Expectancy theory prediction of the goal theory postulate, "The harder the goals, the higher the performance."

Goal theory postulates that harder goals lead to higher performance than do easier goals. The present study tested the prediction, based on expectancy valence theory, that this would be true only if the payoff for succeeding at the harder goal is sufficiently greater than the alternatives to compensate for its greater difficulty. 63 undergraduates were each given an easy and a hard task/goal, requiring the comparison of paired sets of 3-digit numbers. Expectancy theory measures for the 2 goals were obtained from Ss. Performance was higher for the hard goal than for the easy goal, supporting the goal theory postulate. Force was also higher for the hard goal than for the easy goal. In addition, force change across the 2 goals was associated with performance change, supporting the conclusion that expectancy valence theory can predict the goal theory postulate. The valence of goal attainment was higher for the hard goal than for the easy goal. Valence change across the 2 goals was associated with performance change to a greater degree than was expectancy change, suggesting that the attained performance difference can be attributed to the valence difference. (10 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

The role of abduction in chance discovery

Recently, researches on discovery science and knowledge discovery have been carried out in various fields. Basically they are types of learning that learn tendencies from the sets of data of the same or similar categories. In this sense, discovery is to discover the tendencies. As a result, they cannot predict the events that are different from the trend. On the other hand, abduction is thought of as an explanatory reasoning. Indeed, abduction is a reasoning to generate hypotheses to explain an observation. However, the original meaning of abduction was to discover new things that cannot be known in a simple way. In this paper, abduction is defined using the original definition that discovers something that cannot be easily predicted. Then, this paper shows a role of abduction that can suggest or foresee the events that are different from the trend. In fact, Abductive Analogical Reasoning that can generate new hypotheses is adopted to solve the problem. Akinori Abe, Ph.D.: He obtained his Doctor of Engineering (Ph.D) from the University of Tokyo in 1991, with a thesis entitledA Fast Hypothetical Reasoning System using Analogical Case. His main research interests are abduction (hypothetical reasoning), analogical reasoning, chance dicovery and language sense processing. He is a member of the Planning Committee of the New Generation Computing. He worked in NTT MSC (Malaysia) from 2000 to 2002. Currently, he works in ATR.     

Intra-molecular mobility of holes along rod-like helical Si backbones in optically active polysilanes

Intra-molecular mobility of positive charge carriers in poly(n-hexyl-[S]-2-methylbutylsilane) (PHMBS) films doped with N,N′-bis(2,5-di-tert-buthylphenyl)-3,4,9,10-perylenedicarboximide (PDI) is studied by time-resolved microwave conductivity (TRMC) measurements. PHMBS with optically active side chains has a rod-like tightly locked Si catenation with unlikely long persistence length compared with conventional dialkyl-substituted polysilanes. It was found that PDI is a suitable electron acceptor for PHMBS as it provides the high product of photo carrier generation yield ? as ～0.08% under an excitation at 355 nm. The efficient electron transfer reaction from PHMBS to PDI gives clear conductivity transients ascribed to the positive charges on the Si catenation of PHMBS by TRMC measurements. The estimated value of isotropic mobility along the tightly locked Si catenation is 0.36 cm² V^?1 s^?1, suggesting the presence of mobile holes on the backbones of PHMBS.     

Water wettability/non-wettability of polymer materials by molecular orbital studies

The water wettability and non-wettability onto various kinds of polymers, which have so far been macroscopically described by the water contact angle, were investigated using the molecular orbital theory. An atomistic model consisting of an H₂O molecule and a selected polymer crystal surface was analyzed in the isolated and the physisorbed states. The degree of interaction between the water molecule and the polymer surface was evaluated by considering the change of Mulliken charge at the oxygen site in the water molecule, and also the work of adhesion during the physisorption process. Such energetic quantities for several polymers were compared with the macroscopic water wettability/non-wettability. We found fairly good agreement between these approaches for the highly non-wettability polymers.     

Properties of bifunctional phosphonate fibers derived from chloromethylstyrene grafted polyolefin fibers

Bifunctional fibers containing phosphonate and sulfonate were derived from chloromethylstyrene grafted polyolefin fibers (PPPE-g-CMS) by phosphorylation and subsequent sulfonation reactions. It was clarified that phosphorylation of PPPE-g-CMS by Arbusov reaction is more suitable than one by the reaction with PCl₃ in the presence of AlCl₃, because the latter damaged fibers and gave phosphinate groups in addition to phosphonate ones. Then, bifunctional fibers containing phosphonate and sulfonate groups were prepared by sulfonation of monofunctional phosphonate fibers obtained via Arbusov reaction with chlorosulfonic acid. The metal ion selectivity of the bifunctional fibers was governed by both phosphonate and sulfonate groups. In addition, bifunctional fibers gave much more excellent kinetic performances in column-mode uptake of Cu(II) than the monofunctional phosphonate fibers and resin.     

Nucleation effect of inclusion complexes with different polyolefin as guest molecules on the crystallization of polypropylene

The γ‐cyclodextrin (γ‐CD) inclusion complexes (ICs) with four kinds of polyolefin (PO) as guest molecules were prepared. The crystallization behavior of isotactic polypropylene (iPP) blended with the γ‐CD and γ‐CD–PO ICs was investigated by differential scanning calorimetry, polarized optical microscopy, and light scattering. The iPP blended with the ICs was found to exhibit higher crystallization temperature (T_C), smaller spherulites, and faster crystallization rate than those of neat iPP, indicating that the ICs play a role of nucleating agent on the crystallization of iPP and induce accelerated crystallization. The IC with PO having higher T_C as guest molecules showed higher nucleation effect than the IC with PO having lower T_C as guest molecules. The results suggest that the nucleation effect of these ICs was affected by the kinds of the guest molecules. The higher T_C guest molecules could result in higher nucleation effect. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Colorimetric chemosensor for ATP based on phthalimide-appended poly(2,5-dimethoxyaniline)

We have designed a colorimetric conjugated polymer (PDMAp) for selective ATP sensing based on poly(2,5-dimethoxyaniline) bearing phthalimide which can form hydrogen bonds with adenine. PDMAp have been synthesized via chemical oxidative polymerization with CSA and DDQ and dedoping with an aqueous ammonia solution. PDMAp was displayed to signal the colorimetric selective detection for ATP over various nucleotides such as ADP, AMP, CTP, TTP, and GTP in DMSO–water (9:1, v/v) mixture. The absorption spectral change can be attributed to a doping process of ATP to PDMAp through hydrogen bonds between phthalimide and adenine as well as electrostatic interactions between the phosphate group of ATP and the backbone of PDMAp.     

A novel coding method for genetic algorithms based on redundant binary numbers

This article proposes a novel genetic algorithm (GA) which switches the expression of the solution from a redundant binary number to a usual binary number. Furthermore, a GA which switches the expression from the Gray code to the usual binary number is proposed and compared. Comparisons of the performances among five GAs (binary number, redundant binary number, Gray code, switching from redundant binary number to binary number, switching from Gray code to binary number) are illustrated. The performances are evaluated by solving some equations. It is confirmed that the proposed GA effectively decreases the error rate.     

Programmed High‐Hole‐Mobility Supramolecular Polymers from Disk‐Shaped Molecules

In this paper a simple, casting solution technique for the preparation of two‐dimensional (2D) arrays of very‐high molecular weight (MW) 1D‐Pc supramolecular inorganic polymers is described. The soluble fluoroaluminium tetra‐tert‐butylphthalocyanine (ttbPcAlF) is synthesized and characterized, which can be self‐assembled to form 2D arrays of very‐high‐MW 1D‐Pc supramolecular inorganic polymers. High‐resolution transmission electron microscopy (HRTEM) demonstrates that the 1D‐ttbPcAlF, having a cofacial ring spacing of ～0.36 nm and an interchain distance of ～1.7 nm, self‐assembles into 2D‐nanosheets (～140 nm in length, ～20 nm in width, and equivalent to MW of 3.2 × 10⁵ g mol^?1). The film cast from a 1,2‐dichloroethane (DCE) solution shows a minimum hole‐mobility of ～0.3 cm² V^?1 s^?1 at room temperature by flash‐photolysis time‐resolved microwave conductivity (TRMC) measurements and a fairly high dark dc‐conductivity of ～1 × 10^?3 S cm^?1.