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81.
Marcela Trybula Tomasz Gancarz Wladyslaw Gasior Alain Pasturel 《Metallurgical and Materials Transactions A》2014,45(12):5517-5530
Physicochemical properties like density, surface tension, and viscosity of liquid binary Al-Li and Li-Zn alloys have been measured using draining crucible method. The experimentally measured surface-tension values have been compared to theoretical results based either on the Butler model or the compound formation model assuming the existence of the most favored A 1 B 2 and A 2 B 3 clusters. Several models for viscosity calculation have been also applied and discussed in confrontation with measured data. Finally, the clustering effects in the liquid Al-Li and Li-Zn alloys have been examined using two microscopic functions, i.e., the concentration fluctuation function in the long-wavelength limit and the Warren-Cowley short-range order parameter. 相似文献
82.
Maxim Stolyarchuk Julie Ledoux Elodie Maignant Alain Trouv Luba Tchertanov 《International journal of molecular sciences》2021,22(2)
Redox (reduction–oxidation) reactions control many important biological processes in all organisms, both prokaryotes and eukaryotes. This reaction is usually accomplished by canonical disulphide-based pathways involving a donor enzyme that reduces the oxidised cysteine residues of a target protein, resulting in the cleavage of its disulphide bonds. Focusing on human vitamin K epoxide reductase (hVKORC1) as a target and on four redoxins (protein disulphide isomerase (PDI), endoplasmic reticulum oxidoreductase (ERp18), thioredoxin-related transmembrane protein 1 (Tmx1) and thioredoxin-related transmembrane protein 4 (Tmx4)) as the most probable reducers of VKORC1, a comparative in-silico analysis that concentrates on the similarity and divergence of redoxins in their sequence, secondary and tertiary structure, dynamics, intraprotein interactions and composition of the surface exposed to the target is provided. Similarly, hVKORC1 is analysed in its native state, where two pairs of cysteine residues are covalently linked, forming two disulphide bridges, as a target for Trx-fold proteins. Such analysis is used to derive the putative recognition/binding sites on each isolated protein, and PDI is suggested as the most probable hVKORC1 partner. By probing the alternative orientation of PDI with respect to hVKORC1, the functionally related noncovalent complex formed by hVKORC1 and PDI was found, which is proposed to be a first precursor to probe thiol–disulphide exchange reactions between PDI and hVKORC1. 相似文献
83.
Olivier Quéméner Frédéric Joly Alain Neveu 《International Journal of Heat and Mass Transfer》2012,55(4):1197-1207
In this paper, we propose an extension of the amalgam method to reduce advection diffusion problem with time dependent parameters. From a full general basis, this technique consists to select rapidly the most influent modes, and to add to them the remaining modes balanced by a coefficient. The originality of this paper lies in the fast obtention of a full degraded model, used as a reference in a minimization process of the reduced model’s error. Transcribed to the physical space, this error approaches the error between the reduced model and the real physical finite elements model. The treated application is a disk rotating at a variable velocity with time dependent thermal inputs. Comparison between the reduced and the finite elements model gives a gain in term of computational time of 36 for a mean error on the entire domain equal to 0.42%. 相似文献
84.
Thomas Schareina Xiao-Feng Wu Alexander Zapf Alain Cotté Matthias Gotta Matthias Beller 《Topics in Catalysis》2012,55(7-10):426-431
The first copper-catalyzed trifluoromethylation of aryl halides was developed that utilizes inexpensive trifluoroacetates. Providing low concentrations of the most economically attractive and atom-efficient trifluoromethylation reagent this new protocol is advantageous compared to known procedures both economically and ecologically. 相似文献
85.
86.
Isabelle Moretti Alain Prinzhofer João Françolin Cleuton Pacheco Maria Rosanne Fabian Rupin Jan Mertens 《International Journal of Hydrogen Energy》2021,46(5):3615-3628
In many basins, hydrogen-emitting structures are now observed, but the estimation of the H2 flow leading to their formation remains poorly constrained since all data show that the H2 emissions are variable in space and time. We present here the data of a long-term monitoring campaign with a high density of permanent hydrogen detectors installed in 2 structures in the Minas Gerais State (Brazil). Results show that two kinds of signals are recorded, large sporadic pulses that affect the H2 content of the soil for one or two days and smaller ones, with a daily periodicity, that last 6 h and during which the near surface soil concentration usually does not exceed 200 ppm. This last signal is very regular in frequency, less in amount, and the daily maximum happens around noon or in the early afternoon. We interpret the large pulses as evidences of a deep hydrogen flux, leaking either from a reservoir located in the subsurface, from an aquifer which is degassing or, although it seems unlikely, directly from the H2 generation area.The time correlation between the pulse and the increase of the daily signal suggests that this last one corresponds to the slow release of the gas that has been captured by the soil during its transport towards the surface. This daily signal is most likely influenced by external factors such as atmospheric pressure and sub-surface bacterial activity. In map view, the lack of correlation between the highest hydrogen concentrations over time suggests that the soil is very heterogeneous and that preferential pathways exist. The results confirm that long-term monitoring, over a few months, is mandatory to catch a certain number of high pulses and so to have a better estimation of the real flow. Data also suggests that sensors with a large concentration range should be used (from 10 to several 104 ppm). Even if quantification of leakage doesn't help to quantify the subsurface reserves, these new data allow a more precise evaluation of the quantity of H2 released in surface by these structures, few hundred of kilo per day, and confirm the high H2 prospectivity of this basin. 相似文献
87.
A two‐step synthetic procedure is designed for preparing new flame‐retardant methacrylic monomers containing 9,10‐dihydro‐9‐oxa‐10‐phosphaphenanthrene‐10‐oxide (DOPO) as a substituent side group. DOPO and methacrylate moieties are linked by linear aliphatic hydrocarbon spacers (3 to 11 carbon atoms). Copolymerization with methyl methacrylate is carried out leading to copolymers containing between 2 and 10 wt% phosphorus. All homo‐ and copolymers exhibit a unique glass transition temperature (Tg ). A new group contribution for DOPO‐based substituent is extracted that leads to reasonable estimations of Tg s of other published polymers. The Fox equation provides a good estimation of Tg s for most copolymers and for physical blends of poly(methyl methacrylate) (PMMA) and DOPO. When using monomers having three and four carbon atoms in the hydrocarbon spacer, the Tg of copolymers remains close to that of PMMA over a wide range of composition. 相似文献
88.
89.
The present paper is concerned with the design of adaptable automation. It analyses the aggregated data from five experiments (N = 154) to examine which automation levels operators prefer, how often they switch between them, and whether performance is associated with frequent switching or the automation levels being used. Using wide-choice adaptable automation (i.e. up to six levels were offered), the experiments were conducted using a PC-based simulation of a complex work environment. The results showed that about 95% of operators had a clearly preferred automation level, which they used for more than 50% of the time. They strongly preferred intermediate automation levels over levels at the higher and lower ends of the scale. Most operators switched rarely between levels and when they did, they usually made small adjustment rather than large changes. Several implications for the design of adaptable automation were derived from the empirical data. 相似文献
90.