The derivatives of 1,3-benzodioxan (DBBD1) and 1,4-benzodioxan (DBBD2) bearing two tert-butyl groups have been synthesized as new redox shuttle additives for overcharge protection of lithium-ion batteries. Both compounds exhibit a reversible redox wave over 4 V vs Li/Li+ with better solubility in a commercial electrolyte (1.2 M LiPF6 dissolved in ethylene carbonate/ethyl methyl carbonate (EC/EMC 3/7) than the di-tert-butyl-substituted 1,4-dimethoxybenzene (DDB). The electrochemical stability of DBBD1 and DBBD2 was tested under charge/discharge cycles with 100% overcharge at each cycle in MCMB/LiFePO4 and Li4Ti5O12/LiFePO4 cells. DBBD2 shows significantly better performance than DBBD1 for both cell chemistries. The structural difference and reaction energies for decomposition have been studied by density functional calculations. 相似文献
Abstract The extraction behavior of Zn(II) and Cu(II) in acetate media has been investigated using dodecylhydroxydiphosphonic acid, DHDPA, which was previously synthesized and characterized. The extraction of both cations was carried out in different media with the addition of CH3COOH, HCl or H2SO4 at different pH. The maximum extraction yield of 80% for zinc, was obtained in one step after the addition of sulfuric acid at pHi=5.5 and for copper after the addition of 10 mg of sodium acetate. The authors plan additional tests using polar solvents. 相似文献
This paper is concerned with the investigation of the shear effect on the dynamic behavior of a thin microcantilever beam with manufacturing process defects. Unlike the Rayleigh beam model (RBM), the Timoshenko beam model (TBM) takes in consideration the shear effect on the resonance frequency. This effect become significant for thin microcantilever beams with larger slenderness ratios that are normally encountered in MEMS devices such as sensors. The TBM model is presented and analyzed by numerical simulation using Finite Element Method (FEM) to determine corrective factors for the correction of the effect of manufacturing process defects like the underetching at the clamped end of the microbeam and the nonrectangular cross section of the area. A semi-analytical approach is proposed for the extraction of the Young’s modulus from 3D FEM simulation with COMSOL Multiphysics software. This model was tested on measurements of a thin chromium microcantilever beam of dimensions (80 × 2 × 0.95 μm3). Final results indicate that the correction of the effect of manufacturing process defects is significant where the corrected value of Young’s modulus is very close to the experimental results and it is about 280.81 GPa.
As part of information retrieval systems (IRS) and in the context of the use of ontologies for documents and queries indexing, we propose and evaluate in this paper the contribution of this approach applied to Arabic texts. To do this we indexed a corpus of Arabic text using Arabic WordNet. The disambiguation of words was performed by applying the Lesk algorithm. The results obtained by our experiment allowed us to deduct the contribution of this approach in IRS for Arabic texts. 相似文献
With the advent of new haptic feedback devices, researchers are giving serious consideration to the incorporation of haptic communication in collaborative virtual environments. For instance, haptic interactions based tools can be used for medical and related education whereby students can train in minimal invasive surgery using virtual reality before approaching human subjects. To design virtual environments that support haptic communication, a deeper understanding of humans′ haptic interactions is required. In this paper, human′s haptic collaboration is investigated. A collaborative virtual environment was designed to support performing a shared manual task. To evaluate this system, 60 medical students participated to an experimental study. Participants were asked to perform in dyads a needle insertion task after a training period. Results show that compared to conventional training methods, a visual-haptic training improves user′s collaborative performance. In addition, we found that haptic interaction influences the partners′ verbal communication when sharing haptic information. This indicates that the haptic communication training changes the nature of the users′ mental representations. Finally, we found that haptic interactions increased the sense of copresence in the virtual environment: haptic communication facilitates users′ collaboration in a shared manual task within a shared virtual environment. Design implications for including haptic communication in virtual environments are outlined. 相似文献
This paper presents a comprehensive review of emerging technologies for the internet of things(IoT)-based smart agriculture.We begin by summarizing the existing surveys and describing emergent technologies for the agricultural IoT,such as unmanned aerial vehicles,wireless technologies,open-source IoT platforms,software defined networking(SDN),network function virtualization(NFV)technologies,cloud/fog computing,and middleware platforms.We also provide a classification of IoT applications for smart agriculture into seven categories:including smart monitoring,smart water management,agrochemicals applications,disease management,smart harvesting,supply chain management,and smart agricultural practices.Moreover,we provide a taxonomy and a side-by-side comparison of the state-ofthe-art methods toward supply chain management based on the blockchain technology for agricultural IoTs.Furthermore,we present real projects that use most of the aforementioned technologies,which demonstrate their great performance in the field of smart agriculture.Finally,we highlight open research challenges and discuss possible future research directions for agricultural IoTs. 相似文献
In this paper, an efficient architecture for the Finite Ridgelet Transform (FRIT) suitable for VLSI implementation based on
a parallel, systolic Finite Radon Transform (FRAT) and a Haar Discrete Wavelet Transform (DWT) sub-block, respectively is
presented. The FRAT sub-block is a novel parametrisable, scalable and high performance core with a time complexity of O(p2), where p is the block size. Field Programmable Gate Array (FPGA) and Application Specific Integrated Circuit (ASIC) implementations
are carried out to analyse the performance of the FRIT core developed.
Gene expression data usually contain a large number of genes, but a small number of samples. Feature selection for gene expression data aims at finding a set of genes that best discriminates biological samples of different types. In this paper, we propose a two-stage selection algorithm for genomic data by combining MRMR (Minimum Redundancy–Maximum Relevance) and GA (Genetic Algorithm). In the first stage, MRMR is used to filter noisy and redundant genes in high-dimensional microarray data. In the second stage, the GA uses the classifier accuracy as a fitness function to select the highly discriminating genes. The proposed method is tested for tumor classification on five open datasets: NCI, Lymphoma, Lung, Leukemia and Colon using Support Vector Machine (SVM) and Naïve Bayes (NB) classifiers. The comparison of the MRMR-GA with MRMR filter and GA wrapper shows that our method is able to find the smallest gene subset that gives the most classification accuracy in leave-one-out cross-validation (LOOCV). 相似文献
Layout problems are found in several types of manufacturing systems. Typically, layout problems are related to the location of facilities (e.g., machines, departments) in a plant. They are known to greatly impact the system performance. Most of these problems are NP hard. Numerous research works related to facility layout have been published. A few literature reviews exist, but they are not recent or are restricted to certain specific aspects of these problems. The literature analysis given here is recent and not restricted to specific considerations about layout design.
We suggest a general framework to analyze the literature and present existing works using such criteria as: the manufacturing system features, static/dynamic considerations, continual/discrete representation, problem formulation, and resolution approach. Several research directions are pointed out and discussed in our conclusion. 相似文献
The absence of short vowels in Arabic texts is the source of some difficulties in several automatic processing systems of Arabic language. Several developed hybrid systems of automatic diacritization of the Arabic texts are presented and evaluated in this paper. All these approaches are based on three phases: a morphological step followed by statistical phases based on Hidden Markov Model at the word level and at the character level. The two versions of the morpho-syntactic analyzer Alkhalil were used and tested and the outputs of this stage are the different possible diacritizations of words. A lexical database containing the most frequent words in the Arabic language has been incorporated into some systems in order to make the system faster. The learning step was performed on a large Arabic corpus and the impact of the size of this learning corpus on the performance of the system was studied. The systems use smoothing techniques to circumvent the problem of missing transitions words and the Viterbi algorithm to select the optimal solution. Our proposed system that benefits from the wealth of morphological analysis and a large diacritized corpus presents interesting experimental results in comparison to other automatic diacritization systems known until now. 相似文献