Orienting Fibers by Extrusion in Reinforced Reactive Powder Concrete

This paper deals with the problem of orienting short metal fibers (12 mm length, aspect ratio 60) in a reactive powder concrete during an extrusion process to manufacture reinforced tubes. By choosing an appropriate geometry for the die it is possible to orient the fibers in an orthoradial direction, which is the most efficient if one wishes to reinforce the tube for an internal pressure loading. This result is obtained with both a theoretical and an experimental approach. In a theoretical framework the authors carried out numerical modeling with a constitutive behavior deduced from the anisotropic suspensions theory. This calculus enabled the authors to design the shape of the die. Tubes have then been extruded and the fibers' orientation has been measured with optical microscopy.     

Chatter milling modeling of active magnetic bearing spindle in high-speed domain

A new dynamical modeling of Active Magnetic Bearing Spindle (AMBS) to identify machining stability of High Speed Milling (HSM) is presented. This original modeling includes all the minimum required parameters for stability analysis of AMBS machining. The stability diagram generated with this new model is compared to classical stability lobes theory. Thus, behavior's specificities are highlighted, especially the major importance of forced vibrations for AMBS. Then a sensitivity study shows impacts of several parameters of the controller. For example, gain adjustment shows improvements on stability. Side milling ramp test is used to quickly evaluate the stability. Finally, the simulation results are then validated by HSM cutting tests on a 5 axis machining center with AMBS.     

Surface roughness variation of thin wall milling, related to modal interactions

High-speed milling operations of thin walls are often limited by the so-called regenerative effect that causes poor surface finish. The aim of this paper is to examine the link between chatter instability and surface roughness evolution for thin wall milling. Firstly, the linear stability lobes theory for the thin wall milling optimisation was used. Then, in order to consider the modal interactions, an explicit numerical model was developed. The resulting nonlinear system of delay differential equations is solved by numerical integration. The model takes into account the coupling mode, the modal shape, the fact that the tool may leave the cut and the ploughing effect. Dedicated experiments are carried out in order to confirm this modelling. This paper presents surface roughness and chatter frequency measurements. The stability lobes are validated by thin wall milling. Finally, the modal behaviour and the mode coupling give a new interpretation of the complex surface finish deterioration often observed during thin wall milling.     

Mild and neutral deprotections catalyzed by cerium(IV) ammonium nitrate

The development of a novel, chemoselective, and catalytic deprotection methodology that proceeds under mild and neutral conditions is described, and its mechanism of action is analyzed in some detail. The scope, limitations, and advantages of this protocol are discussed. Selected applications in synthesis are also highlighted.     

Failure and scaling properties of a softening interface connected to an elastic block

The damage growth in a softening interface connected to an elastic block is analysed. The elastic block, assumed to be infinite, is modelled as a two-dimensional continuum and the interface is one-dimensional with a constitutive response which follows a scalar damage model. The solution technique is based on the equilibrium of the interfacial forces resulting from the deformation of the elastic block and from the interface constitutive response. The interface failure process is compared to that of a hierarchical model which was obtained analytically (Delaplace et al., 1998). The two are found to be similar, without an internal length scaling the distribution of damage at the inception of macro-cracking. Finally, scale effects on the occurrence of bifurcation and instability are considered. It is shown that bifurcation may occur prior to or after the limit point under displacement control, depending on the elastic block height or stiffness. This revised version was published online in July 2006 with corrections to the Cover Date.