Properties of Ferrite-Filled Natural Rubber Composites

Nickel zinc ferrite (Ni-ZnFe₂O₄)-filled natural rubber (NR) composite was prepared at various loading of ferrite. The tensile properties included in this study were tensile strength, tensile modulus and elongation at break. The tensile strength and elongation at break of the composites increased up to 40 parts per hundred rubber (phr) of ferrite and then decreased at higher loading whereas the tensile modulus was increased gradually with increasing of ferrite loading. Scanning electron microscopy (SEM) was used to determine the wettability of filler in rubber matrix. From the observation, the increase of filler loading reduced the wettability of the filler. Thermal stability of the composites was conducted by using a thermogravimetry analyser (TGA). The incorporation of ferrite in NR composites enhanced the thermal stability of NR composites. The swelling test results indicate that the swelling percentage of the composites decreased by increasing of ferrite loading. The initial permeability, μ_i and quality factor, Q of magnetic properties of NR composites achieved maximum value at 60 phr of ferrite loading for frequency range between 5000–40,000 kHz. The maximum impedance, Z _max of the NR composites was at the highest value at 80 phr ferrite loading for frequency range between 200–800 MHz.     

Effects of acid strength and micro pore size on -caprolactam selectivity and catalyst deactivation in vapor phase Beckmann rearrangement over acid solid catalysts

The vapor phase Beckmann rearrangement of cyclohexanone oxime (CHO) over solid acid catalysts including zeolites was carried out to elucidate the effects of the acid strength and the micropore size of the catalysts on the selectivity of -caprolactam (CL) and the catalyst deactivation rate. It was found that the catalyst deactivation rate was strongly dependent on the acid strength of the acid catalysts. The improvement of catalyst life was achieved by using MFI-type metallosilicates having weak acid sites. The CL selectivity decreased over the acid catalysts with micropores larger than those of the MFI zeolites. Furthermore, using methanol and carbon dioxide as the diluent solvent and diluent gas improved CL selectivity and catalyst life, respectively.     

Effect of inclined roof on the airflow associated with a wind driven turbine ventilator

Rotating wind driven turbine ventilator has been used as cost-effective environmental friendly natural ventilation device. Rotating wind driven turbine ventilator type of device is usually installed on the rooftop to extract air extract air flow from a building to improve air quality and comfort. Performance investigations carried thus far on turbine ventilator have ignored the effect of the inclination on rooftop. An experimental program was, therefore, formulated at the aerodynamic laboratory of the University of New South Wales to study such effect on a simulated rooftop. The results obtained from the measured forces and rotational speeds on different configurations indicate that the effect is minimal in extracting air from a building at low wind speed. The static pressure and skin friction distributions on the simulated roof further supports this finding. Two important conclusions can be drawn from the present investigation: firstly, the presence of the inclined roof may extend the safety margin in the operation of a turbine ventilator at high wind speed by reducing the magnitude of the total force that acts on the ventilator; secondly the dependency of the total fore on low Reynolds number suggests that the efficiency and reliability of operation of such ventilator should be boosted through the provision of other power source such as solar power at low wind speed.     

Protective effect of ω-3 polyunsaturated fatty acids (PUFA) on sodium nitrite induced nephrotoxicity and oxidative damage in rat kidney

Sodium nitrite (SNT) widely used as a curative agent in meat processing industry possesses cell-transforming mutagenic and cytogenic properties. Dietary omega-3 polyunsaturated fatty acids (ω-3 PUFA) has been shown to reduce the severity of certain types of cancers, cardiovascular and renal diseases. The present study examined whether feeding of fish oil (FO)/flaxseed oil (FXO) has protective effect against SNT-induced toxicity. SNT significantly altered the activities of serum creatinine (Crt), blood urea nitrogen (BUN), metabolic and brush border membrane (BBM) enzymes. SNT caused significant imbalances in the antioxidant system associated with increased lipid peroxidation (LPO). Feeding of FO and FXO with SNT ameliorated the changes in various parameters caused by SNT. Nephrotoxicity parameters lowered and enzyme activities of carbohydrate metabolism, BBM and radioactively labeled inorganic phosphate (³²Pi) transport were improved to near control values. The results of the present study suggest that ω-3 PUFA-enriched FO and FXO from sea-foods and plant sources respectively are similarly effective in reducing SNT-induced nephrotoxicity and oxidative damage.     

Viscosity estimation of triacylglycerols and of some vegetable oils, based on their triacylglycerol composition

The experimentally determined kinematic viscosities of simple triacylglycerols [trilaurin, trimyristin (MMM), tripalmitin (PPP), tristearin (SSS), triolein (OOO), and trilinolein (LiLiLi) were correlated to a modified Andrade-type equation. The constants for the modified equation were derived for each simple triacylglycerol. The method was also used to estimate the viscosity of mixed triacylglycerols [1,2-dimyristoyl-3-palmitoyl (MMP), 1,2-dioleoyl-3-palmitoyl (OOP), 1,2-dimyristoyl-3-oleoyl (MMO), and 1,2-dipalmitoyl-3-oleoyl (PPO)], binary triacylglycerol mixtures (PPO/OOP, PPP/SSS, and OOO/SSS of different portions), and three types of vegetable oils [refined, bleached, and deodorized palm oil; cocoa butter; and canola oil] by applying modified Kay’s rule utilizing the simple triacylglycerol constants derived earlier. In all cases, the estimated values for liquid viscosity were compared with experimental values determined in this work and with previous work from the literature. When applied to vegetable oils, the method requires knowledge of their triacylglycerol composition. Despite its simplicity, the method gives a reasonable estimate. The method may be used to predict the viscosity of different blends of vegetable oils, and the accuracy is expected to increase when more experimental data on simple triacylglycerols become available.     

Preparation of presintered zirconia blocks for dental restorations through colloidal dispersion and cold isostatic pressing

This work proposes an effective method for dispersion of zirconia suspension for dental block preparation and optimizes the cold isostatic pressing (CIP) pressure to improve the densification of slip-casted zirconia blocks. Two batches of 44 wt% zirconia suspension were prepared using distilled water in a pH 2 medium containing 0.5 wt% polyethyleneimine as dispersant. The first batch was sonicated for different durations (from 5 min to 30 min), and the second batch was dispersed through ball milling at rotational speeds of 200, 300, and 400 rpm for 60, 90, and 120 min. All suspensions were subjected to sedimentation test and particle size measurement. Results revealed that the optimum ultrasonication duration was 10 min, which yielded the smallest particle size of 133 nm. Ball milling at 300 rpm for 120 min achieved the maximum dispersion of particles, with an average size of 75 nm. Under the optimum conditions of ultrasonication duration, ball milling duration, and ball milling speed, the particle size decreased to 48 nm, which is close to the primary particle size. These dispersion techniques and parameters were selected for preparing a suspension to be consolidated into blocks through slip casting and were enhanced through CIP at pressure ranging from 100 MPa to 300 MPa. CIP compaction at 250 MPa significantly increased the shrinkage percentage of green zirconia blocks, with pore radius decreased to 18 nm. The density of zirconia pressed at 250 MPa and presintered at a low temperature of 950 °C was 59% of the theoretical density and was higher than that of commercial presintered blocks. Thus, CIP should be conducted under a compaction pressure of 250 MPa to produce dense and homogeneous zirconia blocks.     

Analysis of a turbulent boundary layer subjected to a strong adverse pressure gradient

We define two non-dimensional parameters $\text{Λ =}\text{τ}{}_{\mathrm{w}}\text{p}{}_{\mathrm{x}}\text{δ}$ and $\text{R}{}_{\mathrm{p}}\text{=}\text{U}{}_{\mathrm{p}}\text{δ}\text{ν}$ where τ_w is the wall stress, p_x(?0) is the pressure gradient to which the turbulent boundary layer (of thickness δ) is subjected, ν is the kinematic viscosity, $\text{U}{}_{\mathrm{p}}\text{= (}\text{νp}{}_{\mathrm{x}}\text{p}\text{)}{}^{\mathrm{<mtext>1</mtext><mtext>3</mtext>}}$ is a characteristic velocity and p is the density. The limit corresponding to the strong adverse pressure gradient is formulated as Λ → 0, R_p → ∞, ΛR_p finite. Using appropriate inner and outer asympcotic expansions, both above a wall layer possibly scaling with τ_w and ν, it is found by an application of Millikan's argument that there is an inertial sublayer where the streamwise velocity distribution obeys a half-power law, whose slope depends on Λ, and intercept on ΛR_p. Indeed comparison with available experimental data shows the inner law to be well represented by $\text{u}\text{Up}\text{= (3.5 + 19Λ)(}\text{yU}{}_{\mathrm{p}}\text{ν}\text{)}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{+ 2.5ΛR}{}_{\mathrm{p}}$. The outer flow obeys a generalized defect law; use of constant eddy viscosity closure yields results in good agreement with experiment.     

Tracing post-limit-point paths with reduced basis technique

A reduced basis technique and a problem-adaptive computational algorithm are presented for predicting the post-limit-point paths of structures. In the proposed approach the structure is discretized by using displacement finite element models. The nodal displacement vector is expressed as a linear combination of a small number of vectors and a Rayleigh-Ritz technique is used to approximate the finite element equations by a small system of nonlinear algebraic equations.To circumvent the difficulties associated with the singularity of the stiffness matrix at limit points, a constraint equation, defining a generalized arc-length in the solution space, is added to the system of nonlinear algebraic equations and the Rayleigh-Ritz approximation functions (or basis vectors) are chosen to consist of a nonlinear solution of the discretized structure and its various order derivatives with respect to the generalized arc-length. The potential of the proposed approach and its advantages over the reduced basis-load control technique are outlined. The effectiveness of the proposed approach is demonstrated by means of numerical examples of structural problems with snap-through and snap-back phenomena.