Extraction of coals through dilute alkaline hydrolytic treatment at low temperature and ambient pressure

Assam and Talcher (bituminous) coals have been subjected to batch aqueous alkali treatment followed by extraction. It has been shown that alkali treatment increased extractability and reactivity of coal. Use of 1.4% aqueous sodium hydroxide was found to be capable of rendering about 40–50% coal extractable in ethylene diamine in two alkali treatments followed by extractions. Semibatch operation yielded about 26–33% extractable coal, and extraction data were found to be comparable with those obtained in batch degradation via a single alkali treatment. Of the solvents studied, polar and basic solvents were found to be the most effective.     

Differential regulation by estrogens of growth and prolactin synthesis in pituitary cells suggests that only a small pool of estrogen receptors is required for growth

PR1 cells are a prolactin (PRL)-secreting cell line derived from a pituitary lactotroph tumor found in 17beta-estradiol-treated Fischer 344 rats. We examined the effect of estrogen on cell proliferation and PRL synthesis under various culture conditions. Estrogen, at extremely low concentrations, induces cell proliferation in this cell line, whereas antiestrogen inhibits proliferation. Interestingly, the proliferation response is much more sensitive than the PRL response because 0.01 pM estradiol or diethylstilbestrol induces half-maximal growth induction [ approximately 0.1% estrogen receptor (ER) occupancy is required], whereas 0.01 nM concentration is required for half-maximal PRL induction ( approximately 50% ER occupancy is required). The proliferation response is not as sensitive to antiestrogen as the PRL response, because 10 nM concentration of the pure antiestrogen ICI 182,780 could not inhibit 1 nM estradiol- or diethylstilbestrol-induced proliferation. The same concentration of ICI 182,780 decreased PRL secretion to 1% of estradiol- or diethylstilbestrol-induced prolactin secretion suggesting a possible dichotomy of ER control of proliferation and PRL synthesis. The Kd of ER binding in these cells is about 3 x 10(-11) M. These results with the PR1 cells extend previous studies in other estrogen- regulated systems and suggest that only a small pool of ER is required for cell proliferation in contrast with the regulation of expression of specific genes. They also raise questions as to how a dimeric receptor functions when only one ligand site is occupied or when both an estrogen and an antiestrogen occupy one dimer.     

Effect of ash on maximum thickness of plastic layer of coals

A study of the effect of ash yield on the maximum thickness of the plastic layer (MTPL) of some coking coals (as measured by the Sapozhnikov plastometer) has revealed that with an increase in the former the latter in general decre?es. A rectilinear relation approximately exists between the ash percentage (dry basis) and log MTPL values of coals. For the samples studied, a multiple correlation incorporating the rank factor was found to be unnecessary. Higher Fe₂O₃ and SO₃ contents from the coal were found to be associated with higher MTPL values.     

Impact fatigue of an alumina ceramic

A new type of pendulum impact apparatus is described for determining single and repeated impact strength of ceramics, It has been demonstrated that specimens of a Sintox alumina ceramic exhibit fatigue behaviour, having a high stress plateau followed by progressively increasing endurance with decrease in applied impact energy. A fatigue limit, at least from the engineering view point, has been drawn at high endurances (10⁵ impacts). The influence of environment (static fatigue) and/or plastic deformation to explain the fatigue behaviour is suggested.     

Antiredeposition additives face new opportunities

Recent trends in fabric composition, choice of raw materials, and government regulations are placing new demands on the use and utility of antiredeposition additives.     

Generation of Bessel functions of complex order and argument

Recurrence techniques are described for the generation of Bessel functions of the first and second kinds where both the argument and order may be complex. The method is shown to be accurate for several well known forms of functions, including Kelvin and spherical Bessel functions. The accuracy of the general case of complex order and argument is determined by computing the Wronskians and by verifying some addition theorems of the Bessel functions over wide ranges of order and argument. Procedures for the accurate generation of complex-argument gamma functions are also described.     

Algebraic relations between system response and system parameters for linear time-invariant systems

By means of a rational-fraction approximation to the delay function, and through use of a generalised technique for evaluating convolution integrals, it is possible to approximately evaluate the inverse Laplace transform. The time-domain response is approximated by a ratio of polynomials in t, with coefficients which are algebraic functions of the system parameters.     

Precipitation phase transformation in nanocrystalline Fe-Mo alloys

Precipitation phase transformation was studied in nanocrystalline Fe-rich Fe-Mo alloys with the use of X-ray diffraction and M?ssbauer spectroscopy. Alloys up to 5 at% Mo in Fe were synthesized by mechanical alloying and formed in alpha phase bcc solid solutions with average grain sizes in the range of 10-13 nm. The precipitation transformation (alpha-->alpha + lambda) was found to proceed via a Mo clustering that was correlated with the size of the nanograins. This was understood in terms of the Gibbs Thomson effect with a concept of negative surface energy contribution to the Gibbs free energy of mixing in a nanocrystalline alloy with positive internal energy of mixing. This contribution increased the stability of the solid solution for nanosized grains, and the Mo precipitation started once the grains grew beyond a critical size. We argue that the Mo precipitation takes place in the grain boundary regions, and the Mo-rich lambda phase also precipitates directly in the grain boundary regions, in contrast to the microcrystalline alloys, where the Mo clusters formed within the grains and were first dissolved in the Fe matrix before the lambda phase was formed.     

Structuring Optimizing Transformations and Proving Them Sound

A compiler optimization is sound if the optimized program that it produces is semantically equivalent to the input program. The proofs of semantic equivalence are usually tedious. To reduce the efforts required, we identify a set of common transformation primitives that can be composed sequentially to obtain specifications of optimizing transformations. We also identify the conditions under which the transformation primitives preserve semantics and prove their sufficiency. Consequently, proving the soundness of an optimization reduces to showing that the soundness conditions of the underlying transformation primitives are satisfied.The program analysis required for optimization is defined over the input program whereas the soundness conditions of a transformation primitive need to be shown on the version of the program on which it is applied. We express both in a temporal logic. We also develop a logic called temporal transformation logic to correlate temporal properties over a program (seen as a Kripke structure) and its transformation.An interesting possibility created by this approach is a novel scheme for validating optimizer implementations. An optimizer can be instrumented to generate a trace of its transformations in terms of the transformation primitives. Conformance of the trace with the optimizer can be checked through simulation. If soundness conditions of the underlying primitives are satisfied by the trace then it preserves semantics.