Influence new-to-old concrete interface qualities on the behaviour of support zones of composite concrete beams

The paper describes the investigations of concrete composite units consisting of two concrete parts. In each test series the interface was differently arranged and characterised by different strength parameters. They were: non-reinforced interface with existing adhesion, reinforced interface with existing adhesion and reinforced interface with broken adhesion. Simply-supported beams were subjected to four point bending. The failure of all beams was the result of exceeding the shear resistance of the support zones, but the cracks pattern in each series was different. The paper presents the results of the tests, in particular: deflection, stresses in the longitudinal and transverse reinforcement and strains of concrete. The distribution of strains along the height of the beam and the slip between the connected parts are also described.On the basis of these data a classification of failure mechanisms of concrete composite beams is proposed, as well as the analytical criteria allowing to predict failure manner of a composite beam.     

A practical procedure to assess critical defects in pressure vessels subjected to fatigue loads

PSA pressure vessels are equipments used in refining industries for cleaning the hydrogen upcoming from the reforming or hydrogen generation unities. In one regular inspection, some embedded cracks were found in the entrance nozzle-head weld. Then, instead of advance its decommissioning and waste much time until the refinery purchase a new vessel, a structural stress analysis using the finite element method was performed in order to obtain the stress field at the site of the crack, considering the real loading cycle. Despite the acting load is only the internal pressure, the nozzle-head weld is a region where a complex stress state is present (bending and axial stresses). ASME VIII Division 2, Appendix 5 addresses this issue by applying a rule for multiaxial fatigue life estimation for non-proportional loading. With ASME estimated fatigue life results, it was applied the British Standard 7910 procedure to decide if the equipment can operate safely. The calculation also assesses the crack growing by using a modified bi-linear Paris law. Finally, it was computed how long the cracks would take to get to their critical size and then retire definitively the equipment.     

Electrochemical characterization of alternate conducting carbazole-bisthiophene units

An electrochemical and theoretical character of alternate copolymer of carbazole and bithiophene units was investigated. Polymerization is processed as two steps bielectronic oxidation of molecule. With monoelectronic oxidation is connected stable radical cation with spin located mainly on carbazole. The electrochemical properties of polymer are dependent on thickness of film deposited on electrode. In case of the thin layers one it is observed characteristic redox couple of carbazole oxidation to radical cation. Analysis of polymer behavior and results of spectrochemical measurements indicate on mixed type of electroconductivity.Molecular structures, HOMO-LUMO gaps and nature of highest occupied and lowest unoccupied molecular orbitals were also studied in presented work for oligomers ranging from monomer to octamer. The studies applied density functional theory (DFT).     

When public opposition defeats alternative water projects - The case of Toowoomba Australia

Located approximately 100 km west of Brisbane, Toowoomba is home to approximately 95,000 people. Surface water from dams is the main source of water for the city. In 2006 the residents of Toowoomba were invited to vote in a referendum (plebiscite) concerning whether or not an indirect potable wastewater reuse scheme should be constructed to supply additional water to the area. At that stage dam levels in Toowoomba were at approximately twenty percent of capacity. Toowoomba residents, after intense campaigning on both sides of the referendum debate, voted against the proposal. In July 2008 dam levels dropped to eleven percent. Stage 5 water restrictions have been in place since September 2006, subsequently mains water must not be used for any outdoor uses. This paper describes in detail how public opposition in the case of Toowoomba's referendum, defeated the proposal for a water augmentation solution. Reasons for the failure are analysed. In so doing, the paper provides valuable insights with respect to public participation in indirect potable reuse proposals, and discusses factors including politics, vested interest and information manipulation. This paper is significant because of the lack of detailed information published about failed water infrastructure projects.     

New sources of resistance to Acanthoscelides obtectus (Say) and Zabrotes subfasciatus Boheman (Coleoptera: Bruchidae) in mature seeds of five species of Phaseolus

The importance of carefully applied bioassay techniques is highlighted for identifying resistance of Phaseolus spp to the bruchids Acanthoscelides obtectus (Say) and Zabrotes subfasciatus Boheman. Two potential sources of resistance are identified amongst the varieties of P. vulgaris screened. In one the presence of a lectin-like protein (LLP) was identified, which has previously been associated with resistance, while in the other, resistance may be linked to the presence of a novel protein, similar to but not the same as LLP. The use of anti-LLP antibodies are suggested as a useful tool for distinguishing between resistant and susceptible varieties. Five varieties of P. lunatus and six of P. acutifolius are shown to be resistant to A. obtectus, and the potential is recognized for transferring resistant genes to P. vulgaris via interspecific crosses.     

Solution‐Processed GaSe Nanoflake‐Based Films for Photoelectrochemical Water Splitting and Photoelectrochemical‐Type Photodetectors

Gallium selenide (GaSe) is a layered compound, which has been exploited in nonlinear optical applications and photodetectors due to its anisotropic structure and pseudodirect optical gap. Theoretical studies predict that its 2D form is a potential photocatalyst for water splitting reactions. Herein, the photoelectrochemical (PEC) characterization of GaSe nanoflakes (single‐/few‐layer flakes), produced via liquid phase exfoliation, for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) in both acidic and alkaline media is reported. In 0.5 m H₂SO₄, the GaSe photoelectrodes display the best PEC performance, corresponding to a ratiometric power‐saved metric for HER (Φ_saved,HER) of 0.09% and a ratiometric power‐saved metric for OER (Φ_saved,OER) of 0.25%. When used as PEC‐type photodetectors, GaSe photoelectrodes show a responsivity of ≈0.16 A W^?1 upon 455 nm illumination at a light intensity of 63.5 µW cm^?2 and applied potential of ?0.3 V versus reversible hydrogen electrode (RHE). Stability tests of GaSe photodetectors demonstrated a durable operation over tens of cathodic linear sweep voltammetry scans in 0.5 m H₂SO₄ for HER. In contrast, degradation of photoelectrodes occurred in both alkaline and anodic operation due to the highly oxidizing environment and O₂‐induced (photo)oxidation effects. The results provide new insight into the PEC properties of GaSe nanoflakes for their exploitation in photoelectrocatalysis, PEC‐type photodetectors, and (bio)sensors.     

A Novel Switched Parasitic Array and Diversity Scheme Using Horizontally Polarized Linear Antennas

Switched Parasitic Arrays (SPAs) are proposed as an attractive alternative to fully adaptive arrays, due to their compact size and significantly lower cost of development. The main concept of SPAs is the deployment of switches on parasitic elements, which can be properly adjusted, in order to effectively control the radiation pattern of one active element. Conventional SPAs consist of circular arrays of vertically polarized dipoles and parasitic elements. In this paper, a novel SPA design is proposed, which is based on multiple switches employed on the body of horizontally polarized elements (one active and two parasitics). Design considerations are discussed and numerical results are illustrated. Furthermore, a simple diversity scheme is proposed, based on the novel SPA design. Superior performance of the proposed array, relative to simple non-diversity reception schemes, is indicated by simulation results. Stelios A. Mitilineos was born in Athens, Greece, in 1977. He received the Diploma in electrical and computer engineering from the National Technical University of Athens (NTUA), Greece, in October 2001. He is currently working towards his Ph.D. degree in electrical engineering at the same university. His research interests include antennas and propagation, smart antennas and mobile communications, channel estimation and location detection algorithms, MIMO systems and microwave components. Anna E. Andreoudi was born in Thessalonica, Greece, in 1977. She received the Diploma in electrical and computer engineering from the National Technical University of Athens, in 2004. Her research interests include electromagnetic waves propagation and scattering, antenna design and adaptive arrays, wireless communications and wireless mobile networks. Christos N. Capsalis was born in Nafplion, Greece in 1956. He received the Diploma in electrical and mechanical engineering from the National Technical University of Athens in 1979 and the B.S. degree in economics from the University of Athens in 1983. He obtained the Ph.D. degree in electrical engineering from NTUA in 1985. He is currently a Professor at the department of Electrical and Computer Engineering in NTUA. His current scientific activity concerns satellite and mobile communications, antenna theory and design, and electromagnetic compatibility.     

碳纳米管的大面积合成及磁性(英文)

通过溶胶凝胶法和氢气还原法制备出Co纳米颗粒并以此作为催化剂材料,通过催化裂解苯的方法,实现了较低温度(460℃)下在Co纳米颗粒表面上合成碳纳米管。采用X射线衍射、激光喇曼光谱、场发射扫描电镜、透射电子显微镜和振动样品磁强计对所合成的碳纳米材料进行了表征。通过优化实验参数,可制备出最大产率和纯度分别为约50和98.02%(质量分数)的碳纳米管。由于铁磁性Co纳米颗粒的进入,使得整个复合物表现出比较好的磁性能。和以往以苯作为碳源合成碳纳米材料相比,此合成方案简单、成本低,且对环境无任何危害,非常适用于磁性碳纳米复合物的批量合成。     

Provably-Secure Time-Bound Hierarchical Key Assignment Schemes

A time-bound hierarchical key assignment scheme is a method to assign time-dependent encryption keys to a set of classes in a partially ordered hierarchy, in such a way that each class can compute the keys of all classes lower down in the hierarchy, according to temporal constraints.     

Monomolecular and Bimolecular Recombination of Electron–Hole Pairs at the Interface of a Bilayer Organic Solar Cell

While it has been argued that field‐dependent geminate pair recombination (GR) is important, this process is often disregarded when analyzing the recombination kinetics in bulk heterojunction organic solar cells (OSCs). To differentiate between the contributions of GR and nongeminate recombination (NGR) the authors study bilayer OSCs using either a PCDTBT‐type polymer layer with a thickness from 14 to 66 nm or a 60 nm thick p‐DTS(FBTTh₂)₂ layer as donor material and C₆₀ as acceptor. The authors measure JV‐characteristics as a function of intensity and charge‐extraction‐by‐linearly‐increasing‐voltage‐type hole mobilities. The experiments have been complemented by Monte Carlo simulations. The authors find that fill factor (FF) decreases with increasing donor layer thickness (L_p) even at the lowest light intensities where geminate recombination dominates. The authors interpret this in terms of thickness dependent back diffusion of holes toward their siblings at the donor–acceptor interface that are already beyond the Langevin capture sphere rather than to charge accumulation at the donor–acceptor interface. This effect is absent in the p‐DTS(FBTTh₂)₂ diode in which the hole mobility is by two orders of magnitude higher. At higher light intensities, NGR occurs as evidenced by the evolution of s‐shape of the JV‐curves and the concomitant additional decrease of the FF with increasing layer thickness.