全文获取类型
收费全文 | 78篇 |
免费 | 2篇 |
专业分类
电工技术 | 1篇 |
化学工业 | 26篇 |
金属工艺 | 2篇 |
轻工业 | 8篇 |
无线电 | 6篇 |
一般工业技术 | 29篇 |
冶金工业 | 1篇 |
自动化技术 | 7篇 |
出版年
2022年 | 2篇 |
2021年 | 5篇 |
2019年 | 1篇 |
2018年 | 3篇 |
2017年 | 1篇 |
2016年 | 3篇 |
2015年 | 4篇 |
2014年 | 1篇 |
2013年 | 5篇 |
2012年 | 9篇 |
2011年 | 6篇 |
2010年 | 6篇 |
2009年 | 2篇 |
2008年 | 10篇 |
2007年 | 7篇 |
2006年 | 5篇 |
2005年 | 1篇 |
2004年 | 1篇 |
2002年 | 2篇 |
2001年 | 2篇 |
2000年 | 1篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1989年 | 1篇 |
排序方式: 共有80条查询结果,搜索用时 15 毫秒
51.
Frantisek Bozek Ales Komar Jiri Dvorak Jaroslav Obermajer 《Clean Technologies and Environmental Policy》2010,12(1):9-18
The paper deals with the elimination of highly toxic and persistent relict burdens caused by polychlorinated dibenzo-p-dioxins, dibenzofurans, biphenyls, hexachlorobenzene, γ-isomer of hexachlorocyclohexane and other organic halogen derivatives.
The technology is used in eliminating the aforementioned contaminants from soil, rubble and metal parts of former machinery
with the use of best available techniques. Such a technology has been implemented in the northern part of the town of Neratovice
and the Spolana company, plc, which formerly used to be a significant producer of pesticides in the Czech Republic. 相似文献
52.
A novel electrospray ionization (ESI) mass spectrometric approach for the structure elucidation of ionic organotin(IV) compounds or complexes with weakly bonded ligands as for example monodentate carboxylates or sulfonates is proposed using both positive-ion and negative-ion ESI tandem mass spectra. The ionization mechanism of organotin(IV) compounds involves the cleavage of the most labile bond with an ionic character yielding two complementary ions, [Cat]+ and [An]-. Positively charged species containing tin atom, [Cat]+, are analyzed in the positive-ion mode and negatively charged species without the tin atom, [An]-, in the negative-ion mode. Fragmentation patterns of [C24H29N2Sn]+, [C21H22NSn]+, and [C17H30NSn]+ ions are proposed based on the detailed interpretation of MSn spectra, which is simplified by an easy recognition of characteristic tin isotopic clusters in particular fragment ions. Proposed fragmentation mechanisms are supported by comparison with MSn spectra of deuterium-labeled analogues. The applicability of this method is illustrated on two sets of organotin(IV) compounds, including seven [2,6-bis(dimethylaminomethyl)phenyl]diphenyltin(IV) derivatives with small inorganic counteranions X (Br, NO3, SCN, BF4, SeCN, CN, PF6), six organotin(IV) complexes containing two C,N-chelating ligands with azo dyes, and the identification of unknown hydrolysis products. 相似文献
53.
Rade Injac Ales Mlinaric Vukosava Djorjevic-Milic Katarina Karljikovic-Rajic Borut Strukelj 《Food Additives & Contaminants》2008,25(4):424-431
A separation technique for zinc bacitracin, polymyxin B, oxytetracycline and sulfacetamide in animal feedstuffs by micellar electrokinetic capillary chromatography (MEKC) was developed. The running buffer was 20 mmol l-1 borate, 20 mmol l-1 phosphate, pH 8.4, containing 20 mmol l-1 sodium dodecylsulphate and 10% (v/v) methanol. MEKC was performed at 25°C; the applied voltage was 25 kV with a running pressure of 10 mbar. Simultaneous UV detection for all analytes was at 215 nm. The method was validated for specificity, accuracy, linearity, precision and robustness. It was shown to be specific, accurate (recoveries were 99.7 ± 0.3, 99.9 ± 0.9, 99.8 ± 1.0 and 99.5 ± 0.4, respectively, for oxytetracycline-, sulfacetamide-, polymyxin B- and zinc bacitracin-spiked samples of feed for cow, pigs, chicken and cattle), linear over the tested range (correlation coefficients ≥0.9987) and precise (RSDs below 1.8% for each analyte). The method was applied to determine zinc bacitracin, polymyxin B, oxytetracycline and sulfacetamide as additives in animal feed. 相似文献
54.
55.
Jana Machotova Lucie Zarybnicka Adela Ruckerova Radka Bacovska Jozef Rychly Ales Imramovsky 《Polymer-Plastics Technology and Engineering》2017,56(5):563-571
The paper deals with a novel flame retardant and its application in waterborne coatings. The flame retardant was synthesized from hexachloro-cyclo-triphosphazene by nucleophilic substitution with allylamine. Functionalized emulsion copolymers bearing in the structure hexaallylamino-cyclo-triphosphazene were prepared by the semicontinuous emulsion polymerization. The latexes were used as the main component of transparent coating systems cured by melamine formaldehyde resin. The incorporation hexaallylamino-cyclo-triphosphazene did not affect transparency, flexibility, and toughness of resulting coatings and increased their flame stability in terms of the amount of smoke release and maximum average rate of heat emission indicating a slower flame spread during the material combustion. 相似文献
56.
The in vitro antifungal activity of compounds 1-3 ({[(CH3)2NCH2]2C6H3}R2SnX; (where X=Cl, R=n-Bu for 1, X=Br, R=n-Bu for 2 and x=PF6, R=n=Bu for 3)) was estimated with the help of a modified microdilution format of the M27-A guidelines and was compared with in vitro activity of their diphenyltin(IV) analogues 4 and 5 (where X=Br, R=Ph for 4 and X=PF6, R=Ph for 5), and of drugs currently in clinical use (ketoconazole, fluconazole and amphotericin B). It was found that in coordinating solvents the more soluble derivative 2 is less active than the phenyl one (4), and compounds 1 and 3 are even inactive.In this paper, the in vitro antitumour activity of ionic diphenyltin(IV) complexes 4 and 5 against seven tumoural cell lines of human origin is also reported. The preparation and characterization (H1, C13 and Sn119 NMR spectroscopy and electrospray ionization mass spectrometry) of the novel compound 3 is mentioned too. 相似文献
57.
The sources of gamma radiation inside buildings affected by earlier silver and uranium mining activities are discussed. Possibilities how to reduce gamma dose rates from building materials were studied on several houses located in the old mining town Jáchymov. Results of the efficiency analysis are presented. Experience obtained up to now indicates that it is almost impossible to reduce the gamma dose rates in such buildings to the level corresponding with the natural background, because some of the gamma radiation sources cannot be completely removed from the building structures. 相似文献
58.
alpha,beta-unsaturated aldehydes are toxic products of lipid peroxidation. Detection and characterization of these aldehydes is important in many human disease states as well as in the food industry. Our study shows that electron ionization-mass spectrometry (EI-MS) and positive-ion chemical ionization-mass spectrometry (PICI-MS), but not electron capture negative ionization-mass spectrometry (ECNI-MS), can be used to detect the C4-hydroxylation state of alpha,beta-unsaturated aldehydes derivatized with pentafluorobenzyl hydroxylamine alone. EI-MS and PICI-MS spectra of 4-hydroxy-2-alkenals contained a fragment with m/z 252, whereas spectra of 2-alkenals contained a fragment with m/z 250. These fragments are consistent with fragmentation between C3 and C4 with transfer of two hydrogens from C4 and the C4 hydroxyl group in the case of 4-hydroxy-2-alkenals. In addition, EI-MS and PICI-MS were able to distinguish 4-hydroxy-2-alkenals and 2-alkenals from 4-keto-2-alkenals and 4-hydroxyalkanals. On the other hand, ECNI-MS provided complex spectra regarding C4-hydroxylation state. Furthermore, the syn- and anti-configurations of PFB-oximes had different resultant spectra using ECNI-MS, but not with EI-MS or PICI-MS. These data indicate that EI-MS and PICI-MS are more amenable for structural analysis of alpha,beta-unsaturated aldehydes than ECNI-MS. 相似文献
59.
Ploscaru MI Kokalj SJ Uplaznik M Vengust D Turk D Mrzel A Mihailovic D 《Nano letters》2007,7(6):1445-1448
We report on a new highly reproducible route to recognitive self-assembly of molecular-scale circuits using sulfur-terminated subnanometer diameter Mo6S9-xIx (MoSIx) molecular nanowires. We demonstrate solution-processed attachment of MoSIx connecting leads to gold nanoparticles (GNPs). We also show that naked nanowires have the potential to bind thiolated proteins such as green fluorescent protein directly, thus providing a universal construct to which almost any protein could be attached. We further demonstrate three-terminal branched circuits with GNPs, opening a self-assembly route to multiscale complex molecular-scale architectures at the single-molecule level. 相似文献
60.
Chromatin-based processes are essential for cellular functions. Structural maintenance of chromosomes (SMCs) are evolutionarily conserved molecular machines that organize chromosomes throughout the cell cycle, mediate chromosome compaction, promote DNA repair, or control sister chromatid attachment. The SMC5/6 complex is known for its pivotal role during the maintenance of genome stability. However, a dozen recent plant studies expanded the repertoire of SMC5/6 complex functions to the entire plant sexual reproductive phase. The SMC5/6 complex is essential in meiosis, where its activity must be precisely regulated to allow for normal meiocyte development. Initially, it is attenuated by the recombinase RAD51 to allow for efficient strand invasion by the meiosis-specific recombinase DMC1. At later stages, it is essential for the normal ratio of interfering and non-interfering crossovers, detoxifying aberrant joint molecules, preventing chromosome fragmentation, and ensuring normal chromosome/sister chromatid segregation. The latter meiotic defects lead to the production of diploid male gametes in Arabidopsis SMC5/6 complex mutants, increased seed abortion, and production of triploid offspring. The SMC5/6 complex is directly involved in controlling normal embryo and endosperm cell divisions, and pioneer studies show that the SMC5/6 complex is also important for seed development and normal plant growth in cereals. 相似文献