Complementarity effect of governance mechanisms on environmental collaboration: does it exist?

This study evaluates the effect of pre-existing relational governance mechanisms on environmental collaboration. Specifically, our study distinguishes between structural and process dimensions of relational governance mechanisms so as to facilitate a more nuanced investigation into the inherent complementarities and performance implications. Using data collected from 145 US firms and a combination of methodologies – three-stage least squares and structural equation modelling, a number of direct, complementary and mediation effects are hypothesised and tested. The three-stage least squares methodology was adopted to overcome endogeneity and simultaneity issues inherent in the hypotheses covering complementarity. Contrary to conventional wisdom, structural and process governance mechanisms were not found to act as complements for environmental collaboration. Instead, the effect of structural mechanisms was found to be completely mediated by the process mechanisms. Thus, process mechanisms of relational governance were found to be much more important in promoting advanced practices such as environmental collaboration. Our results also document the significant mediating role of environmental collaboration. Implications for future research and practice are offered.     

Near room temperature magnetic entropy changes in as-cast Gd100−xMnx (x = 0, 5, 10, 15, and 20 at.%) alloys

A series of Gd_100−xMn_x (x = 0, 5, 10, 15, and 20 at.%) alloys were prepared by arc-melting. The Curie temperature (T_C) associated with the ferromagnetic-paramagnetic transitions, derived from M-T curves, show decrease in T_C for as-cast alloys (∼279 K) as compared to as-cast Gd (∼292 K). No appreciable decrease in the |ΔS_M|_max values ∼4.6 J/kg K (0-2 T) and ∼8.6 J/kg K (0-5 T) were observed upon alloying Gd with Mn up to x ≤ 15 at.%. Refrigerant capacity (q) showed negligible variation ∼195 J/kg (0-2 T) and ∼450 J/kg (0-5 T) with increasing Mn (up to x ≤ 15 at.%) content. Similar values of |ΔS_M|_max and q coupled with ∼13 K decrease in T_C for as-cast Gd_100−xMn_x (0 ≤ x ≤ 15) alloys as compared to Gd, suggests expansion of working temperature region of Gd upon alloying with Mn up to 15 at.%. Low cost, adjustable T_C, favorable magnetocaloric properties make Gd_100−xMn_x alloys potential candidates as second-order transition based magnetic refrigerants for near room temperature air-conditioning and magnetic refrigeration.     

Lithium ion conduction in Li5La3Ta2O12 and Li7La3Ta2O13 garnet-type materials

Electrical properties of the lithium garnets Li₅La₃Ta₂O₁₂ (L5LTO) and Li₇La₃Ta₂O₁₃ (L7LTO) are reported over a wide frequency range from 10 MHz to 0.1 Hz at different temperatures. The structural properties are characterized by powder X-ray diffraction, Scanning electron microscopy with energy dispersive X-ray spectroscopy and Fourier transformation Infrared spectroscopy. By means of the frame work of classical brick layer model (BLM) and of a finite element approach, the ion transport properties of grain and grain boundary for the lithium garnets were analyzed. The specific grain conductivity of 5.0?×?10^?6?S/cm at 40 °C is found for both lithium garnets. Specific grain conductivities and grain boundary conductivities are thermally activated, with activation energies found to be in the range of 0.55–0.61 eV. The total conductivity is found to be depending on the ion conduction of grain boundary. The information on the fraction of contact area α_contact between grains <0.25 is obtained by the finite element approach for Li₇La₃Ta₂O₁₃.     

Establishing relationship between the base metal properties and friction stir welding process parameters of cast aluminium alloys

In friction stir welding (FSW), the material under the rotating action of non-consumable tool has to be stirred properly to get defect free welds in turn it will improve the strength of the welded joints. The welding conditions and parameters are differing based on the mechanical properties of base materials such as tensile strength, ductility and hardness which control the plastic deformation during friction stir welding. The FSW process parameters such as tool rotation speed, welding speed and axial force, etc. play a major role in deciding the weld quality. FSW Joints of cast aluminium alloys A319, A356, and A413 were made by varying the FSW process parameters and the optimum values were obtained. In this investigation, empirical relationships are established and they can be effectively used to predict the optimum FSW process parameters to fabricate defect free joints with high tensile strength from the known base metal properties of cast aluminium alloys.     

Texture and residual strain in two SiC/Ti-6-2-4-2 titanium composites

Residual strain and texture variations were measured in two titanium matrix composites reinforced with silicon carbide fibers (Ti/SiC) of similar composition but fabricated by different processing routes. Each composite comprised a Ti-6242 α/β matrix alloy containing vol 35 pct continuous SiC fibers. In one, the matrix was produced by a plasma sprayed (PS) route, and in the other by a wiredrawn (WD) process. The PS and WD composites were reinforced with SCS-6 (SiC) and Trimarc (SiC) fibers, respectively. The texture in the titanium matrices differed significantly. The titanium matrix for the PS material exhibited random texture pre and post fabrication of the composite. For the WD material, the starting texture of the monolithic titanium matrix was ≈17 times random, but after consolidation into composite form, it was ≈6 times random. No significant differences were noted in the fiber-induced matrix residual strains between the composites prepared by the two procedures. However, the Trimarc (WD) fibers recorded higher (≈1.3 times) compressive strains than the SCS-6 (PS) fibers. Stresses and stress balance results are reported. Plane-specific elastic moduli, measured in load tests on the unreinforced matrices, showed little difference. This article is based on a presentation made in the Symposium “Mechanisms and Mechanics of Composites Fracture” held October 11–15, 1998, at the TMS Fall Meeting in Rosemont, Illinois, under the auspices of the TMS-SMD/ASM-MSCTS Composite Materials Committee.     

Harakeke (phormium tenax) fibre–waste plastics blend composites processed by screwless extrusion

Most plastic packaging products are discarded after a single use resulting in an abundant supply of waste plastics. Natural fibres are light in weight, abundant and inexpensive. The stiffness and strength of polymers have been shown to improve with the incorporation of natural fibres. Hence, composite materials made of natural fibres and waste plastics would result in the reduction of plastic wastes and the use of fibres from renewable resources. Composite specimens and sheets consisting of fibres from the New Zealand flax plant, phormium tenax or Harakeke as it is known in Maori, and waste plastics have been produced through screwless extrusion followed by injection moulding. The tensile and impact properties of these composites have been determined. The formability of these composites has been assessed through thermoforming.     

Growth and oil price: A study of causal relationships in small Pacific Island countries

This paper investigates the nexus between economic growth and oil price in small Pacific Island countries (PICs). Except Papua New Guinea, none of the 14 PICs has fossil any fuel resources. Consequently, the other 13 PICs are totally dependent on oil imports for their economic activities. Since PICs have limited foreign exchange earning capacities, as they have a very narrow range of exports and are highly dependent on foreign aid, high oil prices in recent months have seriously tested their economic resilience. This paper applies the ARDL bounds testing methodology to four selected PICs, Samoa, Solomon Islands, Tonga and Vanuatu, which have consistent and reliable time series of data, with a view to assess the impact of oil price on economic growth. The findings are that oil price, gross domestic product and international reserve are cointegrated in all the four PICs. Further, both in the long and short runs, we observe that there is a uni-directional relationship as causality linkage runs only from oil price and international reserves to economic growth. The paper makes some policy recommendations.     

Hierarchical 3D Cobalt‐Doped Fe3O4 Nanospheres@NG Hybrid as an Advanced Anode Material for High‐Performance Asymmetric Supercapacitors

Hierarchical nanostructure, high electrical conductivity, extraordinary specific surface area, and unique porous architecture are essential properties in energy storage and conversion studies. A new type of hierarchical 3D cobalt encapsulated Fe₃O₄ nanosphere is successfully developed on N‐graphene sheet (Co?Fe₃O₄ NS@NG) hybrid with unique nanostructure by simple, scalable, and efficient solvothermal technique. When applied as an electrode material for supercapacitors, hierarchical Co?Fe₃O₄ NS@NG hybrid shows an ultrahigh specific capacitance (775 F g^?1 at a current density of 1 A g^?1) with exceptional rate capability (475 F g^?1 at current density of 50 A g^?1), and admirable cycling performance (97.1% capacitance retention after 10 000 cycles). Furthermore, the fabricated Co?Fe₃O₄ NS@NG//CoMnO₃@NG asymmetric supercapacitor (ASC) device exhibits a high energy density of 89.1 Wh kg^?1 at power density of 0.901 kW kg^?1, and outstanding cycling performance (89.3% capacitance retention after 10 000 cycles). Such eminent electrochemical properties of the Co?Fe₃O₄ NS@NG are due to the high electrical conductivity, ultrahigh surface area, and unique porous architecture. This research first proposes hierarchical Co?Fe₃O₄ NS@NG hybrid as an ultrafast charge?discharge anode material for the ASC device, that holds great potential for the development of high‐performance energy storage devices.