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排序方式: 共有10000条查询结果,搜索用时 78 毫秒
971.
Detection of Glutamate and Acetylcholine with Organic Electrochemical Transistors Based on Conducting Polymer/Platinum Nanoparticle Composites 下载免费PDF全文
972.
Biodegradable Ethylene‐Bis(Propyl)Disulfide‐Based Periodic Mesoporous Organosilica Nanorods and Nanospheres for Efficient In‐Vitro Drug Delivery 下载免费PDF全文
973.
Signatures of a Two‐Dimensional Ferromagnetic Electron Gas at the La0.7Sr0.3MnO3/SrTiO3 Interface Arising From Orbital Reconstruction 下载免费PDF全文
974.
975.
Effects of UV exclusion on the physiology and phenolic composition of leaves and berries of Vitis vinifera cv. Graciano 下载免费PDF全文
976.
Experiments were carried out in a system with BOF slags from industrial operations in order to optimize the conditions of recycling BOF slags produced in the steelmaking process. Reduction reactions of FeO and P2O5 proceeded steadily and the FeO reduction rate was almost identical to that of P2O5. The reduction reaction of FeO and P2O5 in BOF slag at the slag/gas interface is the rate‐controlling step. The reaction rates of FeO and P2O5 by dissolved carbon in molten iron are of first order with respect to their respective concentrations. The reduction reactions of FeO and P2O5 by dissolved carbon in iron are much closer to the equilibrium state compared with the reduction by solid carbon. It is necessary to control the portion of phosphorus vaporization during reduction treatment in order to obtain efficient operational conditions for BOF slag reduction. 相似文献
977.
Pretreatment of high manganese hot metal is suggested to produce hot metal suitable for further processing to steel in conventional LD converter and rich manganese slags satisfy the requirements for the production of silicomanganese alloys. Manganese distribution between slag and iron represents the efficiency of manganese oxidation from hot metal. The present study has been done to investigate the effect of temperature, slag basicity and composition of oxidizer mixture on the distribution coefficient of manganese between slag and iron. Ferrous oxide activity was determined in molten synthetic slag mixtures of FeO‐MnO‐SiO2–CaO–MgO‐Al2O3. The investigated slags had chemical compositions similar to either oxidizer mixture or slags expected to result from the treatment of high manganese hot metal. The technique used to measure the ferrous oxide activity in the investigated slag systems was the well established one of gas‐slag‐metal equilibration in which molten slags contained in armco iron crucibles are exposed to a flowing gas mixture with a known oxygen potential until equilibrium has been attained. After equilibration, the final chemical analysis of the slags gave compositions having a particular ferrous oxide activity corresponding to the oxygen potential of the gas mixture. The determined values of ferrous oxide activity were used to calculate the equilibrium distribution of manganese between slag and iron. Higher manganese distribution between slag and iron was found to be obtained by using oxidizer containing high active iron oxide under acidic slag and relatively low temperature of about 1350°C. 相似文献
978.
Christian Exner Andreas Pfaltz Martin Studer Hans‐Ulrich Blaser 《Advanced Synthesis \u0026amp; Catalysis》2003,345(11):1253-1260
A systematic structure‐selectivity study was carried out for the enantioselective hydrogenation of activated ketones with chirally modified Pt/Al2O3 catalysts. For this, 18 modifiers containing an extended aromatic system able to form a strong adsorption complex with the Pt surface, and a suitable chiral group with an amino function capable to interact with the keto group of the substrate ( HCd, Qd, HCn, Qn , and semi‐synthetic derivatives, as well as synthetic analogues) were prepared and tested on 8 different activated ketones in AcOH and toluene under standard conditions. It was found that relatively small structural changes of the substrate and/or modifier structures strongly affected the enantioselectivity, and that no “best” modifier exists for all substrates. The highest ees for all substrates were obtained with quinuclidine‐derived modifiers in combination with naphthalene or quinoline rings, either in AcOH (substrates 1 – 5 and 8 , all carrying an sp3 carbon next to the keto group) or toluene ( 6 and 7 , with an sp2 carbon next to the ketone). The presence and nature of the substituent R' at the quinuclidine significantly affected the ee (positive and negative effects). Certain combinations of an aromatic system and an amino function were preferred: For the quinuclidine moiety, quinoline and to a somewhat lesser extent naphthalene were a better match, while for the pyrrolidinylmethyl group anthracene was better suited. Methylation of the OH group often had a positive effect for hydrogenations in AcOH but not in toluene. With the exception of 8 , higher ees were obtained for the Cd / Qn series [leading to (R)‐products] than for the Cn / Qd series [leading to (S)‐products]. In several cases, opposite structure‐selectivity trends were detected when comparing reactions in toluene and AcOH, indicating a significant influence of the solvent. 相似文献
979.
Rong‐Qun Li Da‐Ying Dou Jin‐Ling Miao Wen‐Feng Wang Si‐De Yao Han‐Min Zeng 《应用聚合物科学杂志》2002,86(9):2217-2221
The resistivity of different polymer composites is investigated in different temperature‐changing processes, which demonstrates more complicated changing behaviors than that usually reported in literatures. The complicated resistivity‐temperature (R‐T) behaviors cannot be explained by current theories, and the contradictions of them with current theories are presented in this article. With the experiments, a new viewpoint on the R‐T behaviors of polymer composites is proposed, i.e., the resistivity changes are attributed to internal stress generated when the morphology and structure of the composites undergo great changes. Based on this speculation, the complicated R‐T behaviors of polymer composites can be well explained. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 2217–2221, 2002 相似文献
980.