Spatio-Temporal Analysis of Regional Trends and Shift Changes of Autocorrelated Temperature Series in Urmia Lake Basin

Recently, the Urmia Lake located in northwestern Iran which is the second largest hyper saline in the world suffers from the significant fluctuations of water level and surface area. The current study tries to investigate the spatiotemporal trends of mean (T_mean), maximum (T_max) and minimum (T_min) temperatures of monthly, seasonal and annual time-series. To do so, the data of 15 temperature gauge stations within the Urmia Lake basin, for the period 1972–2011 was employed. The pre-whitening approach was applied to remove the effects of serial correlation in the air temperature series based on the Mann-Kendall (MK) test. The results of Ljung-Box test showed positive serial correlation in the T_mean and T_max series for all of the stations at the 0.05 significance level. In the monthly series, the significant warming trends in the T_mean series were more perceptible than the same ones in T_max series; however, T_max trend was found more than T_min series. The Mann–Whitney (MW) test detected a significance upward shift changes in the annual T_mean, T_max and T_min series of about 86, 73 and 80 % of the stations, respectively. The average magnitude of significant warming trends in annual T_mean, T_max and T_min series were (+) 0.58 °C, (+) 0.52 °C and (+) 0.69 °C per decade, respectively. Furthermore, the interpolation maps showed that warming trends in the east and west of Urmia Lake were more than southern area. Therefore, the results showed that the basin has suffered from increasing trends in the T_mean, T_max and T_min over the recent decades. Finally, significant changes were found in 1980s and 1990s based on the Mann-Kendall ranks and change point tests. In this study, it is interesting that the period of significant changes in warming trends were close to the beginning of decreasing water level of the Lake.     

Higher order tip enrichment of eXtended Finite Element Method in thermoelasticity

An eXtended Finite Element Method (XFEM) is presented that can accurately predict the stress intensity factors (SIFs) for thermoelastic cracks. The method uses higher order terms of the thermoelastic asymptotic crack tip fields to enrich the approximation space of the temperature and displacement fields in the vicinity of crack tips—away from the crack tip the step function is used. It is shown that improved accuracy is obtained by using the higher order crack tip enrichments and that the benefit of including such terms is greater for thermoelastic problems than for either purely elastic or steady state heat transfer problems. The computation of SIFs directly from the XFEM degrees of freedom and using the interaction integral is studied. Directly computed SIFs are shown to be significantly less accurate than those computed using the interaction integral. Furthermore, the numerical examples suggest that the directly computed SIFs do not converge to the exact SIFs values, but converge roughly to values near the exact result. Numerical simulations of straight cracks show that with the higher order enrichment scheme, the energy norm converges monotonically with increasing number of asymptotic enrichment terms and with decreasing element size. For curved crack there is no further increase in accuracy when more than four asymptotic enrichment terms are used and the numerical simulations indicate that the SIFs obtained directly from the XFEM degrees of freedom are inaccurate, while those obtained using the interaction integral remain accurate for small integration domains. It is recommended in general that at least four higher order terms of the asymptotic solution be used to enrich the temperature and displacement fields near the crack tips and that the J- or interaction integral should always be used to compute the SIFs.     

A Uniform Paradigm to Succinctly Encode Various Families of Trees

We propose a uniform method to encode various types of trees succinctly. These families include ordered (ordinal), k-ary (cardinal), and unordered (free) trees. We will show the approach is intrinsically suitable for obtaining entropy-based encodings of trees (such as the degree-distribution entropy). Previously-existing succinct encodings of trees use ad hoc techniques to encode each particular family of trees. Additionally, the succinct encodings obtained using the uniform approach improve upon the existing succinct encodings of each family of trees; in the case of ordered trees, it simplifies the encoding while supporting the full set of navigational operations. It also simplifies the implementation of many supported operations. The approach applied to k-ary trees yields a succinct encoding that supports both cardinal-type operations (e.g. determining the child label i) as well as the full set of ordinal-type operations (e.g. reporting the number of siblings to the left of a node). Previous work on succinct encodings of k-ary trees does not support both types of operations simultaneously (Benoit et al. in Algorithmica 43(4):275–292, 2005; Raman et al. in ACM-SIAM Symposium on Discrete Algorithms (SODA), pp. 233–242, 2002). For unordered trees, the approach achieves the first succinct encoding. The approach is based on two recursive decompositions of trees into subtrees. Recursive decomposition of a structure into substructures is a common technique in succinct encodings and has even been used to encode (ordered) trees (Geary et al. in ACM Trans. Algorithms 2(4):510–534, 2006; He et al. in ICALP, pp. 509–520, 2007) and dynamic binary trees (Munro et al. in ACM-SIAM Symposium on Discrete Algorithms (SODA), pp. 529–536, 2001; Storm in Representing dynamic binary trees succinctly, Master’s thesis, 2000). The main distinction of the approach in this paper is that a tree is decomposed into subtrees in a manner that the subtrees are maximally isolated from each other. This intermediate decomposition result is interesting in its own right and has proved useful in other applications (Farzan et al. in ICALP (1), pp. 451–462, 2009; Farzan and Munro in ICALP (1), pp. 439–450, 2009; Farzan and Kamali in ICALP, 2011).     

TiN Nanoparticles for Enhanced THz Generation in TDS Systems

By virtue of the surface plasmon resonance effect, plasmonic nanoparticles (NPs) can localize the light field and significantly enhance the performance of some optoelectronic devices. In this work, NPs are employed for an enhanced generation of terahertz radiation from LT-GaAs-based antennas. Therefore, we have prepared plasmonic TiN NPs by direct ultrasonication (ULS) and pulsed laser ablation (PLA) techniques. The zeta potential, particle size, and absorbance were used to characterize the NPs in their colloidal forms in a comparison to commercial Au NPs. A layer of polydispersed titanium nitride (TiN) NPs prepared by PLA and deposited on the surface of an LT-GaAs device shows a significant improvement of terahertz signal generation from these devices with an enhancement of the peak to peak amplitude of 100%.     

Viscoelastic and mechanical properties of multi walled carbon nanotube/epoxy composites with different nanotube content

The viscoelastic and mechanical properties of composites multi walled carbon nanotube (MWNT)/epoxy at different weight fractions (0.1, 0.5, 1 and 2 wt.%) were evaluated by performing tensile and dynamic-mechanical thermal analysis (DMTA) tests. The MWNT/epoxy composite were fabricated by sonication and a cast molding process. The results showed that addition of nanotubes to epoxy had significant effect on the viscoelastic and mechanical properties. However, the use of 0.5 wt.% increased the viscoelastic properties more significantly. Concerning viscoelastic modeling, the COLE–COLE diagram has been plotted by the results of DMTA test. These results show a good agreement between the Perez model and the viscoelastic behavior of the composite.     

Time‐domain hybrid formulations for wave simulations in three‐dimensional PML‐truncated heterogeneous media

We are concerned with the numerical simulation of wave motion in arbitrarily heterogeneous, elastic, perfectly‐matched‐layer‐(PML)‐truncated media. We extend in three dimensions a recently developed two‐dimensional formulation, by treating the PML via an unsplit‐field, but mixed‐field, displacement‐stress formulation, which is then coupled to a standard displacement‐only formulation for the interior domain, thus leading to a computationally cost‐efficient hybrid scheme. The hybrid treatment leads to, at most, third‐order in time semi‐discrete forms. The formulation is flexible enough to accommodate the standard PML, as well as the multi‐axial PML. We discuss several time‐marching schemes, which can be used à la carte, depending on the application: (a) an extended Newmark scheme for third‐order in time, either unsymmetric or fully symmetric semi‐discrete forms; (b) a standard implicit Newmark for the second‐order, unsymmetric semi‐discrete forms; and (c) an explicit Runge–Kutta scheme for a first‐order in time unsymmetric system. The latter is well‐suited for large‐scale problems on parallel architectures, while the second‐order treatment is particularly attractive for ready incorporation in existing codes written originally for finite domains. We compare the schemes and report numerical results demonstrating stability and efficacy of the proposed formulations. Copyright © 2014 John Wiley & Sons, Ltd.     

Study the effect of distribution of density of states on the depletion width of organic Schottky contacts

Organic semiconductor to metal Schottky contacts have been widely used in electronic devices and to investigate the properties of organic semiconductors. In designing and characterizing these devices the full depletion approximation is used. The analytical and numerical simulations presented in this paper suggest that this approximation is not generally valid. Simulations of a Schottky contact between regioregular-poly 3 hexylthiophene (rr-P3HT) and aluminum show that this approximation becomes worse as molecular order decreases, with the potential profile increasingly deviating from the expected quadratic function of position. Also the depletion width decreasing well below that predicted using the approximation. In this work the slope of the band tail is used as a measure of disorder.     

Double-walled microspheres loaded with meglumine antimoniate: preparation,characterization and in vitro release study

Objective: The objective of this study was to fabricate double-walled poly(lactide-co-glycolide) (PLGA) microspheres to increase encapsulation efficiency and avoid rapid release of hydrophilic drugs such as meglumine antimoniate.

Methods: In this study, double-walled and one-layered microspheres of PLGA were prepared using the emulsion solvent evaporation technique to better control the release of a hydrophilic drug, meglumine antimoniate (Glucantime®), which is the first choice treatment of cutaneous leishmaniasis. The effect of hydrophobic coating on microspheres' size, morphology, encapsulation efficiency and drug release characteristics was evaluated. Furthermore, the presence of antimony in meglumine antimoniate made it possible to observe the drug distribution within the microspheres' cross section by means of energy dispersive X-ray spectroscopy.

Results: Drug distribution images confirmed accumulation of the drug within the inner core of double-walled microspheres. In addition, these microspheres encapsulated the drug more efficiently up to 87% and demonstrated reduced initial burst and prolonged release compared to one-layered microspheres. These superiorities make double-walled microspheres an optimum candidate for sustained delivery of hydrophilic drugs.

Conclusion: Double-walled microspheres provide some advantages over traditional microspheres overcoming most of their limitations. Double-walled microspheres were found to be more efficient than their corresponding one-layered microspheres in terms of encapsulation efficiencies and release characteristics.