Covalent 0D–2D Heterostructuring of Co9S8–MoS2 for Enhanced Hydrogen Evolution in All pH Electrolytes

Ultrasmall Co₉S₈ nanoparticles are introduced on the basal plane of MoS₂ to fabricate a covalent 0D–2D heterostructure that enhances the hydrogen evolution reaction (HER) activity of electrochemical water splitting. In the heterostructure, separate phases of Co₉S₈ and MoS₂ are formed, but they are connected by Co–S–Mo type covalent bonds. The charge redistribution from Co to Mo occurring at the interface enhances the electron‐doped characteristics of MoS₂ to generate electron‐rich Mo atoms. Besides, reductive annealing during the synthesis forms S defects that activates adjacent Mo atoms for further enhanced HER activity as elucidated by the density functional theory (DFT) calculation. Eventually, the covalent Co₉S₈–MoS₂ heterostructure shows amplified HER activity as well as stability in all pH electrolytes. The synergistic effect is pronounced when the heterostructure is coupled with a porous Ni foam (NF) support to form Co₉S₈–MoS₂/NF that displays superior performance to those of the state‐of‐the‐art non‐noble metal electrocatalysts, and even outperforms a commercial Pt/C catalyst in a practically meaningful, high current density region in alkaline (>170 mA cm^?2) and neutral (>60 mA cm^?2) media. The high HER performance and stability of Co₉S₈–MoS₂ heterostructure make it a promising pH universal alternative to expensive Pt‐based electrocatalysts for practical water electrolyzers.     

Authenticated key agreement for blockchain-based WBAN

Telecommunication Systems - Certificateless authenticated key agreement (CLAKA) is important to prevent the escrow problem. It also mitigates the certificate management burden in storage and during...     

Face-Based Mobile Target Tracking Technique in Wireless Sensor Network

Wireless Personal Communications - A prediction-based method is presented to track mobile object and its location in a sensor network area. In recent years, energy consumption and high accuracy...     

Integrated Routing Algorithms for Provisioning “Sub-Wavelength” Connections in IP-Over-WDM Networks

This work focuses on developing and implementing comprehensive unified constraint-based routing algorithms within the generalized multi-protocol label switching framework (GMPLS) to provision sub-wavelength circuits (low-rate traffic streams). Constraint-based routing is further augmented in this work by dynamically routing both an active and another alternate link/node-disjoint backup path at the same time in order to provision a given connection request. This new integrated approach combines both IP routing and optical resource allocation to setup end-to-end connections.     

Relay-Assisted Wireless Energy Transfer for Efficient Spectrum Sharing in Harsh Environments

International Journal of Wireless Information Networks - With exponential growth in the number of wireless devices and limited available spectrum, the problem of spectrum sharing remains in...     

WSANFlow: An Interface Protocol Between SDN Controller and End Devices for SDN-Oriented WSAN

When dealing with a Wireless Sensor and Actuator Network (WSAN) structure, one of the challenging problems is lack of flexibility in such network operations as establishment, management, and configuration. Software-defined Networking (SDN) is a promising technology for a simpler, more flexible, and less overworked network structure. Integration of SDN as a solution into the existing WSAN structures seems to be a strong candidate of deployment solutions for next generation WSAN systems. In order to get enhanced performance results for WSAN systems, we proposed an interface protocol, referred to as WSANFlow, which is responsible for all the communications between SDN controller (SDNC) and SDN-oriented end devices. The SDNC in this approach has the network intelligence and is capable of handling all the control and management operations related to the network. Thus, advanced communication operations can be managed and efficiently optimized efficiently by the SDN controller and then, subsequently, corresponding instructions can be delivered to end devices using the proposed WSANFlow protocol. In the study, we analyzed the proposed framework performance, in terms of power consumption ratio, throughput, and end to end delay metrics. Then, we compared the results with those of a ZigBee-based counterpart for different workloads such as; light, heavy and heavier load which modelizes a video stream of mild parameters. The results show that not only has the overall performance of the existing WSAN system been enhanced, but also control and management operations have been simplified by the proposed model.     

Interference Mitigation Based on Radio Aware Channel Assignment for Wireless Mesh Networks

An intricate network deployment for high demand users leads to simultaneous transmission in wireless mesh networks. Multiple radios are adapted to individual nodes for improving network performance and Quality of Service (QoS). However, whenever multiple radios are assigned to the same channel, co-located radio interference occurs, which poses a major drawback. This paper proposes a Radio aware Channel Assignment (Ra-CA) mechanism based on a direct graphical model for mitigation of interference in multi-radio multi-channel networks. Initially, the co-located radio interference is identified by classifying non-interfering links for simultaneous transmission in the network. Proposed channel assignment mechanism helps in allocating the minimal number of channels to the network that mitigate co-located radio interference. Performance analysis of the proposed Ra-CA strategy is carried out compared with other existing techniques, like Breadth First Search-Channel Assignment (BFS-CA) and Maximal Independent Set Channel Assignment (MaIS-CA), in multi-radio networks. Simulation results demonstrate that the proposed channel assignment scheme is more efficient compared to the existing ones, in terms of QoS parameters like, packet drop rate, packet delivery ratio, transmission delay and throughput.     

A Bayer pattern-based fragile watermarking scheme for color image tamper detection and restoration

Multidimensional Systems and Signal Processing - The security of multimedia documents becomes an urgent need, especially with the increasing image falsifications provided by the easy access and use...     

Compact and High Speed Architectures of KASUMI Block Cipher

Wireless Personal Communications - This paper proposes highly compact and high speed hardware architectures of 64-bit KASUMI block cipher for wide range of wireless applications. A novel...