全文获取类型
收费全文 | 742篇 |
免费 | 23篇 |
国内免费 | 3篇 |
专业分类
电工技术 | 5篇 |
综合类 | 3篇 |
化学工业 | 176篇 |
金属工艺 | 12篇 |
机械仪表 | 13篇 |
建筑科学 | 30篇 |
矿业工程 | 1篇 |
能源动力 | 21篇 |
轻工业 | 151篇 |
水利工程 | 7篇 |
石油天然气 | 2篇 |
无线电 | 29篇 |
一般工业技术 | 118篇 |
冶金工业 | 116篇 |
原子能技术 | 6篇 |
自动化技术 | 78篇 |
出版年
2023年 | 6篇 |
2022年 | 30篇 |
2021年 | 34篇 |
2020年 | 13篇 |
2019年 | 12篇 |
2018年 | 19篇 |
2017年 | 17篇 |
2016年 | 19篇 |
2015年 | 13篇 |
2014年 | 33篇 |
2013年 | 34篇 |
2012年 | 30篇 |
2011年 | 40篇 |
2010年 | 31篇 |
2009年 | 34篇 |
2008年 | 35篇 |
2007年 | 23篇 |
2006年 | 22篇 |
2005年 | 11篇 |
2004年 | 17篇 |
2003年 | 11篇 |
2002年 | 10篇 |
2001年 | 17篇 |
2000年 | 10篇 |
1999年 | 15篇 |
1998年 | 45篇 |
1997年 | 29篇 |
1996年 | 25篇 |
1995年 | 8篇 |
1994年 | 10篇 |
1993年 | 10篇 |
1992年 | 7篇 |
1991年 | 9篇 |
1990年 | 8篇 |
1989年 | 8篇 |
1988年 | 5篇 |
1986年 | 5篇 |
1985年 | 7篇 |
1983年 | 5篇 |
1982年 | 8篇 |
1981年 | 4篇 |
1980年 | 2篇 |
1979年 | 4篇 |
1978年 | 6篇 |
1977年 | 2篇 |
1976年 | 6篇 |
1975年 | 4篇 |
1974年 | 3篇 |
1971年 | 2篇 |
1963年 | 2篇 |
排序方式: 共有768条查询结果,搜索用时 31 毫秒
61.
N. Armata G. Baldissin G. Barone R. Cortese V. D’Anna F. Ferrante S. Giuffrida G. Li Manni A. Prestianni T. Rubino Zs. Varga D. Duca 《Topics in Catalysis》2009,52(4):431-443
Monte Carlo algorithms and codes, used to study heterogeneous catalytic systems in the frame of the computational section
of the NANOCAT project, are presented along with some exemplifying applications and results. In particular, time dependent
Monte Carlo methods supported by high level quantum chemical information employed in the field of heterogeneous catalysis
are focused. Technical details of the present algorithmic Monte Carlo development as well as possible evolution aimed at a
deeper interrelationship of quantum and stochastic methods are discussed, pointing to two different aspects: the thermal-effect
involvement and the three-dimensional catalytic matrix simulation. As topical applications, (i) the isothermal and isobaric
adsorption of CO on Group 10 metal surfaces, (ii) the hydrogenation on metal supported catalysts of organic substrates in
two-phase and three-phase reactors, and (iii) the isomerization of but-2-ene species in three-dimensional supported and unsupported
zeolite models are presented. 相似文献
62.
63.
Performance of carbon-carbon supercapacitors based on organic, aqueous and ionic liquid electrolytes 总被引:1,自引:0,他引:1
Andrzej Lewandowski Angelika Olejniczak Maciej Galinski Izabela Stepniak 《Journal of power sources》2010,195(17):5814-159
Properties of capacitors working with the same carbon electrodes (activated carbon cloth) and three types of electrolytes: aqueous, organic and ionic liquids were compared. Capacitors filled with ionic liquids worked at a potential difference of 3.5 V, their solutions in AN and PC were charged up to the potential difference of 3 V, classical organic systems to 2.5 V and aqueous to 1 V. Cyclic voltammetry, galvanostatic charging/discharging and impedance spectroscopy were used to characterize these capacitors. The highest specific energy was recorded for the device working with ionic liquids, while the highest power is characteristic for the device filled with aqueous H2SO4 electrolyte. Aqueous electrolytes led to energy density an order of magnitude lower in comparison to that characteristic of ionic liquids. 相似文献
64.
J Rigó M Burger I Repa A Vereckei I Varga P Pusztai C Dzsinich 《Canadian Metallurgical Quarterly》1997,138(35):2187-2190
Bilateral renal artery stenosis was diagnosed noninvasively in the 17th gestational week, in a chronically hypertensive pregnant woman, by renal artery duplex ultrasound examination, MRI and MR angiography. Continuous monitoring of the mother and the fetus was performed. Blood pressure was stabilized by complex antihypertensive therapy, but from the beginning of the third trimester superimposed preeclampsia developed gradually. In the 34th gestational week a 1600-g newborn was delivered by elective cesarean section. The case report draws attention to the significance of the thorough examination of hypertensive women before pregnancy. 相似文献
65.
66.
Pesticides and polychlorinated biphenyls (PCBs) are found in various parts of the environment in quite small concentrations, but they accumulate and thus become a threat to human health and life. A review is focused on the application of some popular techniques for sample preparation in analysis of these compounds in food. Even with the emergence of advanced techniques of final analysis, complex matrices, such as food, require extensive sample extraction and purification. Traditional sample preparation techniques are time consuming and require large amount of solvents, which are expensive, generate considerable waste, contaminate the sample and can enrich it for analytes. There have been many sample preparation techniques proposed to meet the requirements connected with the multiplicity of food. Optimal sample preparation can reduce analysis time, sources of error, enhance sensitivity and enable unequivocal identification and quantification. Sample extraction and purification techniques are discussed and their most recent applications in food analysis are provided. This review pointed out that sample preparation is the critical step. 相似文献
67.
Oskar Varga 《Zeitschrift für Lebensmitteluntersuchung und -Forschung A》1930,60(3):268-277
Ohne Zusammenfassungbedeutet mit Abbildungen. 相似文献
68.
Riham M. Morcos Alexandra Navrotsky Tamas Varga Dongjoon Ahn Atanu Saha Fabrizia Poli Klaus Müller Rishi Raj 《Journal of the American Ceramic Society》2008,91(7):2391-2393
This communication reports new results on the enthalpy of formation of pseudo-amorphous ceramic compounds constituted from silicon, carbon, oxygen, and nitrogen (SiCNO), made from the polymer route. Again, like the SiCO materials, although with one exception, the enthalpy of formation from crystalline components (SiO2 cristobalite, β-Si3 N4 , SiC, and excess C) is negative. Some of the alloyed oxygen–nitrogen compositions yield enthalpies that are much more negative (∼100 kJ/g·atom) in comparison with compositions that contain mainly oxygen or nitrogen (∼20 kJ/g·atom). The exception, having a N/O ratio near 2, has a positive value for the enthalpy. This may reflect the presence of nanoclusters of stoichiometric Si2 N2 O instead of the pseudo-amorphous nanodomain structure seen for the other samples. 相似文献
69.
Franz Ferdinand Reinthaler Gebhard Feierl Herbert Galler Doris Haas Eva Leitner Franz Mascher Angelika Melkes Josefa Posch Ingrid Winter Gernot Zarfel Egon Marth 《Water research》2010,44(6):1981-1985
The aim of this study was to investigate the degree of contamination of sewage sludge with ESBL-producing Escherichia coli strains and the effectiveness of different sewage sludge treatment methods.Monthly sewage sludge samples were collected between January and September 2009 in 5 different sewage treatment plants and tested for the presence of ESBL E. coli. In addition, the number of colony forming units (CFU) of E. coli and coliform bacteria before and after the different sludge treatment methods (aerobic/anaerobic digestion, lime stabilization, and thermal treatment) was investigated.Of the 72 sewage sludge samples investigated, ESBL-positive E. coli were found in 44 (61.1%) sewage sludge samples. The classification of β-lactamase groups was carried out in 15 strains resulting in the detection of 2 different groups (CTX-M and TEM) of bla genes. All 15 of them had a CTX-M gene and 4 of these strains furthermore carried a TEM gene.With regard to the CFU of E. coli and coliform bacteria, thermal treatment and lime stabilization following dehydration sufficiently reduced pathogen concentrations. The plants using merely stabilization and dehydration showed an increase of E. coli and coliform bacteria and thus also an increase in ESBL-producing E. coli. 相似文献
70.
Patrycja Bober Miroslava Trchová Jan Prokeš Martin Varga Jaroslav Stejskal 《Electrochimica acta》2011,(10):5947
Aniline was oxidized with silver nitrate in aqueous solutions of sulfonic acids: camphorsulfonic, methanesulfonic, sulfamic, or toluenesulfonic acids. Polyaniline–silver composites were produced slowly in 4 weeks in good yield, except for the reaction, which took place in sulfamic acid solution, where the yield was low. Polyaniline in the emeraldine form was identified with UV–visible, FTIR, and Raman spectra. Thermogravimetric analysis was used to determine the silver content, which was close to the theoretical prediction of 68.9 wt.%. Transmission electron microscopy demonstrated the presence of silver nanoparticles of ca 50 nm average sizes as the dominating species, and hairy polyaniline nanorods having diameter 150–250 nm accompanied them. The highest conductivity of 880 S cm−1 was found with the composite prepared in methanesulfonic acid solution. Its conductivity decreased with temperature increasing in the 70–315 K range, which is typical of metals such as silver. The conductivity of composites prepared in solutions of other acids was lower and increased with increasing temperature. Such dependence is typical of semiconductors, reflecting the dominating role of polyaniline in the conductivity behaviour. It is proposed that interfaces between the polyaniline matrix and dispersed silver nanoparticles play a dominating role in macroscopic level of conductivity. 相似文献