Copolymerizations of various ring-fluorinated stilbenes with styrene

Summary The E-isomers of 2-, 3- and 4-fluorostilbene and 4,4-difluorostilbene and also the Z-isomers of 4-fluorostilbene have been examined as comonomers in the radical polymerization of styrene at 60°C. The low levels of incorporation of the fluoro-compounds have been measured by consideration of the 19F-NMR spectra of the copolymers, using fluorobenzene as an internal standard. The reactivities of the various fluorostilbenes towards the polystyrene radical are discussed and compared with those towards the benzoyloxy radical.     

Exploration of the optimisation algorithms used in the implementation of adaptive optics in confocal and multiphoton microscopy

We report on the introduction of active optical elements into confocal and multiphoton microscopes in order to reduce the sample-induced aberration. Using a flexible membrane mirror as the active element, the beam entering the rear of the microscope objective is altered to produce the smallest point spread function once it is brought to a focus inside the sample. The conventional approach to adaptive optics, commonly used in astronomy, is to utilise a wavefront sensor to determine the required mirror shape. We have developed a technique that uses optimisation algorithms to improve the returned signal without the use of a wavefront sensor. We have investigated a number of possible optimisation methods, covering hill climbing, genetic algorithms, and more random search methods. The system has demonstrated a significant enhancement in the axial resolution of a confocal microscope when imaging at depth within a sample. We discuss the trade-offs of the various approaches adopted, comparing speed with resolution enhancement.     

The multi-element content of the lichen Parmelia sulcata, soil, and oak bark in relation to acidification and climate

Understanding how biodiversity is influenced by changing atmospheric conditions is important for conservation, public policy and environmental health. In a recent study, an impact on two of the most abundant lichens in Europe (Parmelia sulcata and Hypogymnia physodes) was recorded at Burnham Beeches lying 40 km west of London (UK) during unusual atmospheric conditions whilst other species remained unaffected. Bark and soil chemistry also influence lichen vitality and community composition. Correlations between element concentrations and element ratios in different samples help understand element cycling. To study this further, the multi-element content of the lichen P. sulcata and bark sampled in 2000 from 16 oak (Quercus robur) trees at Burnham Beeches was compared with the same elements determined in 24 surface soils sampled in 2005 from beneath the same trees. Soil pH ranged from 4.1 to 6.7. Highly significant correlations (p<0.001) for Mn/Ca ratios in lichen versus bark, soil versus bark and soil versus lichen samples confirmed cycling via the soil-tree-lichen system. Similar Mn/Ca ratios were reported in coniferous forests where high Mn concentrations were shown to limit epiphytic lichen abundance. Soil acidification influences element bioavailability and bark chemistry in Burnham Beeches with implications for lichen diversity and health. Recovery was recorded in P. sulcata, including regeneration within monitoring quadrats. Biological systems are well known to be influenced by pollution episodes.     

丹佛斯210/250cm~3排量柱塞泵新品亮相

正日前,丹佛斯推出了210/250cm3排量的柱塞泵,完善了H1家族柱塞泵和弯轴马达的产品型谱。截止目前,丹佛斯柱塞泵拥有覆盖45~250 cm3的14个排量序列,以及弯轴柱塞马达横跨60~250 cm3的5个排量序列。高效率弥补发动机低转速在当今严格的排放和安全法规要求下,H1系列的泵和马达采用紧凑和轻量化的设计理念,能够给系统设计提供较大的灵活性。更高的运行效率可补偿为顺应新的排放法规而降低的发动机转速。拥有专利技术的集成式速度限制器(ISL)作为泵的一个高级功能模块,可以改善车辆制动性能,并消除发动机超速风险。     

Fate and transport of elemental copper (Cu0) nanoparticles through saturated porous media in the presence of organic materials

Column experiments were performed to assess the fate and transport of nanoscale elemental copper (Cu⁰) particles in saturated quartz sands. Both effluent concentrations and retention profiles were measured over a broad range of physicochemical conditions, which included pH, ionic strength, the presence of natural organic matter (humic and fulvic acids) and an organic buffer (Trizma). At neutral pHs, Cu⁰ nanoparticles were positively charged and essentially immobile in porous media. The presence of natural organic matter, trizma buffer, and high pH decreased the attachment efficiency facilitating elemental copper transport through sand columns. Experimental results suggested the presence of both favourable and unfavourable nanoparticle interactions causes significant deviation from classical colloid filtration theory.     

Fire evacuation skills: Cognitive-behavioral versus computer-mediated instruction

Fifty-six fourth-grade children participated in this study to assess three training procedures for relative effectiveness in acquiring fire emergency skills and attaining knowledge. The first training approach was behavioral, the second used animated graphics, and the third used still graphics. Each of the training groups was compared to a control group that received no treatment. Performance on dependent measures was assessed before and immediately after training. It was hypothesized that the behavioral and animated-graphics conditions would produce the greatest level of skill and knowledge acquisition. Results demonstrated a significantly higher level of fire emergency skill acquisition and knowledge attainment for both the behavioral and animated-graphics groups relative to the still-graphics group and the control group, which had no training. The value of using computer-mediated strategies for fire-safety skills training was demonstrated.     

Including Women? (Dis)junctures Between Voice,Policy and Implementation in Integrated Development Planning

Integrated development plans (IDPs) are municipal strategic plans designed to bring about developmental local government. They have been criticised for providing insufficient space for democratic participation. This paper explores the extent to which a marginalised group—women—has been incorporated into the IDP process, in response to three questions. First, how have IDP participatory processes incorporated women’s voice, and are the new participatory spaces realising their transformative potential? Secondly, how have women’s interests and a gender perspective been mainstreamed in the IDP, and has it promoted transformation? And finally, at the interface between officials and women themselves, how are IDP projects implemented and does agency promote or impede the goals of gender equality? A study of three KwaZulu-Natal municipalities reveals some achievements, but unequal gender relations have not been transformed. These case studies demonstrate some of the complexities and difficulties in the practice of democratic governance.     

An Investigation into the critical factors affecting the performance of composite controlled permeable formwork liners: Part I – Drainage medium

The critical elements associated with a CPF drainage medium and their associated effects on the near surface performance of vertically cast concrete slabs are the focus of this study. A range of board absorption levels, textured features and texture depth are investigated using a Taguchi orthogonal array approach. A permeable polypropylene filter layer was used in conjunction with the various drainage mediums. Statistical software was utilised to determine significant variables as a function of the near surface performance. The range of tests used to characterise the surface performance of the various drainage mediums include surface roughness, surface hardness, surface tensile strength and water absorption. Results are compared to a control sample which was cast against impermeable plywood formwork. All drainage medium permutations showed similar evidence of water/cement ratio reduction at the near surface region of the concrete slab. Surface quality was analysed using quantitative methods and showed significant improvements for all systems over the control. The results for the systems studied indicate that the features of a drainage medium are not critical to the functionality of a CPF liner to reduce the near surface w/c ratio. In fact, it is indicated that the absence of a drainage medium has the same enhancement in near surface concrete slab properties as that of a complex structure when compared to the control sample.     

Bioreactivity of municipal solid waste landfill leachates-Hormesis and DNA damage

The issue of domestic waste is recognised as one of the most serious environmental problems facing the nation. With the UK producing 35 million tonnes of municipal solid waste per annum, an understanding of the ranges of toxicity of landfill emissions is crucial to determine the degree of concern we should have about the potential effects these waste sites could have upon nearby populations and the surrounding environment. The aim of this study was to evaluate the bioreactivity of landfill leachates in terms of their capacity to damage ROS-sensitive bacteriophage plasmid DNA and induce toxicity in a commercial photobacterium toxicity assay, based on the light emission of Vibrio fischeri bacteria (ROTAS). The bacterial assay revealed widespread biostimulation and a hormesis response in the bacteria, with alpha-, beta- and gamma-response curves observed following exposure to the different landfill leachates. Different biological mechanisms lead to variations in bioreactivity, as seen in the plasmid DNA scission and ROTAS assays.