The effect of humic acids on the cytotoxicity of silver nanoparticles to a natural aquatic bacterial assemblage

The effect of a terrestrial humic acid (HA) and a river HA on the cytotoxicity of silver nanoparticles (AgNPs) to natural aquatic bacterial assemblages (0 μM, 2.5 μM and 5 μM) was measured with spread plate counting. The effect of HA (20 and 40 ppm) on the cytotoxicity of AgNPs ranging in size between 15 and 25 nm was tested in the presence and in the absence of natural sunlight. The experiment was a full factorial, completely randomized design and the results were analyzed using the General Linear Model in SAS. LSMEANS was used to separate the means or combinations of means. Significant main effects of all independent variables, plus interaction effects in all cases except HA/LI and HA/AgNPs/LI were observed. The toxicity of AgNPs to natural aquatic bacterial assemblages appears to be concentration dependent for concentrations between 0 μM and 5 μM. The data indicate that the light exposure inhibited viability more than the darkness exposure. The HA treatment groups in the presence of light showed greater reduced viability count compared to darkness exposure groups. The inhibition of bacterial viability counts by AgNPs exposure was less in the light treatment groups containing a terrestrial HA compared to that with a river HA. Difference in the extent of reactive oxygen species formation and adsorption/binding of AgNPs was speculated to account for the observed phenomenon.     

Clay exfoliation and organic modification on wear of nylon 6 nanocomposites processed by different routes

The role of nanoclay on the wear characteristics of nylon 6 nanocomposites processed via different routes is examined in this paper. Pristine clay and organoclay were used in melt-extrusion with the matrix resulting in a largely aggregated and a highly exfoliated morphology, respectively. High exfoliation of pristine clay was also achieved by a water-assist process in melt compounding. Nylon 6/pristine clay composite had the worst wear resistance due to the large aggregated clay particles. For the two nylon 6/exfoliated clay nanocomposites, the one with the organically modified clay outperformed that with the pristine clay exfoliated by water. Detailed study on the wear track and subsurface below of the nylon 6/clay composites using both transmission and scanning electron microscopy provided new insight into the differences in their deformation and damage mechanisms. It was revealed that the interfacial adhesion of clay to matrix, and not the exfoliated morphology of clay, played a critical role in wear. However, exfoliated clay morphology is preferred to aggregate morphology. Hence, the superior wear-performance of nylon 6/organoclay nanocomposite is brought about by a combined effect of fine dispersion of clay platelets in nylon 6, high interfacial interaction between nylon 6 and clay layers, and effective constraint on surrounding nylon 6 material exerted by the clay platelets.     

Opportunistic large array concentric routing algorithm (OLACRA) for upstream routing in wireless sensor networks

An opportunistic large array (OLA) is a form of cooperative diversity in which a large group of relays or forwarding nodes operate without any mutual coordination, but naturally fire together in response to energy received from a single source or another OLA. When used for broadcast, OLAs form concentric rings around the source, and have been shown to use less transmit energy than conventional multi-hop protocols during broadcasting. The OLA concentric routing algorithm (OLACRA) and its variants, the main contributions of this paper, leverage the concentric ring structure of the OLAs during the initialization phase to limit the node participation on the upstream connection. For the simulation scenarios considered in this paper, OLACRA is shown to save over 80% of the transmit energy relative to other OLA-based schemes. This paper analyzes the performance of OLACRA over ‘deterministic channels’ or non-faded orthogonal channels and on ‘diversity’ or Rayleigh flat-fading channels with limited orthogonality. Enhancements to OLACRA to further improve its energy efficiency by limited broadcasting in the initial upstream level and limiting the downlink ‘step-sizes’ are also considered. A simple contention avoidance scheme for WSNs with multiple flows is also proposed. In addition to this, the robustness of OLACRA over mobile channels is also studied. The protocols are tested using Monte Carlo evaluation.     

Using OpenFlow to provide cut-through switching in MobilityFirst

Mobile devices are expected to become the Internet’s predominant technology. Current protocols such as TCP/IP were not originally designed with mobility as a key consideration, and therefore underperform under challenging mobile and wireless conditions. MobilityFirst, a clean slate architecture proposal, embraces several key concepts centered around secure identifiers that inherently support mobility and trustworthiness as key requirements of the network architecture. This includes a hop-by-hop segmented data transport based on a globally unique identifier. This allows late and dynamic rebinding of end-point addresses to support mobility. While this provides critical gains in wireless segments, some overheads are incurred even in stable segments such as in the core. Bypassing routing-layer decisions in these cases, with lower layer cut-through forwarding, can improve said gains. In this work, we introduce a general bypass capability within the MobilityFirst architecture that provides better performance and enables both individual and aggregate flow-level traffic control. Furthermore, we present an OpenFlow-based proof-of-concept implementation of the bypass function using layer 2 VLAN tagging. We run experiments on the ORBIT and Global Environment for Network Innovations (GENI) testbeds to evaluate the performance and scalability of the solution. By implementing the bypass functionality, we are able to significantly reduce the number of messages processed by the controller as well as the number of flow rules that need to be pushed into the switches.