There has been an intense research effort in the last decades in the field of biofouling prevention as it concerns many aspects of everyday life and causes problems to devices, the environment, and human health. Many different antifouling and antimicrobial materials have been developed to struggle against bacteria and other micro- and macro-organism attachment to different surfaces. However the “miracle solution” has still to be found. The research presented here concerns the synthesis of bio-based polymeric materials and the biological tests that showed their antifouling and, at the same time, antibacterial activity. The raw material used for the coating synthesis was natural rubber. The polyisoprene chains were fragmented to obtain oligomers, which had reactive chemical groups at their chain ends, therefore they could be modified to insert polymerizable and biocidal groups. Films were obtained by radical photopolymerization of the natural rubber derived oligomers and their structure was altered, in order to understand the mechanism of attachment inhibition and to increase the efficiency of the anti-biofouling action. The adhesion of three species of pathogenic bacteria and six strains of marine bacteria was studied. The coatings were able to inhibit bacterial attachment by contact, as it was verified that no detectable leaching of toxic molecules occurred. 相似文献
N‐Propargyl‐ and N‐homoallenyl‐2‐bromo‐β‐tryptamines undergo gold(I)‐catalyzed dearomatizing cyclizations to afford 2‐bromospiroindolenines that are in situ hydrolyzed to furnish spirooxindoles in a one‐pot process. Tryptophane derivatives (R2=CO2Et) led upon cyclization to chiral spirooxindoles in excellent diastereoselectivities.
Coplanar waveguide (CPW) and thin film microstrip (TFMS) lines integrating porous ultra low-k as inter-metal dielectric layers (k = 2.5) and copper as metal, are for the first time experimentally measured up to 110 GHz and under different temperature conditions, up to 200 °C. The extracted attenuation and propagation coefficients of those transmission lines are compared to simulations performed with MAGWEL software, a frequency domain 3-D Maxwell solver. Based on the characterization results some guidelines related to interconnect design are presented for future applications. 相似文献
ABSTRACT Vacuum drying, j,e drying under absolute gas pressure of about 10? Pa. is an efficient means of reducing the process period and of producing good quality wood. We will examine here continuous vacuum drying where the plank surfaces are kept at a constant temperature, which remains above the boiling point, and moisture flowing to the surface is extracted from the kiln. We have carried out an experimental study of oak drying under such conditions. The drying rate and moisture content profile of the sample (40 mm thick) are recorded during the whole drying period. A model of continuous drying is established from general conservation equations with the main approximation that the air is rapidly extracted. The two constitutive equations of the model which describe temperature and water content fields are of a diffusive type and coupled through coefficients. The adequate boundary equation is not a convective one, but expresses a hygroscopic equilibrium between the vapour in the chamber and the wood surface. The mass diffusive coefficient can be adjusted to the drying rates through capillary pressure and bound water diffusion functions. The wood heterogeneity (seasonal growth) is the main factor of discrepancy in these functions. The simulated drying rates correspond with the experimental ones. 相似文献
The objective of the study is to identify the 3D behaviour of an adhesive in an assembly, and to take into account the effect of ageing in a marine environment. To that end, three different tests were employed. Gravimetric analyses were used to determine the water diffusion kinetics in the adhesive. Bulk tensile tests were performed to highlight the effects of humid ageing on the adhesive behaviour. Modified Arcan tests were performed for several ageing times to obtain the experimental database which was necessary to identify constitutive models. A Mahnken–Schlimmer type model was determined for the unaged state according to a procedure developed in a previous study. This identification used inverse techniques. It was based on the unaged modified Arcan results and on a coupling between an optimisation routine and finite-element analysis. Then, a global inverse identification procedure was developed. Its aim was to relate the unaged parameters to the moisture concentration and overcome the difficulties usually associated with ageing of bonded assemblies in a humid environment: a non-uniformity of the stress state and a gradient of mechanical properties in the adhesive. This procedure was similar to the one used in the first part but needed modified Arcan results for several ageing times. It also required an initial assumption for the evolution of the Mahnken–Schlimmer parameters with the moisture concentration. 相似文献
Bacteria belonging to the Pectobacterium genus are the causative agents of the blackleg and soft-rot diseases that affect potato plants and tubers worldwide. In Pectobacterium, the expression of the virulence genes is controlled by quorum-sensing (QS) and N-acylhomoserine lactones (AHLs). In this work, we screened a chemical library of QS-inhibitors (QSIs) and AHL-analogs to find novel QSIs targeting the virulence of Pectobacterium. Four N,N′-bisalkylated imidazolium salts were identified as QSIs; they were active at the μM range. In potato tuber assays, two of them were able to decrease the severity of the symptoms provoked by P. atrosepticum. This work extends the range of the QSIs acting on the Pectobacterium-induced soft-rot disease. 相似文献
In this study, a method is developed to determine the oil mist characteristics for the minimal quantity lubricant process. The oil mist is characterized by the size, velocity, and volume flow rate of its particles. In each case, a specific measurement process is used: the laser diffraction granulometry method, the particle image velocimetry, and the gravimetric method. These methods are used in the case of static and simple models with different inner channels. Experimental tests have been done with the same inner channel as the existing spindle inner channel. Different output models with different inner canalizations have been tested, using these experimental processes. The main goal is to control the characteristics of output oil mist as a function of the input oil mist device parameters. 相似文献