Fines Accumulation and Distribution in a Storm-Water Rain Garden Nine Years Postconstruction

Storm water control measures (SCMs), also known as best management practices (BMPs), such as rain gardens, are designed to infiltrate storm-water runoff and reduce pollutant transport to surface waters. The life span of these SCMs may be limited depending on the composition of sediments in runoff water. Settling of fine sediments may clog soil pore spaces, reducing the infiltration capacity of the soil and reducing the potential benefits of this SCM. A study was conducted on a Villanova campus rain garden that accepts runoff from an adjacent parking lot to determine if there was a relationship between the accumulation of fine sediments over time and the infiltration capacity. The soil textural profile within the rain garden was characterized prior to SCM installation (2001), after installation, after five years, and after seven years of receiving storm-water runoff. Infiltration data were collected by the single-ring infiltrometer method in 2006 and 2009. Differences in soil texture were found between locations within the infiltration basin, and accumulation of fines smaller than 0.1 mm was observed at both locations sampled in 2009. Infiltration rates were significantly different between the two locations measured within the rain garden, but infiltration rates did not change significantly over time within those regions. This SCM was designed at a 10:1 watershed to SCM area ratio, which is twice what is recommended by the PA DEP BMP Manual. The data collected over the seven years since installation indicate that while fines have accumulated in the SCM there has been no significant change in infiltration potential.     

Carbon nanotubes/polydimethylsiloxanes systems for thermal management of miniaturized electronic components

The thermal performances of nanocomposite layers formed by Single-walled Carbon Nanotubes (SWCNT) dispersed in 2 different kind of polydimethyl-siloxane (PDMSO) matrices has been investigated by measuring the thermal resistance under conditions similar to the ones used for thermal management in microelectronics. A series of nanocomposite samples with thickness in the range 25 microm(-1) cm have been tested. The nanocomposites were prepared varying the amounts of nanotubes embedded in the matrix (from 0.1 to 5%w). In some cases also microsized graphites were mixed to the nanotube's fillers. For 25 micron thick layers, the thermal resistance of the neat silicone specimen can be reduced of 54% with the addition of 2%w carbon nanotubes. The variation of thermal conductivity as a function of the SWCNT's loading is reported and discussed. Furthermore the dispersion's effects of the nanotubes in the layers and the effects on the realization of a net-like system have been investigated.     

Carbon nanotube-based nanocarriers: the importance of keeping it clean

Nanotechnology-introduced materials have promising applications as nanocarriers for drugs, peptides, proteins and nucleic acids. Several studies showed that the geometry (shape and size) and chemical properties of nanoparticles affect the kinetics and pathways of cellular uptake and their intracellular trafficking and signaling. Accurate physico-chemical characterization of nanoparticles customarily precedes their use in cell biology and in vivo experiments. However, a fact that is easily overlooked is that nanomaterials decorated with organic matter or resuspended in aqueous buffers can be theoretically contaminated by fungal and bacterial microorganisms. While investigating the effects of extensively characterized PEGylated carbon nanotubes (PNTs) on T lymphocyte activation, we demonstrated bacterial contamination of PNTs, which correlated with low reproducibility and artifacts in cell signaling assays. Contamination and artifacts were easily eliminated by preparing the materials in sterile conditions. We propose that simple sterile preparation procedures should be adopted and sterility evaluation of nanoparticles should be customarily performed, prior to assessing nanoparticle intracellular internalization, trafficking and their effects on cells and entire organisms.     

Microstructure and mechanical properties of co-continuous metal/ceramic composites obtained from Reactive Metal Penetration of commercial aluminium alloys into cordierite

Co-continuous metal/ceramic composites were obtained by the Reactive Metal Penetration (RMP) method. With the aim of components cost reduction, commercial cordierite preforms and standard aluminium infiltrating alloys (1050, 2011 and 7075) were used in the process. Kinetics of the infiltration reaction, microstructure and mechanical properties of the composites were found to be influenced by both quantity and type of alloying elements. In particular, while Young’s modulus remains quite constant, a marked increase in microhardness is observed with 2011 and 7075 alloys, even if to the detriment of flexural strength.     

Fatigue behaviour of concrete bridge deck slabs reinforced with GFRP bars

GFRP bars are often used for the internal reinforcement of concrete bridge deck slabs as an alternative to traditional steel reinforcements with excellent results in terms of corrosion resistance. Several experiments on bridge decks were conducted to evaluate their structural behaviour but their fatigue performance still needs an adequate experimental investigation. This paper presents the results of an experimental campaign on four full scale concrete bridge deck specimens reinforced with GFRP bars that were designed, constructed and tested to resist cyclic moving loads. Two hydraulic jacks were used to simulate moving concentrated loads. After the cycles, the load was increased to the static failure. The slabs reinforced with GFRP bars showed a better fatigue performance compared to the requests of the European codes.     

A multifractal analysis of fatigue crack growth and its application to concrete

As is well-known, strength of materials is influenced by the specimen or structure size. In particular, several experimental campaigns have shown a decrease of the material strength under static or fatigue loading with increasing structure size, and some theoretical arguments have been proposed to interpret such a phenomenon. As far as fatigue crack growth is concerned, limited information on size effect is available in the literature, particularly for so-called quasi-brittle materials like concrete. In the present paper, by exploiting concepts of fractal geometry, some definitions of fracture energy and stress intensity factor based on physical dimensions different from the classical ones are discussed. A multifractal size-dependent fatigue crack growth law (expressing crack growth rate against stress intensity factor range) is proposed and used to interpret relevant experimental data related to concrete.     

PPy doped PEG conducting polymer films synthesized on LiFePO4 particles

In this work, polyethyleneglycole (PEG) is introduced into polypyrrole (PPy) film coated on LiFePO₄ powder particles to promote the properties of cathode material for lithium-ion batteries. The enhancement of the electrochemical activity by the substitution of a carbon with electrochemically active polymer is investigated. Films of the PPy doped with the PEG were prepared by the chemical oxidative polymerization of pyrrole (Py) monomer. PEG has been added as an additive during polymerization process to improve mechanical and structural properties of the PPy in final PPy/PEG-LiFePO₄ cathode material. Cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and galvanostatic charge/discharge measurements were employed to characterize the electrochemical properties of PPy/PEG-LiFePO₄ material. The electrochemical performance of PPy-LiFePO₄ electrodes was greatly improved by introduction of PEG into the PPy films. Charge/discharge measurements confirmed the increase in capacity when applying PEG in PPy. The morphology and particle sizes of the prepared cathode powder material were investigated by scanning electron microscopy (SEM) and particle size analysis (PSA). Distribution of PPy and PPy/PEG films onto the LiFePO₄ particles surface was studied by time of flight secondary ion mass spectrometry (TOF-SIMS). In addition to polymeric coating layer on the surface of PPy-LiFePO₄ composite particles, some PPy unequally distributed between the particles was found. The median diameter value is 4.92 μm for PPy-LiFePO₄ sample. TOF-SIMS measurements and SEM images confirmed that thickness of polypyrrole coating on LiFePO₄ particles is about 100 nm.     

Sodium borohydride as an additive to enhance the performance of direct ethanol fuel cells

The effect of adding small quantities (0.1-1 wt.%) of sodium borohydride (NaBH₄) to the anolyte solution of direct ethanol fuel cells (DEFCs) with membrane-electrode assemblies constituted by nanosized Pd/C anode, Fe-Co cathode and anion-exchange membrane (Tokuyama A006) was investigated by means of various techniques. These include cyclic voltammetry, in situ FTIR spectroelectrochemistry, a study of the performance of monoplanar fuel cells and an analysis of the ethanol oxidation products. A comparison with fuel cells fed with aqueous solutions of ethanol proved unambiguously the existence of a promoting effect of NaBH₄ on the ethanol oxidation. Indeed, the potentiodynamic curves of the ethanol-NaBH₄ mixtures showed higher power and current densities, accompanied by a remarkable increase in the fuel consumption at comparable working time of the cell. A ¹³C and ¹¹B {¹H}NMR analysis of the cell exhausts and an in situ FTIR spectroelectrochemical study showed that ethanol is converted selectively to acetate while the oxidation product of NaBH₄ is sodium metaborate (NaBO₂). The enhancement of the overall cell performance has been explained in terms of the ability of NaBH₄ to reduce the PdO layer on the catalyst surface.     

Measurement method and results of ice adhesion force on the curved surface of a wind turbine blade

Experimental adhesion force measurements were conducted on accumulated ice on the leading edge of a scaled wind turbine blade in both glaze and rime icing regimes. An apparatus was first designed for specifically measuring the adhesion force of ice on a curved surface at climatic temperature where a vertical force was applied to the mounted structure in the test apparatus. Adhesion force measurements were measured and adhesion pressure calculated for plain and ice-mitigated test specimens. Results are presented for the increase in force of ice adhesion over a curved surface area in proportion to degree centigrade decrease in temperature.     

Why attend school? Chinese immigrant and European American preschoolers' views and outcomes.

The developing views of the purposes of school learning (PSLs) and related achievement among immigrant Chinese preschoolers and their European American (EA) age-mates were examined. Both culture and socioeconomic status (SES) were considered simultaneously, an often neglected research approach to studying Asian children. One hundred and fifty 4-year-olds—50 each of middle-class Chinese (CHM), low-income Chinese (CHL), and EA children—completed 2 story beginnings about school and were also tested for their language and math achievement. Results showed that 4-year-olds held sophisticated PSLs, ranging from intellectual to social and affect benefits. Large cultural and SES differences also emerged. CHM children mentioned more adult expectation and seriousness of learning than EA children who expressed more positive affect for self and compliance with adults. CHL children mentioned fewest PSLs. Achievement scores for oral expression of both immigrant groups were significantly lower than those of EA children despite similar reading and math achievement. Controlling for culture and SES, the authors found that children's articulated intellectual, but not other purposes, uniquely predicted their achievement in all tested domains. Cultural and SES influences on immigrant children are discussed. (PsycINFO Database Record (c) 2010 APA, all rights reserved)