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排序方式: 共有575条查询结果,搜索用时 15 毫秒
101.
Alexis Marsol-Vall Antoni Delpino-Rius Jordi Eras Mercè Balcells Ramon Canela-Garayoa 《Food Analytical Methods》2014,7(2):465-471
A fast and reliable method for the quantification of patulin using ultra high performance liquid chromatography coupled to a photodiode array detector was developed and validated for the analysis of several apple-based foodstuffs. Sample preparation was based on the QuEChERS procedure. Samples were extracted with acetonitrile and partitioned with a mixture of sodium citrate, NaCl, and Mg2SO4. The cleanup step was performed using dispersive SPE mixed with Mg2SO4 and PSA. This step was carried out twice in order to improve chromatographic results. The method was validated in spiked cloudy apple juice, apple puree, apple yogurt, beer with apple juice, and cider and applied to 24 commercial samples. The limits of detection and limits of quantification were ≥0.4 and ≥2 ng/g, respectively. Both were below the maximum legal limit established by the European Union. Recoveries for all the matrices were between 78.4 and 94.7 % while relative standard deviations were between 3.8 and 10.4 %. Patulin was detected on four apple juices from concentrate, one cloudy apple juice from an eco-store, and one beer. Nevertheless, the highest concentration found was 25.4 ng/g. 相似文献
102.
Samélor D Lazar AM Aufray M Tendero C Lacroix L Béguin JD Caussat B Vergnes H Alexis J Poquillon D Pébère N Gleizes A Vahlas C 《Journal of nanoscience and nanotechnology》2011,11(9):8387-8391
Amorphous aluminium oxide coatings were processed by metalorganic chemical vapour deposition (MOCVD); their structural characteristics were determined as a function of the processing conditions, the process was modelled considering appropriate chemical kinetic schemes, and the properties of the obtained material were investigated and were correlated with the nanostructure of the coatings. With increasing processing temperature in the range 350 degrees C-700 degrees C, subatmospheric MOCVD of alumina from aluminium tri-isopropoxide (ATI) sequentially yields partially hydroxylated amorphous aluminium oxides, amorphous Al2O3 (415 degrees C-650 degrees C) and nanostructured gamma-Al2O3 films. A numerical model for the process allowed reproducing the non uniformity of deposition rate along the substrate zone due to the depletion of ATI. The hardness of the coatings prepared at 350 degrees C, 480 degrees C and 700 degrees C is 6 GPa, 11 GPa and 1 GPa, respectively. Scratch tests on films grown on TA6V titanium alloy reveal adhesive and cohesive failures for the amorphous and nanocrystalline ones, respectively. Alumina coating processed at 480 degrees C on TA6V yielded zero weight gain after oxidation at 600 degrees C in lab air. The surface of such low temperature processed amorphous films is hydrophobic (water contact angle 106 degrees), while the high temperature processed nanocrystalline films are hydrophilic (48 degrees at a deposition temperature of 700 degrees C). It is concluded that amorphous Al2O3 coatings can be used as oxidation and corrosion barriers at ambient or moderate temperature. Nanostructured with Pt or Ag nanoparticles, they can also provide anti-fouling or catalytic surfaces. 相似文献
103.
Jesse V. Jokerst Jie Chou James P. Camp Jorge Wong Alexis Lennart Amanda A. Pollard Pierre N. Floriano Nicolaos Christodoulides Glennon W. Simmons Yanjie Zhou Mehnaaz F. Ali John T. McDevitt 《Small (Weinheim an der Bergstrasse, Germany)》2011,7(5):612-612
The slow development of cost‐effective medical microdevices with strong analytical performance characteristics is due to a lack of selective and efficient analyte capture and signaling. The recently developed programmable nano‐bio‐chip (PNBC) is a flexible detection device with analytical behavior rivaling established macroscopic methods. The PNBC system employs ≈300 μm‐diameter bead sensors composed of agarose “nanonets” that populate a microelectromechanical support structure with integrated microfluidic elements. The beads are an efficient and selective protein‐capture medium suitable for the analysis of complex fluid samples. Microscopy and computational studies probe the 3D interior of the beads. The relative contributions that the capture and detection of moieties, analyte size, and bead porosity make to signal distribution and intensity are reported. Agarose pore sizes ranging from 45 to 620 nm are examined and those near 140 nm provide optimal transport characteristics for rapid (<15 min) tests. The system exhibits efficient (99.5%) detection of bead‐bound analyte along with low (≈2%) nonspecific immobilization of the detection probe for carcinoembryonic antigen assay. Furthermore, the role analyte dimensions play in signal distribution is explored, and enhanced methods for assay building that consider the unique features of biomarker size are offered. 相似文献
104.
In this article, we design optimal or near optimal interval routing schemes (IRS, for short) with small compactness for several classes of plane quadrangulations and triangulations (by optimality or near optimality we mean that messages are routed via shortest or almost shortest paths). We show that the subgraphs of the rectilinear grid bounded by simple circuits allow optimal IRS with at most two circular intervals per edge (2-IRS). We extend this result to all plane quadrangulations in which all inner vertices have degrees4. Namely, we establish that every such graph has an optimal IRS with at most seven linear intervals per edge (7-LIRS). This leads to a 7-LIRS with the stretch factor 2 for all plane triangulations in which all inner vertices have degrees6. All routing schemes can be implemented in linear time. 相似文献
105.
Quentin Puydt Sylvain Flouriot Sylvain Ringeval Frédéric De Geuser Guillaume Parry Alexis Deschamps 《Metallurgical and Materials Transactions A》2014,45(13):6129-6140
This work presents a detailed, multiscale, spatially resolved study of the microstructure of an electron beam butt weld of the EN-AW 7020 (Al-Zn-Mg) alloy. Using a combination of optical, scanning and transmission electron microscopy, differential scanning calorimetry, and small-angle X-ray scattering, the distribution of phases in the different areas of the heat-affected zone and of the fusion zone is quantitatively characterized, for two different aging states: naturally aged after welding and artificially aged at 423 K (150 °C). The heat-affected zone consists of regions experiencing different levels of precipitate dissolution and coarsening during welding as well as new precipitation during post-welding heat treatment (PWHT). The microstructure of the fusion zone is typical from a fast solidification process, with a strong solute segregation in the interdendritic zones. The precipitate distribution after PWHT follows this solute distribution, and the resulting hardness is much lower than the relatively homogeneous value in the base metal and the heat-affected zone. 相似文献
106.
107.
Alexis Tran‐Viet Alexander F. Routh Andrew W. Woods 《American Institute of Chemical Engineers》2014,60(3):1193-1201
Experiments explore the reduction in permeability of a porous bead pack when a suspension of thermally responsive polymer is injected and the temperature then increased above the thermal activation temperature. The change in permeability is greater with higher polymer concentration, provided that the ionic concentration of the solution is sufficient for floc formation. The time for activation of the blocking effect is within tens of seconds to minutes of when the polymer solution is heated. This is consistent with the timescale for diffusion‐limited aggregation, although the detailed value depends on the geometry and polymer concentration. Dynamical experiments demonstrate that once the porous media is blocked, adding additional polymer has no effect. The mechanism for permeability reduction may be modeled in the context of a pore‐network model, and we build a simple model to illustrate the permeability reduction as a function of the fraction of pores links which are blocked. © 2014 American Institute of Chemical Engineers AIChE J, 60: 1193–1201, 2014 相似文献
108.
Patricia A. Ignacio-de Leon Alexis E. Abelow Julie A. Cichelli Arkady Zhukov Ivan I. Stoikov Ilya Zharov 《Israel journal of chemistry》2014,54(5-6):767-773
Robust mesoporous membranes composed of silica spheres were surface-modified with chiral selector moieties, including small molecules, macrocycles, and polymers. Diffusion rates of enantiomers of a chiral dye through the resulting asymmetrically modified colloidal membranes were measured and the corresponding permselectivities were calculated. The membranes showed enantioselectivities in the range of 1.2–1.8, which were not significantly affected by the structure of the surface-immobilized chiral electors. This selectivity is on par with most reported polymer-based solid membranes and bulk liquid membranes. The enantioselectivity results from the surface-facilitated mechanism of transport of enantiomers through the mesopores. 相似文献
109.
The lipid composition of blubber, brain, muscle and heart from a Mediterranean monk sealMonachus monachus (an endangered species) were examined to allow comparisons with more common species of seals. Only neutral lipids (mainly
triacylglycerols) were detectable in the blubber lipids, whereas polar lipids predominated in the heart and in the brain.
Neutral and polar lipids comprised almost equal proportions in both liver and muscle. Choline glycerophospholipids (CGP) were
the major polar lipids, followed by ethanolamine glycerophospholipids (EGP) in the liver, heart and muscle. Cerebrosides accounted
for 28.8% of the brain lipids. All lipid classes of the liver contained high levels (31–47%) of polyunsaturated fatty acids
(PUFA), with the exception of phosphatidylserine. The total proportion of n−6 PUFA exceeded that of n−3 PUFA in all lipid
classes of the liver, due mainly to the high levels of 20∶4n−6. The highest level of 20∶4n−6 occurred in phosphatidylinositol,
where it comprised 32.4% of the total fatty acids. The CGP and EGP of the brain contained lower levels of PUFA than those
of the liver, muscle and heart. Alkenyl ethers accounted for 35.8% of the total long-chain moieties in brain EGP. The fatty
acid composition of blubber triacylglycerols differed from those of the lipid classes from other tissues in that it had a
very low ratio of n−6 to n−3 PUFA (0.3) as a result of a lower content of 20∶4n−6. 相似文献
110.
The effects of adding mixtures of titania and zirconia on the methanol synthesis activity and selectivity of Cu/SiO2 were investigated. The synthesis of methanol from both CO/H2 and CO2/H2 mixtures was examined at 0.65 MPa and temperatures between 448 and 573 K. For CO hydrogenation, the addition of ZrO2 alone increased the methanol synthesis activity of Cu/SiO2 by up to three-fold. Substitution of a portion of the ZrO2 by TiO2 decreased the methanol synthesis activity of the catalyst relative to that observed when only ZrO2 is added. ZrO2 addition also enhanced the methane synthesis activity by as much as seven fold. In the case of CO2 hydrogenation, the maximum methanol synthesis activity is achieved when a 50/50 wt% mixture of ZrO2 and TiO2 is added to Cu/SiO2. Neither the presence of the oxide additive nor its composition had any effect on the activity of the reverse water–gas-shift reaction, which suggests that this reaction proceeds only on Cu. The observed effects of ZrO2 and TiO2 on the catalytic activity of methanol synthesis from CO and CO2, and methane synthesis from CO, are interpreted in terms of the strength and concentration of acidic and basic groups on the surface of the dispersed oxide. 相似文献