Interlaboratory ring test of time-resolved fluoroimmunoassays for zeranol and alpha-zearalenol and comparison with zeranol test kits.

Many zeranol immunoassay test kits cross-react with toxins formed by naturally occurring Fusarium spp. fungi, leading to false-positive screening results. This paper describes the evaluation and application of recently published, dry reagent time-resolved fluoroimmunoassays (TR-FIA) for zeranol and the toxin alpha-zearalenol. A ring test of bovine urine fortified with zeranol and/or alpha-zearalenol in four European Union National Reference Laboratories demonstrated that the TR-FIA tests were accurate and robust. The alpha-zearalenol TR-FIA satisfactorily quantified alpha-zearalenol in urine fortified at 10-30 ng ml(-1). The specificity-enhanced zeranol TR-FIA accurately quantified zeranol in the range 2-5 ng ml(-1) and gave no false-positive results in blank urine, even in the presence of 30 ng ml(-1) alpha-zearalenol. Zeranol TR-FIA specificity was demonstrated further by analysing incurred zeranol-free urine samples containing natural Fusarium spp. toxins. The TR-FIA yielded no false-positive results in the presence of up to 22 ng ml(-1) toxins. The performance of four commercially available zeranol immunoassay test kits was more variable. Three kits produced many false-positive results. One kit produced only one potential false-positive using a protocol that was longer than that of the TR-FIA. These TR-FIAs will be valuable tools to develop inspection criteria to distinguish illegal zeranol abuse from contamination arising from in vivo metabolism of Fusarium spp. toxins.     

Thin-film nickel coatings on fiber materials

Vacuum deposition of thin films onto fiber materials is a promising method of obtaining electromagnetic screens. We have studied the structure and the electromagnetic properties of machine-knitted fabric coated with nickel by means of magnetron sputtering. When the fabric is irradiated from the metal-coated side, the reflection coefficient is higher by a factor of 1.4 as compared to the case when the same source of electromagnetic radiation is situated on the opposite side (facing the uncoated surface), while the absorption coefficient in both cases is the same.     

On the prospects of developing high-efficiency piezocomposites based on crystals of solid solutions of ferroelectric relaxors

Electromechanical properties of the 0-0-2-2 type composite based on platelike crystals of solid solutions of ferroelectric relaxors of the Pb(A_1/3Nb_2/3)O₃-PbTiO₃ system (A = Zn, Mg) have been studied for the first time. Factors accounting for the record values of some effective parameters of this composite are considered. The relationship between the components of the elastic compliance tensor of the layered structures forming the composite and the positions of maxima of the effective hydrostatic parameters is established.     

Nanostructural crack arrest

The problem of brittle crack development in a nanocrystalline material has been theoretically studied. Expressions describing the conditions of crack stability are obtained.     

The optimum characteristics of a halogen lamp pumped by transverse RF discharge

We report on the optimized characteristics of a small-size bactericidal lamp pumped by transverse RF (f=1.76 MHz) discharge, operating on a system of the molecular emission bands of chlorine in a wavelength range of 195–310 nm. The spectral characteristics of the plasma emission were measured and the intensity of chlorine emission bands were studied as functions of the total pressure and partial composition of a helium-chlorine mixture. Oscillograms of the pumping current and output radiation intensity were measured and the total output radiation power was determined. It is established that the lamp radiates predominantly in a bactericidal wavelength interval on an electron-vibrational transition at 200 nm in Cl₂** molecules. The optimum partial pressures of helium and chlorine are 100–300 and 90–120 Pa, respectively. The maximum output power of UV emission from the side cylindrical surface of the lamp reached 10 W. The lamp can be used in photochemistry, ecology, genetics, and medicine.     

Surface Films on Zinc-Plated Steel Formed on Holding in Aqueous Extracts of Anticorrosion Pigments

The methods of X-ray photoelectron spectroscopy and Auger spectroscopy are used to study surface films formed on zinc and zinc-plated steel in the process of holding in aqueous extracts of mixtures of phosphate and calcium-containing pigments. It is shown that protective films formed mainly of zinc and calcium phosphates of different chemical structure are deposited in inhibited solutions on specimens of pure zinc and zinc-plated steel. The protective properties of these films are much better than the protective properties of the surface layers formed on the metal in the extracts of a single phosphate (or calcium-containing) pigment. The mixture of these pigments may serve as a promising substitution of chromate inhibitors in anticorrosive organic coatings.     

Interaction of NbVNi with Hydrogen

The interaction of NbVNi with hydrogen is studied over wide pressure and temperature ranges. Hydrogen absorption–desorption isotherms are measured, and the compositions of the resulting hydride phases are determined. X-ray diffraction analysis demonstrates that the incorporation of hydrogen into NbVNi leads to an isotropic expansion of its crystal lattice.