A highly selective triphenylamine-based indolylmethane derivatives as colorimetric and turn-off fluorimetric sensor toward Cu detection by deprotonation of secondary amines

A new triphenylamine-based fluorogenic probe bearing an indolylmethane unit (R1) was developed as a fluorescent chemosensor with high selectivity toward Cu²⁺ over other cations tested. The new probe R1 only sensed Cu²⁺ among heavy and transition metal (HTM) ions in CH₃CN/H₂O (70/30, v/v) solution. The capture of Cu²⁺ by the receptor resulted in deprotonation of the secondary amine conjugated to the triphenylamine, so that the electron-donation ability of the “N” atom would be greatly enhanced; thus sensor showed a 250 nm change in the new absorption band (from 291 nm to 541 nm) and a large colorimetric response, it also exhibited the large decrease in fluorescence intensity at 378 nm and affinity to Cu²⁺ over other cations such as Hg²⁺, Fe³⁺, Pb²⁺, Zn²⁺, Cd²⁺, Ni²⁺, Co²⁺ and Mn²⁺ make this compound a useful chemosensor for Cu²⁺ detection in CH₃CN/H₂O (70/30, v/v) mixture. The probe R1 (c = 1.0 × 10⁻⁶ M) displayed significant fluorescence change and colorimetric change upon addition of Cu²⁺ among the metal ions examined.     

New Technology Introduction and Implementation: The Case of Paging Technology in the Ratlam Division of Indian Railways

Concomitant to the liberalisation policy and market reforms in India has been the issue of declining budgetary support for public sector organisations. Hitherto, Indian Railways, the biggest publicly-owned enterprise, has largely been supported by the exchequer. Since the early 1990s, however, the Railways has had to operate increasingly as a commercial rather than a social organisation. One of the ways of improving efficiency is to introduce efficiency-enhancing technologies. This paper is a case study of the introduction of paging technology to the Ratlam Division of Indian Railways. It describes the process of planning and implementation, the HRM implications of the adoption and how the process was successfully managed. It aims at shedding further light on the nature and the processes whereby technologies eventually gain company recognition and acceptance.     

钢框架非比例损伤识别

提出能够鉴别损伤位置和截面损伤严重程度的钢框架非比例破坏监测方法。所提出的方法由两部分组成,一是损伤识别,二是损伤严重程度分析。损伤识别和严重程度分析均以结构动力性质的变化作为损伤的判据,以此来确定损伤位置和严重程度。所提方法中损伤判别的重要特点是能够在损伤严重程度分析之前,精确地区分不同的损伤区域。与整个结构尺寸相比,损伤区域相对较小,因此,确定损伤严重程度的计算量更小。检测方法的另一个特点是有些特征值或振型对噪声相对不敏感。采用所提检测方法对几个框架进行验证,结果表明,该方法能够成功地检测及量化截面的损伤。     

A Convenient Synthesis of Some Coumarin Derivatives Using SnCl2 · 2H2O as Catalyst

Some substituted coumarins have been synthesized by von-Pechmann condensation using SnCl₂ · 2H₂O (10 mol %) as catalyst in ethanolic medium. The reactions are simple, easy in handling and environmentally benign.     

Lean philosophy: implementation in a forging company

This research addresses the implementation of lean philosophy in a forging company with a focus on radial forging production flow lines. Here, the prime motive is to evolve and test several strategies to eliminate waste on the shop floor. In this research, a systematic approach is suggested for the implementation of lean principles. This paper describes an application of value stream mapping (VSM). Consequently, the present and future states of value stream maps are constructed to improve the production process by identifying waste and its sources. Furthermore, Taguchi’s method of design of experiments is pursued here to minimize the forging defects produced due to imperfect operating conditions. A noticeable reduction in set-up time and work-in-process (WIP) inventory level is substantiated. Finally, we conclude with a discussion of managerial implications and the future scope of research.     

Estimation of wood char size at the end of devolatilization in a bubbling fluidized bed combustor

Two processes, namely shrinkage and primary fragmentation are known to be the major causes of size reduction of wood during its devolatilization in a fluidized bed combustor. A simple phenomenological model incorporating these effects to compute the average char size at the end of devolatilization is proposed. Experiments are conducted in a bubbling fluidized bed combustor using wood having three different shapes namely, cylinder, cuboid and sphere, to measure the average char size at the end of devolatilization. The model prediction of average char size agrees with the measured values within a deviation of 15%. An experimental correlation is derived to determine the number of fragments and is used to estimate the mean char size.     

Modelling and experimental investigation of devolatilizing wood in a fluidized bed combustor

A two-dimensional model is developed for the determination of devolatilization time and char yield of cylindrical wood particles in a bubbling fluidized bed combustor. By using the concept of shape factor, the model is extended to particles of cuboid shape. The model prediction of the devolatilization time agrees with the measured data (present and those reported in the literature) for cylindrical and cuboidal shaped particles within ±20% while the char yield is predicted within ±17%. Influence of some important parameters namely, thermal diffusivity, external heat transfer coefficient and shrinkage, on the devolatilization time and char yield are studied. Thermal diffusivity shows noticeable influence on devolatilization time. The external heat transfer coefficient shows little influence beyond a value of 300 W/(m² K). However particle shrinkage shows negligible effect on the devolatilization time but has a significant influence on the char yield.