Laminar burning velocity with oxygen-enriched air of syngas produced from biomass gasification

Several studies on the laminar burning velocity of syngas mixtures have been conducted by various researchers. However, in most of these studies, dry air was used as the oxidizer, whereas very few studies have been conducted on syngas combustion in oxygen – enriched air. In this work, a numerical and experimental study on the laminar burning velocity of a mixture of H₂, CO and N₂ (20:20:60 vol%) was performed using air enriched with oxygen as the oxidizer, varying the oxygen content from 21% up to 35% for different equivalence ratios. Numerical calculations were conducted using three detailed reaction mechanisms and transport properties. Flames were generated using contoured slot-type nozzle burners, and Schlieren images were used to determine the laminar burning velocity with the angle method. The experiments were performed under the conditions of Medellin (1550 m.a.s.l.), 0.838 atm and 298 K. The laminar burning velocity increases with the concentration of the oxygen in the mixture due to the increase of the reaction rate; for a stoichiometric mixture, the laminar burning velocity increases by almost 25% with an increment of 4% of oxygen in the oxidant. However, the flammability limits also increase, allowing stable flames to exist in a wider range of equivalence ratios.     

Nitroxide‐mediated synthesis of styrenic‐based segmented and tapered block copolymers using poly(lactide)‐functionalized TEMPO macromediators

Poly(styrene)‐poly(lactide) (PS‐PLA), poly (tert‐butyl styrene)‐poly(lactide) (PtBuS‐PLA) diblocks, and poly(tert‐butyl styrene)‐poly(styrene)‐poly(lactide) (PtBuS‐PS‐PLA) segmented and tapered triblocks of controlled segment lengths were synthesized using nitroxide‐mediated controlled radical polymerization. Well‐defined PLA‐functionalized macromediators derived from hydroxyl terminated TEMPO (PLA_T) of various molecular weights mediated polymerizations of the styrenic monomers in bulk and in dimethylformamide (DMF) solution at 120–130°C. PS‐PLA and PtBuS‐PLA diblocks were characterized by narrow molecular weight distributions (polydispersity index (M_w/M_n) < 1.3) when using the PLA_T mediator with the lowest number average molecular weight M_n= 6.1 kg/mol while broader molecular weight distributions were exhibited (M_w/M_n = 1.47‐1.65) when using higher molecular weight mediators (M_n = 7.4 kg/mol and 11.3 kg/mol). Segmented PtBuS‐PS‐PLA triblocks were initiated cleanly from PtBuS‐PLA diblocks although polymerizations were very rapid with PS segments ～ 5–10 kg/mol added within 3–10 min of polymerization at 130°C in 50 wt % DMF solution. Tapering from the PtBuS to the PS segment in semibatch mode at a lower temperature of 120°C and in 50 wt % DMF solution was effective in incorporating a short random segment of PtBuS‐ran‐PS while maintaining a relatively narrow monomodal molecular weight distribution (M_w/M_n ≈ 1.5). © 2008 Wiley Periodicals, Inc. J Appl Polym Sci 2008     

Facetted patchy particles through entropy-driven patterning of mixed ligand SAMS

We present a microscopic theory that describes the ordering of two distinct ligands on the surface of a facetted nanoparticle. The theory predicts that when one type of ligand is significantly bulkier than all others, the larger ligands preferentially align themselves along the edges and vertices of the nanoparticle. Monte Carlo simulations confirm these predictions. We show that the intrinsic conformational entropy of the ligands stabilizes this novel edge-aligned phase.     

Fire Department Attended and Unattended Fires: Estimates from the 2004–2005 National Sample Survey and Comparison with Previous Surveys

Previous national surveys in 1974 and 1984 have shown that although attended and unattended fires differed substantially in severity and fire losses, there were between 10 and 29 unwanted residential fires for every fire reported to, or attended by, U.S. fire departments. The study objective was to obtain new estimates of fires not attended by fire departments. Interest in unattended fires derives from the understanding that most fires begin small, then unless controlled, grow until fire department assistance is needed. To update these analyses, a national telephone survey was conducted during 2004 and 2005. The survey had 916 respondents who reported one or more residential fires during the previous 90-day period. The principal methodological issues in analyzing the survey data included: (1) determining the optimum recall period to balance sampling variance and bias, and (2) imputing incompletely specified fire dates. The resulting estimates were 7.2 million unattended residential fires per year, a 69% decrease from the 1984 survey estimate of 22.9 million fires. During the same time period, fire department attended residential fires decreased by 36%. The greater decrease in unattended fires is at variance with the conjecture in the 1984 survey that increasing availability of smoke alarms would result in more fires detected at an earlier stage when they could be controlled by residents; a conjecture that would predict a greater decrease in attended rather than unattended fires.     

Effect of the thermo‐alkaline treatment over the thermal degradation of corn starch

In this work, thermogravimetric data were used for to study the thermal degradation of corn starch with and without thermo‐alkaline treatment. Flynn–Wall–Ozawa, modified Coats–Redfern, and Kissinger methods were used to determine the activation energy. Corn starch treated with calcium hydroxide exhibited the highest activation energy values during the whole thermal degradation process which could be related to the physical crosslinking process between starch constituents and Ca ions as was confirmed by the infrared analysis. The energy activation was dependent of the conversion, indicating that this degradation is a complex process. DSC at high temperatures, used for starch, corroborated that the degradation in this material is a complex process governed by different chemical reactions. Thermo‐alkaline treatment has a decelerator role in thermal degradation of corn starch.     

Temperature Control of a Thermal Plasma Torch with Inductive Coupling Using the Arduino Board

Plasma torch is a device that transforms electrical energy into heat carried by a gas and its safe operation is necessary to control her temperature. This paper presents the use of the Arduino board in temperature control of a plasma torch through fuzzy control. The plasma torch of this project was built so that a flow of water can circulate through your body, allowing its cooling. The cooling system mounted consists of one radiator, one expansion vase, one water pump and one temperature sensor. The heated water coming the plasma torch is passed by the temperature sensor. This is converted in a voltage and read by an analog input port of the Arduino. This processes the information received and makes the decision to turn on/off the radiator fan and/or powered the frequency inverter water pump to control the temperature. The graph of the fuzzy control showed an oscillation between 104 °F to 122 °F around the chosen reference 113 °F. The results show that it is possible to control the temperature of a plasma torch using the Arduino board and fuzzy logic.     

Organic-based molecular switches for molecular electronics

In a general sense, molecular electronics (ME) is the branch of nanotechnology which studies the application of molecular building blocks for the fabrication of electronic components. Among the different types of molecules, organic compounds have been revealed as promising candidates for ME, due to the easy access, great structural diversity and suitable electronic and mechanical properties. Thanks to these useful capabilities, organic molecules have been used to emulate electronic devices at the nanoscopic scale. In this feature article, we present the diverse strategies used to develop organic switches towards ME with special attention to non-volatile systems.     

Effects of Fluid Inertia on Finite-Length Squeeze-Film Dampers

The influence of fluid inertia on the SFD force response to circular-centered motions of arbitrary amplitude is analyzed in detail, For finite length, locally sealed SFDs, integro-differential equations are derived in terms of the mean flow components. Numerical predictions, using the finite-element method, show that the damping and added mass coefficients remain invariant as the Reynolds number increases from small values to a moderate Reynolds number equal to 10. An approximate, finite-length, solution for the fluid-film forces has been analytically obtained which accounts for the fluid-inertia effect as well as local end seal effects in symmetric SFD configurations. The approximate solution, strictly valid for small Reynold numbers (Re < 1), agrees well with the results from the numerical solution for most SFD configurations and orbit radii considered.