Corrosion inhibition of copper in near neutral aqueous solutions by gamma-pyrodiphenone

The inhibition effect of gamma-pyrodiphenone (PD) on copper corrosion in near neutral sulphate solutions was investigated. Weight loss and polarization measurements show a high inhibition efficiency (>96%) of PD on copper corrosion at extremely low concentrations. PD suppresses active copper dissolution and oxygen reduction. The potentiodynamic cathodic reduction measurements showed an inhibition of oxide formation and stabilization of the Cu2O oxide in the presence of PD. XPS measurements suggested that the high inhibition effect of PD on copper corrosion is due to the adsorption of PD molecules, as a first stage, and the formation of a film with a polymer-like structure by coordination of PD with Cu2O on prolonged exposure.     

Cu2O/Cu Cermet as a Candidate Inert Anode for Al Production

Cu₂O/ x Cu ( x =0–25 wt%) cermets were evaluated as a novel partially inert anode for aluminum (Al) production. The physical and mechanical properties, including the compressive strength, flexural strength, thermal expansion coefficient, thermal conductivity, and dc electrical conductivity were tested at room temperature and at temperatures up to 950°C. The coefficient of thermal expansion, compressive strength, flexural strength, thermal conductivity, and electrical conductivity of Cu₂O/Cu cermets increased with increasing Cu content. High-temperature electrical conductivity measurements showed that with increasing temperature, the electrical conductivity increased when the Cu content was below the percolation threshold, while it decreased when the Cu content was above the percolation threshold. A relatively stable CuAlO₂ layer formed on the cermet surface during electrochemical testing, and the corrosion rate of this anode was estimated to be about 1.8–1.9 cm/year in Al production.     

Scale effect in high-rate (spall) failure

Experimental results on the spall strength of copper in which the scale of the system was changed by a factor of ten show that the scale effect for high-rate one-dimensional strain depends on energy. The spall energy per unit surface area for failure increases with time. Arzamas-16. Translated from Fizika Goreniya i Vzryva, Vol. 29, No. 6, pp. 88–93, November–December, 1993.     

Engineering of functional supramacromolecular complexes of proteins (enzymes) using reversed micelles as matrix microreactors

The size of the inner water cavity of reversed micelles formedin a triple system ‘water-surfactant-organic solvent’can be widely varied by changing the degree of surfactant hydration.This gives grounds to use reversed micelles as matrix microreactorsfor the design of supramolecular complexes of proteins. Usingultracentrifugation analysis, it has been demonstrated thatthe oligomeric composition of various enzymes (ketoglutaratedehydrogenase, alkaline phosphatase, lactic dehydrogenase, glyceraldehyde-3-phosphatedehydrogenase) solubilized in reversed micelles of Aerosol OT[sodium bis(2-ethylehexyl)sulfosuccinate] in octane changesupon variation of the degree of hydration. An oligomeric complexforms under conditions when the radius of the micelle innercavity is big enough to incorporate this complex as a whole.At lower degrees of hydration the micelles ‘uncouple’such complexes to their components. The catalytic propertiesof various oligomeric complexes have been studied. Possibilitiesof using reversed micelles for the separation of subunits ofoligomeric enzymes under non-denaturating conditions have beendemonstrated. In particular, the isolated subunits of alkalinephosphatase, lactic dehydrogenase and glyceralde-hyde-3-phosphatedehydrogenase have been found to be active in Aerosol OT reversedmicelles. The dependences of the catalytic activity of oligomericenzymes represent saw-like curves. The maxima of the catalyticactivity observed at these curves relate to the functioningof various oligomeric forms of an enzyme. The radii of the micelleinner cavity under conditions when these maxima are observedcorrelate with the linear dimensions of the enzyme oligomericforms. Correlation of the position of a maximum with the shapeof an oligomeric complex is discussed.     

Internal Stresses, Corrosion and Electrochemical Behavior in Soils, and Stress Corrosion of Pipe Steels

The results of field tests carried out at main gas pipelines (MP) are shown. The distribution of internal stresses along the MP perimeter is obtained. Polarization currents at differently strained pipeline fragments are determined in soils taken at different distances from the failure epicenter. The mechanoelectrochemical effect is shown to be twice greater in failure soils. Its value can serve as a criterion of the stress corrosion probability.     

Surface saturation of low-carbon martensite steels with boron and copper

Conclusions  

Analysis of instantaneous cardiac rhythm in a model of multifractal dynamics based on Holter monitoring

For the specific analysis of the variability of RR intervals of the cardiac rhythm, a method for measuring the instantaneous cardiac rhythm (ICR) represented by a multifractal dynamical model (MDM) has been developed. The advantages of this method, compared to the statistical methods of analysis of the RR intervals used, have been demonstrated. The method allows possible catastrophes of the cardiovascular system to be predicted. Using the data of Holter monitoring and the program system developed, we have plotted ICR curves, an ICR piecewise linear trend, and variability charts for three randomly chosen time intervals. The self-similarity (fractality) of the ICR up to an accuracy of 5% has been shown based on the explicit data. The MDM parameters have been calculated based on the ICR data. The analysis of the dynamics of these parameters has been conducted and their compliance with the status of the patient examined has been studied. The relevance of the ICR examination within MDM is closely related to the necessity of recognizing new markers of adverse cardiovascular episodes. The research performed shows that the results obtained could be taken as a basis for developing a new mathematical method of ICR examination based on Holter monitoring.     

Switching networked attitude control of an unmanned quadrotor

In this article, a switching networked attitude controller for an unmanned quadrotor over a wireless sensor network is presented. To deal with the network induced time varying delays, the quadrotor is being modeled as a switching time varying linear system, while the applied switching output feedback control scheme, is calculated based on Linear Matrix Inequalities, and is able to guarantee the stability of the quadrotor under arbitrary changes in the time delays.