Shear effect on dynamic behavior of microcantilever beam with manufacturing process defects

This paper is concerned with the investigation of the shear effect on the dynamic behavior of a thin microcantilever beam with manufacturing process defects. Unlike the Rayleigh beam model (RBM), the Timoshenko beam model (TBM) takes in consideration the shear effect on the resonance frequency. This effect become significant for thin microcantilever beams with larger slenderness ratios that are normally encountered in MEMS devices such as sensors. The TBM model is presented and analyzed by numerical simulation using Finite Element Method (FEM) to determine corrective factors for the correction of the effect of manufacturing process defects like the underetching at the clamped end of the microbeam and the nonrectangular cross section of the area. A semi-analytical approach is proposed for the extraction of the Young’s modulus from 3D FEM simulation with COMSOL Multiphysics software. This model was tested on measurements of a thin chromium microcantilever beam of dimensions (80 × 2 × 0.95 μm³). Final results indicate that the correction of the effect of manufacturing process defects is significant where the corrected value of Young’s modulus is very close to the experimental results and it is about 280.81 GPa.

     

Cold alkali refining of cellulosic pulps derived from Egyptian cotton and bagasse

A cotton linter pulp, a bagasse dissolving pulp and a bagasse paper pulp were subjected to cold sodium hydroxide refining and the resulting changes in their chemical, physical and submicroscopic characteristics were investigated. In the case of cotton linters the main change took place in the physical and submicroscopic properties and the refining resulted in better reactivity towards xanthation. The α-cellulose content of the paper and viscose pulps increased with alkali concentration until it reached a constant value which depends on the type of pulp and the concentration of alkali. The refining of the paper and viscose pulps impaired their reactivity towards xanthation. The presence of the more hydrophilic hemicellulose increased the swelling ability of the fibres and made them more reactive towards xanthation. The undesirable effects of drying after refining with high alkali concentration could be overcome if the DP is sufficiently lowered. In this case the resulting shorter chain macromolecules dissolve more readily during xanthation.     

Rheological quantification of molecular parameters: Application to a hydrogen bond forming blend

The component dynamics and molecular parameters were investigated for miscible poly(4‐vinyl phenol)/poly(ethylene oxide) (PVPh/PEO) blends. Global values of molecular weight between entanglements (M_e) were first estimated for the blends and were compared with existing athermal model predictions. Global interchain friction coefficients (ξ) of the blends were deduced from the zero‐shear viscosity. A maximum was observed at a composition of 20–30 wt % of PEO. Chain dimensions of this phase are estimated by using a relationship between the plateau modulus and a packing length (i.e., number of individual chains present in a given small volume of the melt). A slight increase in M_e is observed at low PEO weight fraction (before 0.20), followed by a sharp decrease in M_e values after this concentration. Values of ξ in PVPh/PEO blends show a maximum value at 20–30 wt % of PEO. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 1623–1630, 2004     

Semi-supervised superpixel classification for medical images segmentation: application to detection of glaucoma disease

Glaucoma is a disease characterized by damaging the optic nerve head, this can result in severe vision loss. An early detection and a good treatment provided by the ophthalmologist are the keys to preventing optic nerve damage and vision loss from glaucoma. Its screening is based on the manual optic cup and disc segmentation to measure the vertical cup to disc ratio (CDR). However, obtaining the regions of interest by the expert ophthalmologist can be difficult and is often a tedious task. In most cases, the unlabeled images are more numerous than the labeled ones.We propose an automatic glaucoma screening approach named Super Pixels for Semi-Supervised Segmentation “SP3S”, which is a semi-supervised superpixel-by-superpixel classification method, consisting of three main steps. The first step has to prepare the labeled and unlabeled data, applying the superpixel method and bringing in an expert for the labeling of superpixels. In the second step, We incorporate prior knowledge of the optic cup and disc by including color and spatial information. In the final step, semi-supervised learning by the Co-forest classifier is trained only with a few number of labeled superpixels and a large number of unlabeled superpixels to generate a robust classifier. For the estimation of the optic cup and disc regions, the active geometric shape model is used to smooth the disc and cup boundary for the calculation of the CDR. The obtained results for glaucoma detection, via an automatic cup and disc segmentation, established a potential solution for glaucoma screening. The SP3S performance shows quantitatively and qualitatively similar correspondence with the expert segmentation, providing an interesting tool for semi-automatic recognition of the optic cup and disc in order to achieve a medical progress of glaucoma disease.     

Platinum‐Coated Hollow Graphene Nanocages as Cathode Used in Lithium‐Oxygen Batteries

One of the formidable challenges facing aprotic lithium‐oxygen (Li‐O₂) batteries is the high charge overpotential, which induces the formation of byproducts, loss in efficiency, and poor cycling performance. Herein, the synthesis of the ultrasmall Pt‐coated hollow graphene nanocages as cathode in Li‐O₂ batteries is reported. The charge voltage plateau can reduce to 3.2 V at the current density of 100 mA g^?1, even maintain below 3.5 V when the current density increased to 500 mA g^?1. The unique hollow graphene nanocages matrix can not only provide numerous nanoscale tri‐phase regions as active sites for efficient oxygen reduction, but also offer sufficient amount of mesoscale pores for rapid oxygen diffusion. Furthermore, with strong atomic‐level oxygen absorption into its subsurface, ultrasmall Pt catalytically serves as the nucleation site for Li₂O₂ growth. The Li₂O₂ is subsequently induced into a favorable form with small size and amorphous state, decomposed more easily during recharge. Meanwhile, the conductive hollow graphene substrate can enhance the catalytic activity of noble metal Pt catalysts due to the graphene‐metal interfacial interaction. Benefiting from the above synergistic effects between the hollow graphene nanocages and the nanosized Pt catalysts, the ultrasmall Pt‐decorated graphene nanocage cathode exhibits enhanced electrochemical performances.     

Comparative study of different crystallographic structure of LiNi0.5Mn1.5O4−δ cathodes with wide operation voltage (2.0-5.0 V)

LiNi_0.5Mn_1.5O_4−δ cathode materials with two different structures ( and P4₃32) were synthesized by ultrasonic spray pyrolysis method. The X-ray diffraction (XRD) data was confirmed that face-centered spinel () transformed into primitive simple cubic (P4₃32) structure by annealing process at 700 °C. In spite of two electrons operated cut-off voltage range between 2.0 and 5.0 V, LiNi_0.5Mn_1.5O₄ with P4₃32 structure has better electrochemical behaviors than the cathode with simple cubic structure. Ex situ XRD study of the electrode revealed that LiNi_0.5Mn_1.5O₄ (P4₃32) has reversible crystal transformation between fully lithiated state (2.0 V) and delithiated state (5.0 V) whereas LiNi_0.5Mn_1.5O_4−δ () showed irreversible phase transformed at two voltage region. The LiNi_0.5Mn_1.5O_4−δ () has voltage drop was occurred after 20th cycled compared without any voltage drop of the P4₃32 structure.     

Heat transfer inside a horizontal channel with an open trapezoidal enclosure subjected to a heat source of different lengths

The heat transfer phenomena inside a horizontal channel with an open trapezoidal enclosure subjected to a heat source of different lengths was investigated numerically in the present work. The heat source is considered as a local heating element of varying length, which is embedded at the bottom wall of the enclosure and maintained at a constant temperature. The air flow enters the channel horizontally at a constant cold temperature and a fixed velocity. The other walls of the enclosure and the channel are kept thermally insulated. The flow is assumed laminar, incompressible, and two‐dimensional, whereas the fluid is considered Newtonian. The results are presented in the form of the contours of velocity, isotherms, and Nusselt numbers profiles for various values of the dimensionless heat source lengths (0.16 ≤ ε ≤ 1). while, both Prandtl and Reynolds numbers are kept constant at (Pr = 0.71) and (Re = 100), respectively. The results indicated that the distribution of the isotherms depends significantly on the length of the heat source. Also, it was noted that both the local and the average Nusselt numbers increase as the local heat source length increases. Moreover, the maximum temperature is located near the heat source location.     

Structural and photoluminescence characterization of vertically aligned multiwalled carbon nanotubes coated with ZnO by magnetron sputtering

Zinc oxide (ZnO) nanostructures are very attractive in various optoelectronic applications such as light emitting devices. A fabrication process of these ZnO nanostructures which gives a good crystalline quality and being compatible with that of micro-fabrication has significant importance for practical application. In this work ZnO films with different thicknesses were deposited by RF-sputtering on vertically aligned multiwalled carbon nanotube (MWCNTs) template in order to obtain ZnO nanorods. The obtained hybrid structures (ZnO/MWCNTs) were characterized by scanning electron microscopy, X-ray diffraction, transmission electron microscopy, and time resolved photoluminescence spectroscopy (PL). Results show that the ZnO/MWCNTs have a nanorod structure like morphology with a good crystalline quality of the deposited ZnO on the MWCNTs. PL measurements reveal an enhancement of the band edge signal of ZnO/MWCNTs which is three times of magnitude higher compared to the ZnO film deposited on silicon. Moreover, the intensity enhancement varies as function of the ZnO thickness. Such hybrid structures are promising for optoelectronic application, such as blue-violet sources.     

Exfoliation and reassembly of cobalt oxide nanosheets into a reversible lithium-ion battery cathode

An exfoliation-reassembly-activation (ERA) approach to lithium-ion battery cathode fabrication is introduced, demonstrating that inactive HCoO(2) powder can be converted into a reversible Li(1-x) H(x) CoO(2) thin-film cathode. This strategy circumvents the inherent difficulties often associated with the powder processing of the layered solids typically employed as cathode materials. The delamination of HCoO(2) via a combination of chemical and mechanical exfoliation generates a highly processable aqueous dispersion of [CoO(2) ](-) nanosheets that is critical to the ERA approach. Following vacuum-assisted self-assembly to yield a thin-film cathode and ion exchange to activate this material, the generated cathodes exhibit excellent cyclability and discharge capacities approaching that of low-temperature-prepared LiCoO(2) (~83 mAh g(-1) ), with this good electrochemical performance attributable to the high degree of order in the reassembled cathode.