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91.
Masaru Takahashi Noriyuki Inoue Tatsuya Takeguchi Shinji Iwamoto Masashi Inoue Tsunenori Watanabe 《Journal of the American Ceramic Society》2006,89(7):2158-2166
The reaction of mixtures of aluminum isopropoxide and gallium acetylacetonate in 1,4-butanediol or 1,5-pentanediol at high temperatures (glycothermal reaction) directly gave the γ-Ga2 O3 –Al2 O3 solid solutions, which had high catalytic activities for selective reduction of NO using methane as the reducing agent. However, the reaction with a higher Al/(Ga+Al) charged ratio yielded the glycol derivative of boehmite as a by-product and the catalytic activity of the solid solution decreased. Therefore, synthesis of the solid solution using various glycols was examined and it was found that solid solutions with high Al contents without contamination of the glycol derivative of boehmite were obtained by using 1,6-hexanediol as a reaction medium. The solid solution exhibited a higher NO conversion than that synthesized in other glycols. 相似文献
92.
Yujiro Watanabe Yusuke Moriyoshi Yasushi Suetsugu Toshiyuki Ikoma Takeshi Kasama Tadashi Hashimoto Hirohisa Yamada Junzo Tanaka 《Journal of the American Ceramic Society》2004,87(7):1395-1397
Type-A zeolite evenly covered with hydroxyapatite thin layers was prepared using hydrothermal treatment at 120°C for 8 h under autogenous pressure. The hydroxyapatite needlelike nanocrystals, 100–200 nm in diameter and 30 nm in thickness, were grown under the reaction between discharged Ca2+ ions from type-A zeolite and PO4 3− ions in (NH4 )3 PO4 solution. The preferential orientations of the c -axis of hydroxyapatite crystals perpendicular to a zeolite surface were observed using transmission electron microscopy. The crystal structure of type-A zeolite was not destroyed under the reaction, but the surface morphology was changed only with complete covering of scaly hydroxyapatite particles. 相似文献
93.
Minoru Tsuda Setsuko Oikawa Akira Yokota Mitsuo Yabuta Wataru Kanai Ken-Ichi Kashiwagi Isamu Hijikata Hisashi Nakane 《Polymer Engineering and Science》1983,23(18):993-999
A dry developable negative working resist composition comprised of poly(methyl isopropenyl ketone) (PMIPK) and 4-methyl-2,6-di(4′-azido-benzylidene) cyclohexanone-1 was examined. The main photochemical product formed in the resist pattern was found to be a secondary amine which crosslinks PMIPK. Post-annealing forms a hydrogen-bonded product which shows a powerful electronic excitation energy quenching effect. The quencher is more powerful than the aromatic compound arising from the azide by post-annealing only. The residual resist thickness of the negative pattern is about 80 percent of the initial thickness of the coating in spite of all the azide compound remaining in the resist coating. The obtained dry developed resist pattern has a high dry etch resistance. Etchings of Si and SiO2 were performed by plasma and reactive ion etching, respectively. 相似文献
94.
Adsorption properties of graphite oxides hydrophobized by n-hexadecylamine, (C16)xGO, were investigated using pyrene molecules as a model of nonionic organic contaminants. A large quantity of pyrene (28.5 mg/g) was adsorbed from a water-ethanol mixture (1:2) containing 2 mM of pyrene when (C16)0.6GO was used. The isotherm of pyrene adsorption was better described by Freundlich equation rather than Langmuir equation, which indicated a single adsorption mechanism was involved. The change in the amount of adsorbed pyrene as a function of amine content in GO was very similar to that which occurs upon introduction of pyrene into (C16)xGO films from chloroform solution, as determined by X-ray measurements. This suggests that pyrene molecules were adsorbed not only on the outer surface but also within the interlayer space of the intercalation compound. Swelling of the intercalation compound by ethanol can render the interlayers more organophilic and make access to hexadecylamine molecules bonded to the graphite oxide layer easier for pyrene molecules, especially in (C16)xGOs with lower amine contents. 相似文献
95.
S. Watanabe S. Nakasato S. Hayano H. Kuwamura T. Nagai M. Negishi Y. Sasamoto H. Seino S. Shiraishi 《Journal of the American Oil Chemists' Society》1973,50(9):360-363
In this study known mixtures of four or five fatty acid methyl esters were analyzed collaboratively by gas chromatography
with flame ionization detectors. The experimental data was treated statistically to examine inter- and intralaboratory scattering.
More-over the effect of the use of correction factors was investigated. Even if only the specific analytical values that scattered
a little were chosen, the averages of such values did not always approach the actual values. In some laboratories a sort of
regularity was observed in the deviation of analytical values from real values throughout the analyses of four samples. The
application of correction factors to the analytical values obtained by these laboratories resulted in a considerable decrease
of interlaboratory scattering and deviation from the real values. When a constant amount of sample was injected, intralaboratory
scattering was decreased, whereas interlaboratory scattering was not. Injection of large sample sizes caused deviation. From
this collaborative study it was recommended that 0.5–1.0 μl of 20% solution be injected.
Presented at the JOCS-AOCS Joint Meeting, Los Angeles, April 1972. 相似文献
96.
Functionally graded materials (FGMs) belong to a relatively new class of inhomogeneous composite materials, in which the composition
and/or microstructure undergo a gradual change along some directions. In this review article, the microstructures and composition
gradients in Al/SiC, Al/Shirasu (volcanic eruptions commonly found in south Kyushu in Japan), Al/Al3Ti, Al/Al3Ni, Al/Al2Cu FGMs have been investigated. The Al/SiC, Al/Shirasu and Al/Al3Ti FGMs are fabricated by the centrifugal solid particle method where the distribution particles of SiC, Shirasu and Al3Ti are solids in the melts. On the other hand, Al/Al3Ni and Al/Al2Cu FGMs are fabricated by the centrifugalin-situ method where Al/Al3Ni and Al/Al2Cu systems have lower liquidus temperatures than the processing temperatures. The feature of Al/(Al3Ti−Al3Ni) hydrid FGM, which is fabricated by a method combining both the centrifugal solid-particle andin-situ methods, is also shown. 相似文献
97.
Masamitsu Watanabe Etsuko Toyoda Toshihiro Ichino Yasuhiro Higashi 《Corrosion Science》2007,49(2):766-780
Copper plates were exposed under sheltered outdoor conditions for up to one year, starting in September 2001 in Musashino City, Tokyo, a suburban area. Following various periods of exposure, the patinas on the plates were characterized to investigate their evolution by using X-ray fluorescence analysis, X-ray diffraction, field emission scanning electron microscopy, and glow discharge optical emission spectroscopy. The difference in the roles of sulfur and chlorine in the early stages of copper patination were identified by analyzing the depth profiles of these two elements. Sulfur was found on top of the patina as cupric sulfates such as posnjakite (Cu4SO4(OH)6 · H2O) or brochantite (Cu4SO4(OH)6). Brochantite appeared only after 12 months of exposure. In contrast, chlorine was found on the surface after only one month of exposure. It gradually penetrated the patina as the exposure period lengthened, forming copper chloride complexes. Chloride ions accumulated at the patina/copper interface, forming nantokite (CuCl), which promoted corrosion. 相似文献
98.
We analyzed the copper corrosion products that formed during a month in summer and a month in winter at three sites in Tokyo using several analytical techniques. The X-ray diffraction patterns revealed that cuprite Cu2O and posnjakite Cu4SO4(OH)6·H2O formed on copper exposed in summer. By contrast, only cuprite was found in winter exposed copper. The X-ray fluorescence results indicated that the amounts of sulfur and chlorine on the copper plates exposed in summer were much greater than those in winter. This could be explained by the change in particulate sulfate and sea salt concentrations. Depth profiling analysis by Auger electron spectroscopy revealed that the oxide layer formed in summer was thicker than that in winter. This difference in oxide layer thickness could have been due to the differences in temperature, relative humidity, and the amount of sulfur and chlorine on the copper plate. 相似文献
99.
Sun-Chan Jeong Ichiro Katayama Hirokane Kawakami Yutaka Watanabe Hironobu Ishiyama Nobuaki Imai Yoshikazu Hirayama Hiroari Miyatake Masao Sataka Satoru Okayasu Hiroyuki Sugai Shin-Ichi Ichikawa Katsuhisa Nishio Shinichi Mitsuoka Takamitsu Nakanoya Masahito Yahagi Takanori Hashimoto Kazunori Takada Mamoru Watanabe Tomoko Ishikawa Akihiro Iwase 《Journal of Phase Equilibria and Diffusion》2005,26(5):472-476
For the effective use of short-lived radioactive beams, soon to be available at the Tokai Radioactive Ion Accelerator Complex, the authors have developed a radiotracer method for diffusion studies in solids. The experimental test was performed by the measurement of the diffusion coefficients of Li in a sample of the compound βLiAl using an α-emitting radiotracer of 8Li (T1/2=0.84 s). It was found that the time-dependent yields of the α particles from the diffusing 8Li that was initially implanted in the sample could be used as a measure of the diffusivity of the tracer in a nondestructive way. The method was applied to measure the self-diffusion coefficients of Li in βLiGa, and for investigating how the Li diffusion in the Li ionic conductors is affected by the concentration of atomic defects (i.e., the existence of the atomic vacancies of Li and the defects in Ga sites that are replaced by Li). 相似文献
100.
Naoji Shiroma Ryo Miyauchi Akira Nagafusa Youhei Haga Fumitoshi Matsuno 《Advanced Robotics》2015,29(3):149-163
In robot teleoperation, a robot works as a physical agent at a remote site for a robot operator. There are mainly two tasks in robot teleoperation using camera images: environment recognition using visual information and robot control according to the recognition. In this paper, we propose a gaze direction based vehicle teleoperation method with an omnidirectional image stabilization and an automatic body rotation control. In the proposed method, we manage above two tasks in the same manner that are usually treated separately. This method is an intuitive vehicle teleoperation method where an operator do not need to have concern about vehicle body orientations and can absorb differences of vehicle driving mechanisms. That is, this method frees an operator from being bothered from controlling a vehicle and the operator can concentrate on where he/she intends to go. This method mainly consists of two technologies: an omnidirectional image stabilization technology and automatic body rotation control. The conducted experiments show effectiveness of the proposed method. 相似文献