Time-Temperature-Transformation Curves for Kaolinite-α-Alumina

The C-shaped time-temperature-transformation curves (T-T-T curves) of cristobalite formation and the L-shaped T-T-T curves of α-alumina reaction were established for a high-purity kaolinite-α-alumina mixture during heating. The results revealed that cristobalite formation in kaolinite was retarded by the presence of α-alumina between 1250° and 1350°C and was totally prohibited above 1380°C due to the reaction of kaolinite with α-alumina to form secondary mullite. The reaction of α-alumina with kaolinite was initiated at about 1250°C. It became quite extensive above 1380°C and was extremely fast at 1600°C and above, indicating the strong effect of the eutectic liquid formation at ∼1587°C in silica-alumina. The effectiveness of the established T-T-T curves was demonstrated and discussed.     

New sesquiterpenes fromMaytenus species (Celastraceae). Taxonomic and chemotaxonomic considerations concerning chileanMaytenus

Three new dihydro--agarofuran sesquiterpenes from two species ofMaytenus were isolated and their structures were elucidated by means of¹H and¹³C NMR studies. The differences and similarities noted in the chemical content of the dihydro--agarofuran sesquiterpenes from the fourMaytenus species from Chile are in line with the taxonomic characterization of these species; their geographical distribution is also given.     

Melt extrusion and blow molding parts-per-million POSS interspersed the macromolecular network and simultaneously enhanced thermomechanical and barrier properties of polyolefin films

There has been the expectation that polymers filled with small concentrations of nanosized particles will exhibit superior thermomechanical properties. We demonstrate that dispersing parts-per-million (ppm) polyhedral oligomeric silsesquioxane (POSS) nanochemicals by melt extrusion with polyolefins increased the tensile Young's modulus, yield stress, and toughness of blow molded and extruded films without penalizing extensibility, which is common to polymers reinforced with nano/microparticles. Transmission electron microscopy showed that the key to mechanical reinforcement is the spatial distribution of POSS at ca. single nanocage thus enabling interspersion of the macromolecular network. The thermal stability, water contact angle, and oxygen transmission of the films were also enhanced enabling a single component food package capable to keep food without decay for two weeks. The physical properties are improved when the nanoparticle size <D> is about the size of the virtual tube diameter d_t, that is, <D>/d_t ≈ 1. The enhancement of physical properties by placing the nanoparticle in the free space of the molecular network is a new paradigm in engineering polymer nanocomposites and opens opportunities for recyclable single component packaging films and tunable lightweight engineering and biomimetic materials.     

On truthfulness and approximation for scheduling selfish tasks

We consider the problem of designing truthful mechanisms for scheduling n tasks on a set of m parallel related machines in order to minimize the makespan. In what follows, we consider that each task is owned by a selfish agent. This is a variant of the KP-model introduced by Koutsoupias and Papadimitriou (Proc. of STACS 1999, pp. 404–413, 1999) (and of the CKN-model of Christodoulou et al. in Proc. of ICALP 2004, pp. 345–357, 2004) in which the agents cannot choose the machine on which their tasks will be executed. This is done by a centralized authority, the scheduler. However, the agents may manipulate the scheduler by providing false information regarding the length of their tasks. We introduce the notion of increasing algorithm and a simple reduction that transforms any increasing algorithm into a truthful one. Furthermore, we show that some of the classical scheduling algorithms are indeed increasing: the LPT algorithm, the PTAS of Graham (SIAM J. Appl. Math. 17(2):416–429, 1969) in the case of two machines, as well as a simple PTAS for the case of m machines, with m a fixed constant. Our results yield a randomized r(1+ε)-approximation algorithm where r is the ratio between the largest and the smallest speed of the related machines. Furthermore, by combining our approach with the classical result of Shmoys et al. (SIAM J. Comput. 24(6):1313–1331, 1995), we obtain a randomized 2r(1+ε)-competitive algorithm. It has to be noticed that these results are obtained without payments, unlike most of the existing works in the field of Mechanism Design. Finally, we show that if payments are allowed then our approach gives a (1+ε)-algorithm for the off-line case with related machines.     

Experimental modelling of free-surface dry granular flows under a centrifugal acceleration field

We investigate the dynamics of granular flows under the action of a centrifugal acceleration field. The granular flows consist of a monodisperse set of glass beads flowing down an inclined plane. The experiments are performed at variable slope angles \(\zeta \) and equivalent centrifugal accelerations \(a_\text {cf}\equiv Ng\). We study the effect of this parameters on the superficial flow velocity u and flow height h. Two trends are observed, by increasing \(\zeta \) and \(a_\text {cf}\), u increases proportionally, and h decreases asymptotically until a constant height. This relation is analysed in terms of the system potential and kinetic energy, leading to the estimation of equivalent impact forces one order of magnitude larger than those observed in small scale 1g laboratory experiments, with the possibility to reach higher forces by increasing N. Finally, considering the trend of u and h, our results suggest a scaling principle of inertial velocity proportional to \(\sqrt{N}\).     

A Non-Uniform Predictor-Observer for a Networked Control System

International Journal of Control, Automation and Systems - This paper presents a Non-Uniform Predictor-Observer (NUPO) based control approach in order to deal with two of the main problems related...     

Optimization–Simulation Model for Planning Supply Transport to Large Infrastructure Public Works Located in Congested Urban Areas

This article proposes an optimization–simulation model for planning the transport of supplies to large public infrastructure works located in congested urban areas. The purpose is to minimize their impact on the environment and on private transportation users on the local road network. To achieve this goal, the authors propose and solve an optimization problem for minimizing the total system cost made up of operating costs for various alternatives for taking supplies to the worksite and the costs supported by private vehicle users as a result of increased congestion due to the movement of heavy goods vehicles transporting material to the worksite. The proposed optimization problem is a bi-level Math Program model. The upper level defines the total cost of the system, which is minimized taking into account environmental constraints on atmospheric and noise pollution. The lower level defines the optimization problem representing the private transportation user behavior, assuming they choose the route that minimizes their total individual journey costs. Given the special characteristics of the problem, a heuristic algorithm is proposed for finding optimum solutions. Both the model developed and the specific solution algorithm are applied to the real case of building a new port at Laredo (Northern Spain). A series of interesting conclusions are obtained from the corresponding sensitivity analysis.     

Providing effective feedback, monitoring and evaluation to on-line collaborative learning discussions

Learning and knowledge building have become critical competences for people in the knowledge society era. In this paper, we propose a sociolinguistic dialogue model for understanding how learning evolves and how cognitive process is constructed in on-line discussions. The knowledge extracted from this model is used to assess participation behavior, knowledge building and performance. The ultimate purpose is to provide effective feedback, evaluation and monitoring to the discussion process. Seven hundred students from the Open University of Catalonia in Spain participated in this study. Results showed that learning and knowledge building may be greatly enhanced by presenting selected knowledge to learners as for their particular skills exhibited during interaction. In addition, this valuable provision of information is used as a meta cognitive tool for tutors and moderators for monitoring and evaluating the discussion process more conveniently. This contribution presents our conceptual model for interaction management as well as key design guidelines and evaluation results. Implications of this study are remarked and further research directions are proposed.     

Multi‐agent system for knowledge‐based event recognition and composition

This work presents a multi‐agent system for knowledge‐based high‐level event composition, which interprets activities, behaviour and situations semantically in a scenario with multi‐sensory monitoring. A perception agent (plurisensory agent and visual agent)‐based structure is presented. The agents process the sensor information and identify (agent decision system) significant changes in the monitored signals, which they send as simple events to the composition agent that searches for and identifies pre‐defined patterns as higher‐level semantic composed events. The structure has a methodology and a set of tools that facilitate its development and application to different fields without having to start from scratch. This creates an environment to develop knowledge‐based systems generally for event composition. The application task of our work is surveillance, and event composition/inference examples are shown which characterize an alarming situation in the scene and resolve identification and tracking problems of people in the scenario being monitored.     

Development of clinical indicators for performance measurement and improvement: an HMO/purchaser collaborative effort

This article describes a collaborative effort between a major health care purchaser, three area health maintenance organizations, and a state Medicaid agency to develop clinical indicators as the basis for a comparison database. Some of the difficulties in developing a "common yardstick" of quality and value are candidly discussed.