Template-assisted synthesis of high packing density SrLi2Ti6O14 for use as anode in 2.7-V lithium-ion battery

SrLi₂Ti₆O₁₄ has been prepared by using mesoporous TiO₂ brookite as a template and reactant. The prepared particles retained the rounded shape of the precursor, leading to high dispersivity and high packing density. The material has been further electrochemically characterized in both half and full cells. It shows good cycling stability and rate capability. A 2.7-V cell has been built by combining a SrLi₂Ti₆O₁₄ anode with a 4-V spinel cathode of LiMn₂O₄. This cell has a higher voltage compared to the 2.5-V LiMn₂O₄/Li₄Ti₅O₁₂ system.     

Understanding the redox shuttle stability of 3,5-di-tert-butyl-1,2-dimethoxybenzene for overcharge protection of lithium-ion batteries

3,5-di-tert-butyl-1,2-dimethoxybenzene (DBDB) has been synthesized as a new redox shuttle additive for overcharge protection of lithium-ion batteries. DBDB can easily dissolve in carbonate-based electrolytes, which facilitates its practical use in lithium-ion batteries; however, it has poor electrochemical stability compared to 2,5-di-tert-butyl-1,4-dimethoxybenzene (DDB). The structures of DBDB and DDB were investigated using X-ray crystallography and density functional calculations. The structures differ in the conformations of the alkoxy bonds probably due to the formation of an intramolecular hydrogen bond in the case of DBDB. We investigated reaction energies for decomposition pathways of neutral DBDB and DDB and their radical cations and found little difference in the reaction energies, although it is clear that kinetically, decomposition of DBDB is more favorable.     

Microscopic image segmentation based on pixel classification and dimensionality reduction

Pathological image analysis plays a significant role in effective disease diagnostics. In this article, a tool for diagnosis assistance by automatic segmentation of bone marrow images is introduced. The aim of our segmentation is to demarcate cell's component: nucleus, cytoplasm, red cells, and background. Different color spaces were used to extract color's features to profit of their complementarity. We introduce several dimensionality reduction techniques. These techniques are exemplified on a support vector machine pixel‐based bone marrow image segmentation problem in which it is shown that it may give significant improvement in segmentation accuracy and time consuming. © 2013 Wiley Periodicals, Inc. Int J Imaging Syst Technol, 23, 22–28, 2013     

A comparative evaluation of sequential set point adjustment procedures for tolerance control

The machining of complex parts typically involves a logical and chronological sequence of n operations on m machine tools. Because manufacturing datums cannot always match design datums, some of the design specifications imposed on the part are usually satisfied by distinct subsets of the n operations prescribed in the process plan. Conventional tolerance control specifies a fixed set point for each operation and permissible variation about this set point to insure compliance with the specifications. Sequential tolerance control (STC) uses real-time measurement information at the completion of one stage to exploit the available space inside a dynamic feasible zone and reposition the set point for subsequent operations. This paper introduces an extension of STC that utilizes the variability of the operations to scale the problem data and further enhance the ability of STC to optimize the production of an acceptable part.     

Lattice Boltzmann Simulation of Convective Heat Transfer from Heated Blocks in a Horizontal Channel

This article presents the application of the multiple-relaxation-time (MRT) lattice Boltzmann equation (LBE) method with nine-velocity model to the numerical prediction of a laminar and convective-heated transfer through a two-dimensional obstructed channel flow. The obstruction is carried out by three obstacles including two located on the upper wall and the other on the lower wall of the channel. The calculations are validated against results available in literature. Various physical arrangements are regarded as the size of the obstacles and the distance between the two upper obstacles to investigate their effects on thermal and flow characteristics. Results, presented for a Prandtl number equal to 0.71 and a Reynolds number ranging from 100 to 1200, showed that the heat transfer and the air flow depend both on the Reynolds number and geometric data of the configuration.     

Impact of tripropyl borate on life and impedance of lithium-ion cells

Tripropyl borate was investigated as a low cost anion receptor to improve the performance of lithium-ion cells. The impact of tripropyl borate was examined using lithium-ion cells comprising a negative electrode of mesocarbon microbeads, a positive electrode of Li_1.1[Mn_1/3Ni_1/3Co_1/3]_0.9O₂ and an LiPF₆-based electrolyte. It was found that the performance of the cells was improved by adding a proper amount of tripropyl borate (≤0.1 wt%) to the LiPF₆-based electrolyte. However, a small amount of gas was observed from cells with high contents of tripropyl borate when cycled at 55 °C, and as a result, the performance of the cells deteriorated.     

Fatty Acids in Heterocyclic Synthesis Part XII: Synthesis of Surfactants from Pyrazole, Isoxazole, Pyrimidine and Triazine, Incorporating the 1,3,4-Thiadiazole Moiety Having Dyeing and Antimicrobial Activities

The titled compounds were prepared from 2-amino-5-heptadecyl[1,3,4]thiadiazole (1). Diazotization of (1) produced (2) which was coupled with active methylene compounds and gave azo ⇌ hydrazono derivatives (3A, 3B) _a–d . It was found that there is regio-specificity for addition of different nucleophiles to these tautomers; thus, nitrogen nucleophiles such as hydrazine hydrate, hydroxylamine hydrochloride and thiourea were reacted via Azo tautomer (3A) to yield pyrazole, isoxazole and pyrimidine respectively (5-7), while carbon nucleophiles as phenylisocyanate was reacted via the hydrazono tautomer (3B) and produced triazine derivatives (4). Additionally, the diazonium chloride (2) was coupled with alkaline 2-naphthol and produced 2-(5-heptadecyl-[1,3,4]thiadiazol-2-yl)-1,2-dihydro-3-oxa-1,2-diaza-cyclopenta[a]naphthalene (8). UV–visible spectra of the synthesized colored compounds (2-8) showed λ _max at 374–398 nm, while screening these compounds in vitro against micro-organisms (including structure-activity relationship SAR study) revealed high antibacterial and moderate antifungal activities. Propoxylation of compounds 1, 3, 5, 6, 7 and 8 with 3, 5, 7 mol of propylene oxide produced nonionic surfactants I(a–c)–IX(a–c) having surface active properties so, it is clear that the tested surfactants can be used in the manufacture of dyes, drugs, cosmetics, emulsifiers, pesticides, luminphores for optical applications and many other industries with low toxicity to human beings and the environment owing to their high solubility and good biodegradability.     

A hybrid multiagent routing approach for wireless ad hoc networks

Wireless ad-hoc networks are infrastructureless networks that comprise wireless mobile nodes able to communicate each other outside wireless transmission range. Due to frequent network topology changes in one hand and the limited underlying bandwidth in the other hand, routing becomes a challenging task. In this paper we present a novel routing algorithm devoted for mobile ad hoc networks. It entails both reactive and proactive components. More precisely, the algorithm is based on ant general behavior, but differs from the classic ant methods inspired from Ant-Colony-Optimization algorithm [1]. We do not use, during the reactive phase, a broadcasting technique that exponentially increases the routing overhead, but we introduce a new reactive route discovery technique that considerably reduces the communication overhead. In the simulation results, we show that our protocol can outperform both Ad hoc On-demand Distance Vector (AODV) protocol [2], one of the most important current state-of-the-art algorithms, and AntHocNet protocol [5], one of the most important ant-based routing algorithms, in terms of end-to-end delay, packet delivery ratio and the communication overhead.     

Investigating the impact of Cloisite® 15A nanoclays on the diffusivity of Irganox 1035 antioxidant in high-density polyethylene nanocomposite

Knowing the diffusion coefficients of antioxidants in packaging materials is essential to assess their effectiveness in protecting materials against oxidation, but also to prevent their eventual migration to food. In this work, the diffusion of a commercial phenolic antioxidant (Irganox 1035) was measured experimentally in pristine high-density polyethylene (HDPE) and in HDPE nanocomposite filled with 3 wt% of nanoclays (Cloisite® 15A). Diffusion experiments were performed using the Roe's method between 60 and 100°C. The local concentration of Irganox1035 in each film was measured by UV–Vis spectroscopy from the UV absorbance at 282 nm. The adjustment of the experimental data by Fick's second law allowed us to deduce the values of the diffusion coefficient of Irganox1035 at each temperature and to show that the temperature dependence of this coefficient obeys an Arrhenius' law. It is shown that the incorporation of 3 wt% of Cloisite®15A into HDPE significantly hinders the diffusion of Irganox 1035 and increases its activation energy. Several mechanistic assumptions could explain this result, first the increase in the tortuosity of diffusion paths, but also the possible establishment of strong intermolecular interactions between the antioxidant and some chemical groups on the nanofiller surface, or even the formation of an interphase with reduced molecular mobility around the nanofillers.     

Analysis of TCP Vegas and TCP Reno

In this paper we use an analytic fluid approach in order to analyze the different features of both Vegas and Reno TCP versions. We then use simulations to confirm our analytic results. When the available bandwidth is high, indeed Vegas can retransmit less than one‐fifth as much data as Reno does, so that the higher the available bandwidth is, the more efficient Vegas is. However, under heavy congestion Vegas behaves like Reno and does not manage to make efficient use of its new mechanism for congestion detection. The analytic results that we obtain are the evolution of the window size, round trip times and their averages, and the average throughput. This revised version was published online in June 2006 with corrections to the Cover Date.