, k = 10⁻⁸ m/sn), R2: Geomembrane (2 mm HDPE) + compacted clay liner (10 cm + 10 cm, k = 10⁻⁸ m/sn), R3: Geomembrane (2 mm HDPE) + compacted clay liner (10 cm, k = 10⁻⁸ m/sn) + bentonite liner (2 cm) + compacted clay liner (10 cm, k = 10⁻⁸ m/sn), and R4: Geomembrane (2 mm HDPE) + compacted clay liner (10 cm, k = 10⁻⁸ m/sn) + zeolite liner (2 cm) + compacted clay liner (10 cm, k = 10⁻⁸ m/sn). Wastes representing Istanbul municipal solid wastes were disposed in the reactors. To represent bioreactor landfills, reactors were operated by leachate recirculation. To monitor and control anaerobic degradation in the reactors, variations of conventional parameters (pH, alkalinity, chloride, conductivity, COD, TOC, TKN, ammonia and alcaly metals) were also investigated in landfill leachate samples. The results of this study showed that about 35-50% of migration of organic contaminants (phenolic compounds) and 55-100% of migration of inorganic contaminants (heavy metals) to the model groundwater could be effectively reduced with the use of bentonite and zeolite materials in landfill liner systems. Although leachate contaminants can reach to the groundwater in trace concentrations, findings of this study concluded that the release of these compounds from landfill leachate to the groundwater may potentially be of an important environmental concern based on the experimental findings.     

Mechanical and microstructural properties of low-carbon steel-plate-reinforced gray cast iron

In the present experimental study, strengthening of gray cast iron by reinforcing with steel plates was investigated in the as-cast and normalized conditions. Normalizing heat treatments were applied to the specimens at temperatures of 800 °C and 850 °C. Three-point bend specimens were manufactured from gray cast iron and also from gray cast iron with reinforced steel plates. Flexural strengths of the steel-plate-reinforced cast iron were calculated for four distinct volume fractions (V_r = 0.04, 0.08, 0.12, and 0.16). The current study shows that the steel-plate-reinforced gray cast iron has higher flexural strength and flexural modulus than the cast iron without reinforcement. The flexural strength considerably increases with slight increase in normalization temperature. Optical and scanning electron microscopy analyses were used to examine flake morphology and microstructures of gray cast iron and steel-plate-reinforced gray cast iron. It is noted that carbon diffuses from the gray cast iron to the steel plates. A transition region containing partially dissolved graphite and having high hardness was observed due to the carbon diffusion.