Facile fabrication of mesoporous carbon nanofibers with unique hierarchical nanoarchitecture for electrochemical hydrogen storage

A colloidal silica incorporated porous anodic aluminum oxide (AAO) was utilized as a dual-template to prepare mesoporous carbon nanofibers (MCNFs). Such a strategy is simple because it takes advantage of commercially available materials (i.e., colloidal silica and AAO) and the templates can be removed in one step. The as-prepared MCNF shows a hierarchical nanostructure consisting of open macroporous channel connected with large mesopores and micropores. As a result of the large surface area and unique hierarchical nanoarchitecture which facilitates fast mass and electron transport, the MCNF reveals a discharge capacity of 679 mA h g⁻¹ at 25 mA g⁻¹. This value is significantly greater than that (i.e., 394 mA h g⁻¹) observed for an ordered mesoporous carbon (OMC) with a similar specific surface area. Furthermore, at 3000 mA g⁻¹, the MCNF demonstrates a discharge capacity of 585 mA h g⁻¹, which is about twice that (i.e., 256 mA h g⁻¹) of the OMC.     

Subset simulation method including fitness-based seed selection for reliability analysis

Probability estimation of rare events is a challenging task in the reliability theory. Subset simulation (SS) is a robust simulation technique that transforms a rare event into a sequence of multiple intermediate failure events with large probabilities and efficiently approximates the mentioned probability. Proper handling of a reliability problem by this method requires employing a suitable sampling approach to transmit samples toward the failure set. Markov Chain Monte Carlo (MCMC) is a suitable sampling approach that solves the SS transition phase using the failed sample of each simulation level as the seed of next samples. This paper is aimed to study the seed selection effect on the SS accuracy through several seed selection approaches inspired by the genetic algorithm and particle filter and using the main PDF of the variables to assign a mass function probability to each subset sample in the failure domain. Roulette wheel (I, II), tournament and proportional probability techniques are then employed to choose the weighed samples as seeds to be placed in the MCMC to transmit the samples. To examine the capability of each approach, reliabilities of some engineering problems were investigated and results showed that the proposed approaches could find proper failure sets better than the original SS method, especially in problems with several failure domains.

     

Heat transfer due to electroosmotic flow of viscoelastic fluids in a slit microchannel

The bio-microfluidic systems are usually encountered with non-Newtonian behaviors of working fluids. The rheological behavior of some bio-fluids can be described by differential viscoelastic constitutive equations that are related to PTT and FENE-P models. In the present work, thermal transport characteristics of the steady fully developed electroosmotic flow of these fluids in a slit microchannel with constant wall heat fluxes have been investigated. The Debye–Huckel linearization is adopted and the effects of viscous dissipation and Joule heating are taken into account. Analytical solutions are obtained for the transverse distributions of velocity and temperature and finally for Nusselt number. Two different behaviors are observed for the Nusselt number variations due to increasing ?_geWe² which are an increasing trend for positive wall heat flux and a decreasing one for negative wall heat flux. However, the influence of ?_geWe² on Nusselt number vanishes at higher values of the dimensionless Debye–Huckel parameter. It is also realized that the effect of viscous heating is more important at small values of both ?_geWe² and the dimensionless Debye–Huckel parameter. Furthermore, the results show a singularity in Nusselt number at higher negative values of the dimensionless Joule heating parameter.     

Thermomechanical properties of poly(lactic acid) films reinforced with hydroxyapatite and regenerated cellulose microfibers

Novel composite films constituted of poly(lactic acid) (PLA), hydroxyapatite (HAp), and two types of regenerated cellulose fillers—particulate and fibrous type—were produced by melt extrusion in a twin‐screw micro‐compounder. The effect of the film composition on the tensile and dynamic mechanical behavior and the HAp dispersion in the PLA matrix were investigated thoroughly. Appearance of crazed regions and prevention of HAp aggregation in the PLA matrix were elucidated in the composites with up to 15 wt % particulate cellulose content, which was the main reason for only slight reduction in the tensile properties, and consequently trivial degradation of their pre‐failure energy absorption as compared to neat PLA films. Superior dynamical energy storage capacities were obtained for the particulate cellulose modified composites, while their fibrous counterparts had not as good properties. Additionally, the anisotropic mechanical behavior obtained for the extruded composites should be favorable for use as biomaterials aimed at bone tissue engineering applications. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40911.