Entschwefelung von gerührtem und ungerührtem Roheisen mit kalkreicher Schlacke unter oxidierender Gasatmosphäre

Aus Betriebsergebnissen bei der Pfannenentschwefelung ist ein negativer Einfluß oxidierender Gasphasen bekannt. Daher war es das Ziel der eigenen Untersuchungen in einer geeigneten Apparatur die Wirkung oxidierender Bedingungen in der Gasphase sowohl auf den Verlauf des Schwefelabbaues in der Schlacke als auch des Schwefeltransportes aus dem Roheisen in die Schlacke zu untersuchen. Oxidierende Gasphasen erwirken bei der Pfannenentschwefelung an der Phasengrenze Schlacke/Gas eine Oxidation des Schwefels aus der Schlacke, ohne jedoch bei ruhender Schlackenschicht ein Oxidationspotential in der Schlacke aufzubauen, das bis zur Phasengrenze Roheisen/Schlacke durchgreift und dort die Entschwefelung des Roheisens durch die Siliciumgehalte stört. Sowohl die Entschwefelung des Roheisens als auch die Oxidation des Schwefels aus der Schlacke werden durch höhere Temperaturen und durch eine Rührwirkung gefördert. Der Schwefeltransport wird bei den ungerührten wie bei den gerührten Schmelzen durch Diffusionsvorgänge gesteuert und auch hier durch steigende Temperaturen und rührende Kräfte begünstigt.     

Das Twinning-Programm der Europäischen Union: Praktische Erfahrungen in der Umsetzung von veterinärmedizinischen Verwaltungspartnerschaften

Zusammenfassung:  Mit Verwirklichung des gemeinsamen Binnenmarktes ab 01.01.1993 wurde ein freier Warenverkehr innerhalb der Europ?ischen Union mit Wegfall zwischenstaatlicher Kontrollen im tiergesundheitlichen und lebensmittelsicher-heitsrelevanten Bereich realisiert. In allen Mitgliedstaaten soll ein vergleichbares Schutzniveau bzgl. des gesundheitlichen Verbraucherschutzes erfüllt werden. In der Praxis hat sich jedoch gezeigt, dass die Anwendung des EU-Rechtes in den neuen Mitgliedstaaten teilweise noch Schwierigkeiten bereitet. Vor diesem Hintergrund sind von der Kommission verschiedene Fortbildungs- und F?rderma?nahmen mit der Zielsetzung entwickelt worden, vorhandene Defizite in diesem Bereich zu minimieren. Dazu z?hlen die seit 1998 von der Kommission initiierten sog. Twinning-Projekte (Verwaltungspartnerschaften) zwischen Beh?rden alter und neuer Mitgliedstaaten. Seit diesem Zeitpunkt wurden mehr als 1100 Twinning-Projekte durchgeführt, davon fast 300 Projekte unter deutscher Leitung (Schwerpunkt: Landwirtschaftlicher Bereich). Im vorliegenden Artikel werden Bedeutung und Inhalte von Twinning-Projekten im Veterin?r- und Lebensmittelbereich dargestellt. Ihr formales Verfahren sowie die in den Verwaltungspartnerschaften gewonnenen Erfahrungen und M?glichkeiten der Verbesserung werden erl?utert.

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The Twinning-Programme of the European Union: Experiences in the implementation of Twinning- projects in veterinary and food affairs. Since 01.01.1993 a common market was built up within the EU with cancelling of border controls of foods, animal products and living animals. An equal level of consumer protection should be established in all member states. In practice however, implementation of EU food and feed legislation in the new member states often causes problems. To reduce deficiencies in this field, the EU commission developed several measures of training and strenghtening for new member states. These measures include the so called Twinning-projects between competent authorities of old and new member states, which have been initiated since 1998. More than 1100 Twinning projects have been performed so far, including about 300 projects in Germany (with emphasis on agriculture). This article shows meaning and contents of Twinning-projects in the field of veterinary and food affairs. Formal procedures, experiences and possibilities of improvement of twinning-projects are described.

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Eingegangen: 16. Januar 2008     

Zoonotic Brugian lymphadenitis. An unusual case with florid monocytoid B-cell proliferation

Human infection with a zoonotic Brugia species in the United States is uncommon. Positive identification of the filarial nematode is required for histopathologic diagnosis. Many cases may go unrecognized because of the nonspecific clinical manifestations and the nondiagnostic histologic changes occurring in involved lymph nodes. A case of zoonotic Brugia lymphadenitis is described in a patient from Rhode Island, in which a small nongravid female worm was identified in a lymph node biopsy specimen. The lymph node also showed a spectrum of reaction changes including the presence of florid monocytoid B-cell proliferation, which has not been described in association with zoonotic Brugian filariasis.     

Darstellung komplexer Betriebsschlacken des LD-Verfahrens im Quasidreistoffsystem

Aus der Darstellung der Schlackenzusammensetzungen im Quasidreistoffsystem ist die Lage der Schlacken zur Kalksättigungslinie deutlich zu erkennen. Die Sublanzenschlacken lassen den Schlackenweg während der letzten Blasminuten erkennen, durch Bodenspülung und Nachspülen wird eine geringe Annäherung an die Kalksättigungslinie erreicht. Aus der Lage der Schlacken im Quasidreistoffsystem läßt sich der Einfluß der Temperatur auf den Verlauf der Kalksättigung entlang unterschiedlicher T-X-Schnitte bestimmen.     

Effect of center block structure on the physical and rheological properties of ABA block copolymers. Part II. Rheological properties

The effect of the chemical structure of the center block on the rheological properties of ABA block copolymers with polystyrene end blocks has been investigated. The chemical structure of the center blocks investigated in the present paper are polybutadiene, polyisoprene, ethylene/butene copolymer, ethylene/propylene copolymer and polydimethyl-siloxane. The chemical structure of the center block was found to have a pronounced effect on the rheological properties of the ABA block copolymer melts. The long range relaxation times of these block copolymer melts increases with increasing incompatibility between the styrene block and the center block. However, the rheological properties of the block copolymers are not influenced significantly by the glass transition or the entanglement molecular weight of the center block.     

Der Sicherheitsaspekt beim Eintrag von Schüttgütern in Behälter

Safety aspects of charging bulk material into vessels or containers . The safe charging of bulk material requires a careful analysis of the potential sources of danger which can result from the physical properties of the materials and the design and construction material of plant and equipment. The method adopted in this analysis is illustrated and explained for selected examples. Criteria for safe charging methods are compiled and explained. A selection of proven charging equipment is listed and technically evaluated with respect to safety and operating criteria. Steps that must be taken to avoid charging errors are discussed. Special problems encountered on connecting pressureless charging devices to pressure vessels are outlined explained. The utilization of inert gas as a preferred method of explosion protection is discussed. Various methods are compared, and their application to special problems in charging bulk material is illustrated.     

Metallchelate ungesättigter 1,2-Dithioäther

Metal Chelates of Unsaturated 1,2-Dithioethers The dialkyl- and diaralkyldithioethers of ethylenebisthiol (edt) and xylenedithiol form cationic 1:2 chelates with the d⁸-metal ions Ag^I and Cu^I, which have been isolated and characterized. Pd^II- and Pt^II-halides yield neutral mixed ligand complexes of the type Me (L L) X₂ (L L = dithioether, X = halogen). The dibenzyldithioether of edt is cleaved oxidatively by Cu^II and yields dibenzyldisulfide, Cu^I and an unidentified product.     

Network Discovery and Verification

Due to its fast, dynamic, and distributed growth process, it is hard to obtain an accurate map of the Internet. In many cases, such a map-representing the structure of the Internet as a graph with nodes and links-is a prerequisite when investigating properties of the Internet. A common way to obtain such maps is to make certain local measurements at a small subset of the nodes, and then to combine these in order to "discover" (an approximation of) the actual graph. Each of these measurements is potentially quite costly. It is thus a natural objective to minimize the number of measurements which still discover the whole graph. We formalize this problem as a combinatorial optimization problem and consider it for two different models characterized by different types of measurements. We give several upper and lower bounds on the competitive ratio (for the online network discovery problem) and the approximation ratio (for the offline network verification problem) in both models. Furthermore, for one of the two models, we compare four simple greedy strategies in an experimental analysis     

Analysis of free amino acids in green coffee beans

To investigate amino acid changes in green coffee beans in the post-harvest period, amino acid concentrations were determined in green beans and after modelled drying, fermentation and storage. After the drying at alternating temperatures up to maximally 40°C, considerable changes in the concentrations of individual amino acids were identified. At the beginning of the storage period, significant changes in concentration were found to a minor extent. Under the condition of drying, it was mainly the concentration of glutamic acid that changed considerably. There was an increase in all the samples by 500 mg/kg dry matter on average, which corresponds to an increase of about 50% of the original value. In contrast, the concentration of aspartic acid in most of the samples decreased clearly due to drying. For the predominant part of the coffee samples, there was a significant increase in the hydrophobic amino acids Val, Phe, Ile and Leu. Changes of the quantities of other amino acids were non-uniform and only insignificant. Constant drying at 80°C for most of the amino acids brought about only minor concentration changes compared to those values obtained at 40°C. Modelled fermentation had no significant effect on the concentrations of the individual amino acids. After a 4-week storage of dried beans, amino acid concentrations did not change further. It is very possible that different post-harvest treatment parameters may influence the amount of aroma precursor compounds in the coffee beans.