Unloading angular momentum for inertial actuators of a spacecraft in the pitch channel

The problem of gravitational unloading of the angular momentum of inertial actuators of a spacecraft in the pitch channel for circular and elliptic orbits is considered using the band theory of modal control. Control laws for gravitational unloading and stabilization of a given spacecraft position unambiguously determined by the object parameters and given coefficients of characteristic equation are obtained.     

Unexpected products of the allyldiethylamine hydroformylation homogeneously catalyzed by rhodium complexes

Attempts to carry out the hydroformylation of allyldiethylamine homogeneously catalyzed by rhodium complexes led to unexpected formation of N,N,N,N-tetraethyl-1,4-diaminobutane and 4-(diethylamino)-1-butanole as final products. The role of the catalyst on the product formation and the reaction mechanism are briefly discussed.     

On the Transition from a Model to a Real Solid in the Course of Photoelastic Simulation of Problems of the Mechanics of Orthotropic Solids

We propose a method for the recalculation of dynamic stresses from a photoelastic model to a real solid in plane problems of the mechanics of orthotropic bodies. To estimate the accuracy of the method, we recalculate stresses for a problem with known theoretical solution.     

Generalized Deformation Curve for High-Strength Steel over a Wide Range of Strain Rates

Test results for different high-strength steel specimens in static and impact tension and compression over a wide range of strain rates were summarized. These data were used to calculate the generalized deformation curve. The calculations based on this curve were compared with the experimental data on impact indentation with the conical indenter to evaluate the applicability of this method for studying the behavior of metals at high strain rates.     

Band formulas for calculating the numerator’s coefficients of the transfer function of a single-input system

Based on band matrices, a new formula for finding polynomial coefficients of the numerator of the transfer function for a linear single-input single-output system is derived. Its properties are studied for analyzing and synthesizing linear systems with many outputs, as a result of which a method is developed for the synthesis of the specified polynomial of zero dynamics (specified output) for a linear system with many outputs.     

Mechanochemical preparation of kaempferol intermolecular complexes for enhancing the solubility and bioavailability

Abstract

In this study, complexes of kaempferol (KF) with polysaccharide arabinogalactan (AG) and disodium glycyrrhizinate (Na₂GA) were prepared through mechanochemical technique to improve the solubility and bioavailability of KF. The physicochemical properties and the interactions of KF with AG/Na₂GA were investigated through dissolution, SEM, XRD, and DSC studies. The reduction of particle sizes and destruction of crystal forms revealed the formation of solid dispersion which may have assisted the dissolution of the drug. The accelerated stability study showed higher stability for KF–Na₂GA complex. In vivo pharmacokinetic study was performed to observe the plasma drug concentrations for KF complexes. Mechanochemical complexation of KF with AG/Na₂GA improved the pharmacological activity as evident by the inhibitory potential of the complexes towards carbohydrate metabolic enzymes. In vivo studies were performed in STZ-induced diabetic mice, where the group treated with KF–AG complex showed better liver and kidney function and lower blood glucose levels than pure KF. Therefore, mechanochemical complexes of KF with polysaccharide or glycyrrhizate may serve as a promising formulation for the treatment of diabetes.     

Effect of Acidic Peptization on Formation of Highly Photoactive TiO2 Films Prepared without Heat Treatment

Nowadays, it is a great challenge to synthesize crystalline TiO₂ nanostructures using low‐temperature methods without annealing stage. Such an approach allows to perform functional and structural modification in the formed crystalline phase by thermally unstable compounds, such as biomaterials, MOFs, dye sets in situ, which was previously considered impossible. In this work, we have developed and analyzed the effect of acidic peptization on formation of highly photoactive titania crystallites in an aqueous solution using titanium tetraisopropylate as a precursor. Acids with different dissociation degrees in water were used as peptizing mediators to determine the effect of protonation on sol formation. The dip‐coating films were obtained with consequent drying of the sols via evaporation of the solvent. The as‐prepared catalysts were characterized by X‐ray diffraction, AFM microscopy, UV–V is spectroscopy, Brunauer–Emmett–Teller surface area. The aggregate size of TiO₂ in the colloidal suspension solution was measured by dynamic light scattering. Photocatalytic activity of films was studied by decomposition of Rhodamine B dye. It is found that the size of colloids in an aqueous solution is proportional to the protonation degree of the surface of particles and does not depend on the [Ti⁴⁺]/[H⁺] ratio, and peptization under weakly acidic conditions leads to anisotropic rod‐like nanoparticles. The highest photocatalytic activity was exhibited by the TiO₂–HCl‐based coatings, ~3.5 times higher than that of the Acet.‐prepared sample.     

The structure of highly oriented high modulus polyethylene

A comparative study of the structure of uniaxially-oriented bulk samples of linear PE of various molecular weights over a wide range of draw ratios has been carried out by means of small and wide angle X-ray analysis, NMR-spectroscopy and DSC. The structure of oriented high molecular weight PE samples, prepared by drawing single crystal mats to draw ratios up to 200, have also been studied. A large number of unfolded tie-molecules have been found to exist in the trans-conformation in PE amorphous regions. These tie-molecules, which connect the adjacent crystallites along the axis of orientation, and are not large crystals, account for the high mechanical properties of these samples. It has been shown that in the course of the orientation process, chain unfolding in the amorphous regions is accompanied by the formation of continuous linear systems consisting of several coherent crystallites and tie-molecules. These are coherently aligned along the macromolecular axis.     

Phase diagram of the Li2SO4–Na2SO4 system

The thermal analysis and X-ray powder diffraction studies of the Li₂SO₄–Na₂SO₄ system, including the high-temperature X-ray diffraction technique, have elucidated four phases of variable composition: three solid solutions based on the α-Li₂SO₄, α-Na₂SO₄, and α-LiNaSO₄ high-temperature polymorphs, and a low-temperature β-LiNaSO₄ phase. α-Na₂SO₄-Base solid solution disintegrates into two phases via a monotectoid phase transformation. It is quite probable that the monotectoid process is related to the conversion of the second-order phase transition to the first-order phase transition.