全文获取类型
收费全文 | 769篇 |
免费 | 31篇 |
专业分类
电工技术 | 13篇 |
化学工业 | 183篇 |
金属工艺 | 15篇 |
机械仪表 | 15篇 |
建筑科学 | 22篇 |
能源动力 | 30篇 |
轻工业 | 41篇 |
水利工程 | 3篇 |
石油天然气 | 2篇 |
无线电 | 116篇 |
一般工业技术 | 141篇 |
冶金工业 | 92篇 |
原子能技术 | 6篇 |
自动化技术 | 121篇 |
出版年
2024年 | 2篇 |
2023年 | 10篇 |
2022年 | 20篇 |
2021年 | 29篇 |
2020年 | 14篇 |
2019年 | 14篇 |
2018年 | 18篇 |
2017年 | 14篇 |
2016年 | 29篇 |
2015年 | 26篇 |
2014年 | 42篇 |
2013年 | 53篇 |
2012年 | 32篇 |
2011年 | 54篇 |
2010年 | 38篇 |
2009年 | 33篇 |
2008年 | 41篇 |
2007年 | 38篇 |
2006年 | 35篇 |
2005年 | 23篇 |
2004年 | 31篇 |
2003年 | 26篇 |
2002年 | 13篇 |
2001年 | 8篇 |
2000年 | 7篇 |
1999年 | 6篇 |
1998年 | 17篇 |
1997年 | 21篇 |
1996年 | 9篇 |
1995年 | 7篇 |
1994年 | 5篇 |
1993年 | 10篇 |
1992年 | 3篇 |
1991年 | 4篇 |
1990年 | 8篇 |
1989年 | 2篇 |
1988年 | 6篇 |
1987年 | 4篇 |
1986年 | 4篇 |
1985年 | 4篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1980年 | 4篇 |
1979年 | 2篇 |
1977年 | 3篇 |
1976年 | 14篇 |
1975年 | 3篇 |
1972年 | 2篇 |
1968年 | 1篇 |
排序方式: 共有800条查询结果,搜索用时 15 毫秒
31.
The reversible addition-fragmentation chain transfer (RAFT) polymerization process was used to synthesize well-defined N-acryloxysuccinimide (NAS) based copolymers, very useful reactive building blocks for various applications. Kinetic studies of RAFT copolymerization of NAS with a bi-substituted acrylamide derivative, N-acryloylmorpholine (NAM), were performed in the presence of tert-butyl dithiobenzoate (tBDB). An excellent control was reached with very high conversions (>95%), molecular weights (MW) up to 80?000 g mol−1 and very narrow molecular weight distributions (MWD) (polydispersity indices, PDI<1.1), as determined by aqueous size exclusion chromatography with on-line light scattering detector (SEC/LS). In addition, the comparison of RAFT and conventional NAM/NAS free radical copolymerization indicated that the apparent reactivity ratios in RAFT are similar to the reactivity ratios determined from conventional copolymerization. An identical azeotropic composition (60/40 NAM/NAS molar ratio) was obtained providing perfectly random poly(NAM-co-NAS) copolymers with full control of composition and MW. These copolymer chains with regularly-distributed reactive functions can be integrated into more complex architectures. As an example, poly[(NAM-co-NAS)-b-NAM] block copolymers with length-varying poly(NAM) block were synthesized with a very efficient control over MW, MWD and composition. 相似文献
32.
Smet C Leroy A Sillen A Wieruszeski JM Landrieu I Lippens G 《Chembiochem : a European journal of chemical biology》2004,5(12):1639-1646
A combined strategy to obtain a partial NMR assignment of the neuronal Tau protein is presented. Confronted with the extreme spectral degeneracy that the spectrum of this 441 amino acid long unstructured protein presents, we have introduced a graphical procedure based on residue type-specific product planes. Combining this strategy with the search for pairwise motifs, and combining the spectra of different Tau isoforms and even of peptides derived from the native sequence, we arrive at a partial assignment that is sufficient to map the interactions of Tau with its molecular partners. The obtained assignments equally confirm the absence of regular secondary structure in the isolated protein. 相似文献
33.
Vincent Cantarel David Lambertin Arnaud Poulesquen Fabrice Leroux Guillaume Renaudin Fabien Frizon 《Ceramics International》2018,44(9):10558-10568
This work investigates emulsion templating to synthesize hexadecane oil/geopolymer composites. In a system with hexadecane as the internal (dispersed) phase and an alkali activated continuous phase without added surfactant, adding aluminosilicate clay particles does not increase resistance against creaming or coalescence, while adding a surfactant (L35 or CTAB) stabilizes the solid-liquid interface. Infrared studies and rheological studies of the associated geopolymerization determined that the presence of the organic phase or surfactant has no significant effect on the geopolymerization kinetics, as determined by the change in time of the Si-O-T IR stretching frequency and the rheological moduli involved during the process. The stabilization of the organic template is reminiscent of Pickering emulsion even though we employ a much greater amount of inorganic material for geopolymer formation. Although the addition of surfactant has a significant effect on the behavior of the paste, the percolation of the network remains unmodified, highlighting the fact that the phenomenon is not dependent on viscosity. Finally, rheological measurements were used to obtain the mass fractal dimension of the as-made gel network, which is able to differentiate the interfacial effect between surfactant molecules with a slightly denser interphase when a cationic surfactant is used. 相似文献
34.
Fast Measurements of the Gas‐Liquid Diffusion Coefficient in the Gaussian Wake of a Spherical Bubble 下载免费PDF全文
Nicolas Dietrich Jessica Francois Mélanie Jimenez Arnaud Cockx Pascal Guiraud Gilles Hébrard 《化学工程与技术》2015,38(5):941-946
A fast method is proposed for determining the oxygen gas‐liquid diffusion coefficient from measurements of the fluorescence quenching behind a bubble. The approach consists of capturing pictures of the concentration field at micro‐scale in the laminar bubble wake. The Gaussian concentration profiles measured in the wake are demonstrated to be systematically equivalent to an instantaneous plane diffusion case. The approach permits to accurately evaluate the gas‐liquid diffusivity in a very short time of around one second. 相似文献
35.
Modeling of the transfer between a porous medium and its surroundings is commonly made using transfer coefficients that are theoretically well known only under boundary layer hypothesis. The resolution of Navier–Stokes equations in the surroundings of the product in order to get information about the boundary conditions avoids the classical use of these transfer coefficients. In this article, a modeling and a simulation of superheated steam drying of a rectangular piece of porous medium is proposed using a coupling method between a porous medium code and a CFD software. In some cases of superheated steam drying, even if a thermal boundary layer exists, a mass boundary layer cannot be defined. Moreover, boiling occurs during the process. An analysis of the interfacial transfer coupled with the analysis of the temperature, moisture content, and pressure profiles inside the porous medium is proposed. 相似文献
36.
ABSTRACT Vacuum drying, j,e drying under absolute gas pressure of about 10? Pa. is an efficient means of reducing the process period and of producing good quality wood. We will examine here continuous vacuum drying where the plank surfaces are kept at a constant temperature, which remains above the boiling point, and moisture flowing to the surface is extracted from the kiln. We have carried out an experimental study of oak drying under such conditions. The drying rate and moisture content profile of the sample (40 mm thick) are recorded during the whole drying period. A model of continuous drying is established from general conservation equations with the main approximation that the air is rapidly extracted. The two constitutive equations of the model which describe temperature and water content fields are of a diffusive type and coupled through coefficients. The adequate boundary equation is not a convective one, but expresses a hygroscopic equilibrium between the vapour in the chamber and the wood surface. The mass diffusive coefficient can be adjusted to the drying rates through capillary pressure and bound water diffusion functions. The wood heterogeneity (seasonal growth) is the main factor of discrepancy in these functions. The simulated drying rates correspond with the experimental ones. 相似文献
37.
N. Arnaud J.Y. Cognard P. Davies P.Y. Le Gac 《Journal of Adhesion Science and Technology》2013,27(21):2355-2380
The objective of the study is to identify the 3D behaviour of an adhesive in an assembly, and to take into account the effect of ageing in a marine environment. To that end, three different tests were employed. Gravimetric analyses were used to determine the water diffusion kinetics in the adhesive. Bulk tensile tests were performed to highlight the effects of humid ageing on the adhesive behaviour. Modified Arcan tests were performed for several ageing times to obtain the experimental database which was necessary to identify constitutive models. A Mahnken–Schlimmer type model was determined for the unaged state according to a procedure developed in a previous study. This identification used inverse techniques. It was based on the unaged modified Arcan results and on a coupling between an optimisation routine and finite-element analysis. Then, a global inverse identification procedure was developed. Its aim was to relate the unaged parameters to the moisture concentration and overcome the difficulties usually associated with ageing of bonded assemblies in a humid environment: a non-uniformity of the stress state and a gradient of mechanical properties in the adhesive. This procedure was similar to the one used in the first part but needed modified Arcan results for several ageing times. It also required an initial assumption for the evolution of the Mahnken–Schlimmer parameters with the moisture concentration. 相似文献
38.
Arnaud Zenerino Sonia Amigoni Elisabeth Taffin de Givenchy Denis Josse Frédéric Guittard 《Reactive and Functional Polymers》2013,73(8):1065-1071
The main difficulty still encountered in the elaboration of polymer/silica nanocomposites is the control of the nanoparticles dispersion homogeneity and the stability of the nanoparticle dispersion in the surrounding substance. The innovative point of this work is the elaboration of hybrid networks in aqueous solution performed with ASE (alkali swellable emulsion) thickeners grafted with silica nanoparticles. The thickening ability of the polymer should favour silica nanoparticles dispersion in fluid matrices. Two ASE copolymers were realised by copolymerisation in emulsion of MA (methacrylic acid) and EA (ethyl acrylate) and/or TFEM (trifluoroethyl methacrylate). The substitution of a part of EA by TFEM gave fluorinated ASE copolymers. Their free acid functions were then coupled with different ratio of amine functionalized silica nanoparticles to afford nanocomposites. The amounts of silica nanoparticles in the copolymers were determined by thermogravimetric experiments. Depending on the silica nanoparticles/copolymer ratio in basic aqueous solutions we achieved stable translucent gel like aqueous suspensions of silica nanoparticles containing 1 wt.% of the polymer/SiO2 nanocomposite. 相似文献
39.
Yannick Raoul des Essarts Mohamad Sabbah Arnaud Comte Laurent Soulère Yves Queneau Yves Dessaux Valérie Hélias Denis Faure 《International journal of molecular sciences》2013,14(10):19976-19986
Bacteria belonging to the Pectobacterium genus are the causative agents of the blackleg and soft-rot diseases that affect potato plants and tubers worldwide. In Pectobacterium, the expression of the virulence genes is controlled by quorum-sensing (QS) and N-acylhomoserine lactones (AHLs). In this work, we screened a chemical library of QS-inhibitors (QSIs) and AHL-analogs to find novel QSIs targeting the virulence of Pectobacterium. Four N,N′-bisalkylated imidazolium salts were identified as QSIs; they were active at the μM range. In potato tuber assays, two of them were able to decrease the severity of the symptoms provoked by P. atrosepticum. This work extends the range of the QSIs acting on the Pectobacterium-induced soft-rot disease. 相似文献
40.
Laurent Boilet Michel Descamps Emmanuelle Rguiti Arnaud Tricoteaux Jianxi Lu Fabrice Petit Véronique Lardot Francis Cambier Anne Leriche 《Ceramics International》2013,39(1):283-288
Stoichiometric β-tricalcium phosphate (β-TCP) and hydroxyapatite (HA) powders were synthesized by chemical precipitation of aqueous solutions of diammonium phosphate and calcium nitrate. After a calcination treatment and a milling step, the powders were shaped by slip casting. The sintering temperature effect on the relative density and the average grain size was investigated. By natural sintering at 1200 and 1120 °C, densities of 98% and 99% were obtained for HA and TCP, respectively. After determination of minimum temperatures to obtain only closed porosity and a pre-sintering at these temperatures, hot isostatic pressing (HIP) treatment was carried out. Transparent or translucent samples were obtained, indicating a relative density very close to the theoretical value (>99.9%). Mechanical properties (three-point bending strength, fracture toughness, Young's modulus and Vickers hardness) were measured on both materials with similar grain size (~ 1 μm). Bending strengths of 181 and 105 MPa were measured for TCP and HA, respectively. 相似文献