Morphology and properties of poly[2‐methoxy‐5‐(2′‐ethyl‐hexyloxy)‐para‐phenylene vinylene]/silica nanoparticle hybrid films

Poly[2‐methoxy‐5‐(2′‐ethyl‐hexyloxy)‐para‐phenylene vinylene] (MEH‐PPV)/silica nanoparticle hybrid films were prepared and characterised. Three kinds of materials were compared: parent MEH‐PPV, MEH‐PPV/silica (hybrid A films), and MEH‐PPV/coupling agent MSMA/silica (hybrid B films), in which MSMA is 3‐(trimethoxysilyl) propyl methacrylate. It was found that the hybrid B films could significantly prevent macrophase separation, as evidenced by scanning electron and fluorescence microscopy. Furthermore, the thermal characteristics of the hybrid films were largely improved in comparison with the parent MEH‐PPV. The UV‐visible absorption spectra suggested that the incorporation of MSMA‐modified silica into MEH‐PPV could confine the polymer chain between nanoparticles and thus increase the conjugation length. The photoluminescence (PL) studies also indicated enhancement of the PL intensity and quantum efficiency by incorporating just 2 wt% of MSMA‐modified silica into MEH‐PPV. However, hybrid A films did not show such enhancement of optoelectronic properties as the hybrid B films. The present study suggests the importance of the interface between the luminescent organic polymers and the inorganic silica on morphology and optoelectronic properties. Copyright © 2004 Society of Chemical Industry     

生态平衡的伦理学意蕴解读

20世纪以来，人类采用技术工程治理、法律制裁和经济惩罚等措施，一定意义上改善了局部的生态环境，但是未能遏制住全球环境问题的恶化态势。生态危机的根本解决，关键在于人类自身必须进行深刻的利益观念和价值观念的变革。重新审视人与自然界的关系，对自然进行伦理关怀，寻求和建立以保护地球环境和人类生存与可持续发展的生态平衡理念。     

浅析露天栈桥改造

结合工程实例，论述了露天栈桥产生裂缝和腐蚀的原因，对栈桥结构进行了评价，提出了加固方案及加固施工中应注意的事项，经使用证明，加固效果良好。     

四川马海毛钢花呢的试制

根据四川马海毛原料资源的品质特性，运用精纺粗做的方法，成功地试制出手感滑糯而富有弹性、光泽明亮悦目，各项物理指标符合FZ/T24002-93标准的四川马海毛纯毛钢花呢，达到了马海毛产品的特殊风格。同时指出四川马海毛制成率偏低。     

多级网络多处理机系统的性能评估

本文建立了多级网络(δ-网)多处理机系统的马尔柯夫模型,为系统结构参数和任务粒度的选择提供了依据。文中分析了处理机数目、网络结构参数和任务粒度对系统性能的影响,并对模型计算结果和仿真结果作了比较。     

β″－Al_2O_3陶瓷的强化和韧化

研究了稳定ＺｒＯ＿２和部份稳定ＺｒＯ＿２对β″－Ａｌ＿２Ｏ＿３陶瓷的强化和韧化作用，观察了不同种类、不同含量的ＺｒＯ＿２对β″－Ａｌ＿２Ｏ＿３陶瓷的显微结构、力学性能和电导率的影响，探讨了β″－Ａｌ＿２Ｏ＿３的韧化机理。     

映射半解析边界元法解瞬态弹性动力问题的有关问题

提出了映射半解析边界元法解百轴对称瞬态弹性动力问题时存在解析方向不能正确反映波的传播现象的问题，产生该问题的原因和如何解决该问题的建议。     

二元复合驱采出液矿场处理试验

利用研制的二元复合驱采出液矿场处理装置，对辽河油田兴28块兴191井采出液进行了矿场处理试验。结果表明，采用适宜的破乳剂及处理工艺技术，可以使矿场采出液处理达到净化油含水≤0．5％的指标。     

The maximum bit rates of soliton communication systems with lumpedamplifiers and filters in different distances

The maximum bit rate of a soliton communication system with lumped amplifiers and optical filters is considered. When the dispersion of the fiber varies from one amplifier spacing to another amplifier spacing, the maximum bit rate is significantly reduced. To overcome the effect, the amplitude of the soliton is amplified so that it is still the average soliton corresponding to the fiber dispersion for an amplifier spacing. Thus, the maximum bit rate is only slightly less than that without the dispersion variations. For a given distance, the maximum bit rate limited by the stability and soliton interaction is obtained. The result is compared with that limited by the Gordon-Haus effect. For shorter transmission distance, the maximum bit rate is limited by the stability and soliton interaction. For longer transmission distance, the maximum bit rate is limited by the Gordon-Haus effect     

柴油机低频排气噪声规律分析

针对柴油机（4－85）低频排气噪声，对其产生机理、规律及其影响因素等作了理论计算、分析及实验。对低频排气噪声信号进行频域分析后可知，其主要由一系列离散的谐波组成，是以柴油机点火频率为基频的一种类周期性噪声，有可能应用有源噪声控制技术。