Impact of sand and filler materials on the hydration behavior of calcium aluminate cement

In earlier work, we have observed discrepancies relating to the early hydration of calcium aluminate cement (CAC) when comparing data from heat flow calorimetry of CAC paste with results from mortar strength tests using the crushing method. Here, we investigated on this phenomenon and found that the sand which is used as a filler exerts a major influence on CAC hydration resulting in acceleration. Furthermore, in particular fine filler materials such as, for example, microsilica, fine limestone powder, and especially α- and γ-Al₂O₃ also produced a strong hydration accelerating effect which is dependent on their specific surface area. The mechanism underlying the acceleration is that under alkaline conditions their negative surface charge attracts calcium ions as was confirmed via inductively coupled plasma atomic emission measurements. Such a layer generates favourable conditions for the nucleation of CAC hydration products (C-A-H phases). The resulting crystalline hydrates which form on the surface of the filler particles submerged in CAC cement pore solution were visualized via SEM imaging. This way, specifically selected fillers can significantly accelerate CAC hydration and save precious lithium salts which are commonly used to boost the early strength of CAC.     

Low-temperature phase formation in the SrF2–LaF3 system

Phase formation in the SrF₂–LaF₃ system was studied at temperatures ranging from 300°C to 450°C using nitrate flux. The solubility of LaF₃ in SrF₂ decreases with decreasing temperature. The equilibrium width of the solid solution region Sr_1−xLa_xF_2+x at 400°C, it is 44.6 ± 0.4 mol% LaF₃ (x = 0.446), at 350°C — 38.3 ± 0.7 mol% LaF₃ (x = 0.383), and decreases almost to zero at 300°C.     

A New Research Infrastructure for Investigating Flow Hydraulics and Process Equipment at Critical Fluid Properties

An optimized equipment design for natural gas processing and liquefaction plants becomes increasingly difficult with changing process conditions: Particularly low values of surface tension create rising challenges on the design of phase separators and column internals. The TERESA test rig at HZDR was designed to allow the investigation of multiphase thermohydraulics and phase separator performance under critical fluid properties in industrial dimensions. A versatile pipe test section is available in DN200 and equipment internals may be tested in a sectional DN300/DN500 test separator. The applied test fluid shows a high vapor-liquid density difference between 1470 and 940 kg m⁻³, viscosity as low as 0.12 mm²s⁻¹, and surface tension down to 1.3 mN m⁻¹. Volumetric liquid and vapor flow rates may be varied up to 9 and 530 m³h⁻¹ in the test rig, respectively.     

Synthesis of amphiphilic (meth)acrylates with oligo(ethylene glycol) and (or) oligo(propylene glycol) blocks by the esterification of (meth)acrylic acid

Thermoresponsive PEG-based (PEG stands polyethylene glycol) polymers are unique for use in medicine because of their low toxicity, good biocompatibility and biodegradability, but usually more hydrophobic and more toxic comonomers are used to adjust lower critical solution temperature (LCST). A convenient way to overcome this problem and to finely tune LCST is to use alkoxy oligo(ethylene glycol)- or alkoxy oligo(propylene glycol) (meth)acrylates as starting comonomers. Here we report on the conditions for the simple and affordable synthesis of methoxy oligo(propylene glycol) (meth)acrylate- and methoxy oligo(propylene glycol)-block-oligo(ethylene glycol) (meth)acrylate-based macromonomers with high yields (80%–98.7%) by the acid-catalyzed esterification of (meth)acrylic acid with alkoxy oligo(alkylene glycols) containing oligo(ethylene glycol) (OEG) and/or oligo(propylene glycol) (OPG) blocks. p-Toluene sulphonic acid (pTSA), alkyl(C₁₂–C₁₄)benzene sulfonic acid (ABSA) and H₂SO₄ were used as catalysts. It has been shown that pTSA and ABSA are practically the same in catalytic activity and are superior to sulfuric acid. The reaction orders with respect to catalyst was found to be close to 1 in all cases. It has been shown that the reaction is actually insensitive to the lengths of OEG and OPG blocks, as well as to the structure of the terminal alkyl group, while the esterification of acrylic acid (AA) proceeds much faster compared to methacrylic acid (MAA) one under the same conditions. The influence of temperature on the equilibrium conversions of alcohols was determined, which were found to be 89%–93% for the esterification of AA and 61%–86% for MAA in the temperature range of 60–120°C. A further increase in conversion was achieved by introducing an azeotropic agent (toluene), its optimal concentration was found to be 10%–15%.     

Magnetization reversal of a double-layer exchange-coupled ferromagnetic film

A theoretical investigation of magnetization reversal of a double-layer magnetic film with an easy-plane and easy-axis anisotropy has been performed. An analytical expression for the magnetization distribution in the layers in the presence of a magnetic field has been obtained. The calculations performed on the basis of the analytical relationships obtained show that when the thickness of the layers is close to the width of a magnetic inhomogeneity, it substantially affects the magnitude of the critical field for the magnetization reversal of the sample and the shape of the magnetization curve. It is also shown that a decrease in the exchange coupling between the layers leads to an increase in the magnitude of the critical field of magnetization reversal.     

Polishing and buffing: Theory and practice

There are many other aspects of buffing and polishing than these briefly discussed here. Though this very important contributor to the metal-finishing industry is still a great deal more an art than a science, basic engineering principles can be applied. With the proper melding of buff and compound, applied in a controlled fashion, optimum finish and maximum economy can be achieved.     

Knowledge and Belief: Some Clarifications

The notions of knowledge and belief play an important role in philosophy. Unfortunately, the literature is not very consistent about defining these notions. Is belief more fundamental than knowledge or is it the other way around? Many accounts rely on the widely accepted strategy of appealing to the intuition of the reader. Such an argumentative methodology is fundamentally flawed because it lets the problems of common sense reasoning in through the front door. Instead, I suggest that philosophical arguments should be based on formal-computational models to (a) reduce the ambiguities and uncertainties that come with intuitive arguments and reasoning, and (b) capture the dynamic nature of many philosophical concepts. I present a model of knowledge and belief that lends itself to being implemented on computers. Its purpose is to resolve terminological confusion in favor of a more transparent account. The position I defend is an antirealist naturalized one: knowledge is best conceived as arising from experience, and is fundamental to belief.     

Tethered space orientation via adaptive sliding mode

Here, we study the problem of a rotating tethered satellite system (TSS) orientation. The rotation TSS is used for propellantless delivery of the payload from low earth orbits to geostationary orbits or other transfer orbits. Driving the angular positions to correct desired orientation in rendezvous and tossing moments, in fact, is important operation in many real sceneries. We suggest the mathematical model describing the dynamics of TSS and catch mechanism/payload rendezvous with external disturbance terms. Here is shown that using sliding mode control (SMC), we are able to control successfully the position of TSS. The conventional and adaptive versions of SMC are considered. We show that SMC with the gain matrix adaptation based on the equivalent control method can significantly reduce the undesirable chattering effect provoking possible damages of TSS. Copyright © 2015 John Wiley & Sons, Ltd.