A hybrid method for detecting the onset of local necking by monitoring the bulge forming load

Strain-based Forming Limit Diagrams (FLD), which are typically obtained under linear or quasi-linear loading conditions, describe the limiting strains in terms of the major and minor in-plane strains before the onset of necking or the final failure (FFD). These strains can be detected by analysing the strain field in the vicinity of necking or cracking defects. It has generally been agreed that the loading versus time signal is not suitable for detecting necking processes. A novel hybrid method of detecting the onset of necking based on the experimental and simulated bulging load is presented in this paper. This method consists mainly in comparing the experimental forming load, i.e., a load showing plastic instability, with the numerical predictions obtained by performing finite element simulation. The simulation of the bulging process does not include any damage or failure criteria. A homogeneous forming load can therefore be simulated without requiring any information about the localization. This method was applied to detecting the onset of local necking in circular and elliptic quasistatic bulge tests on sheet material, with a diameter of 200 mm. Two materials were tested, a 0.8 mm thick DP450 Dual Phase steel sheet and a 1 mm thick AA6016-T4 aluminium sheet. The onset of necking observed with our method was compared with the results obtained by performing Hogström’s analysis based on the measured strain field over time and similar necking strains were obtained. Beside, the Bressian Williams Hill (BWH) shear criterion was identified for each test from experimental results. A slight scattering of the shear stress values was observed.     

New potential for preparation of performing h-BN coatings via polymer pyrolysis in RTA furnace

An innovative IR irradiation annealing process is used to increase the crystallization ratio of hexagonal boron nitride (h-BN) coatings on pure titanium pellets. Since the polymer pyrolysis route requires heating the green polymer at high temperature to convert it into a ceramic, the use of IR radiation furnace (compared to a resistive furnace) allows achievement of better crystallized h-BN while the substrate remains at relatively low temperature (<1000 °C). Annealing treatments have been performed under argon or nitrogen using either a halogen lamp or a Rapid Thermal Annealing (RTA) furnace. Advanced structural and chemical characterizations have shown a good chemical stability of the coatings. In addition, it has been revealed that samples annealed under Ar present a micro-composite structure at the interphase composed of a μ-layer of TiB₂/TiB/Ti(N)_x between the coating and the substrate, whereas samples annealed under nitrogen display a simpler structure at the interphase, with only TiN.     

Desorption of large molecules with light-element clusters: Effects of cluster size and substrate nature

This contribution focuses on the conditions required to desorb a large hydrocarbon molecule using light-element clusters. The test molecule is a 7.5 kDa coil of polystyrene (PS61). Several projectiles are compared, from C₆₀ to 110 kDa organic droplets and two substrates are used, amorphous polyethylene and mono-crystalline gold. Different aiming points and incidence angles are examined. Under specific conditions, 10 keV nanodrops can desorb PS61 intact from a gold substrate and from a soft polyethylene substrate. The prevalent mechanism for the desorption of intact and ‘cold’ molecules is one in which the molecules are washed away by the projectile constituents and entrained in their flux, with an emission angle close to ∼70°. The effects of the different parameters on the dynamics and the underlying physics are discussed in detail and the predictions of the model are compared with other published studies.     

On the relationship between snow grain morphology and in-situ near infrared calibrated reflectance photographs

Seasonal and permanent snow cover a significant portion of our planet, and its impact on climate is significant. Through specific thermophysical properties, snow controls radiative and turbulent fluxes between the ground and the atmosphere, but many aspects of the energy balance are poorly understood due to lingering uncertainties regarding snow properties, such as grain size in particular. Rapid and accurate measurement method has yet to be developed given the reality of field and laboratory logistical constraints, and the sensitivity of snow to any sort of manipulation.In this paper, we investigate the relationship between snow grain morphology parameters measured from visible (traditional) snow grain photography and optical diameter estimated from Near-InfraRed (NIR) reflectance photographs of snow walls. A total of 51 snowpits were analyzed during our International Polar Year field campaign across a 1000 km South-to-North transect over Eastern Canada. We compared the NIR measurements with the theoretical snow albedo model of Kokhanovsky and Zege (2004). Results show the large difference between the snow specific surface area (SSA) of snow grains derived from snow albedo model and the geometrical (visual) diameter. From three different snow grain classes which can be distinguished from traditional photography, linkages can be made with shape factors required in the optical model in order to retrieve optical grain size from NIR photography.     

Accuracy of Fabry-Perot method of semiconductor laser gain measurement

The Fabry?Perot (FP) method of semiconductor laser gain measurement, first proposed by Hakki and Paoli (1975), is widely used. It is based on the measurement of the FP resonances excited by spontaneous emission. Its validity rests on the assumption that a single mode is significant. We show, using a simplified laser model, that this assumption is valid only when the power mirror reflectivity is very small, or near the laser oscillating frequency. For example, the error is in the order of 20% when the power facet reflectivities are equal to 37% and the modal gain is unity. These results apply to both index-guided and gain-guided lasers.     

A compact model of MOSFET mismatch for circuit design

This paper presents a compact model for MOS transistor mismatch. The mismatch model uses the carrier number fluctuation theory to account for the effects of local doping fluctuations along with an accurate and compact dc MOSFET model. The resulting matching model is valid for any operation condition, from weak to strong inversion, from the linear to the saturation region, and allows the assessment of mismatch from process and geometric parameters. Experimental results from a set of transistors integrated on a 0.35 /spl mu/m technology confirm the accuracy of our mismatch model under various bias conditions.     

Failure and scaling properties of a softening interface connected to an elastic block

The damage growth in a softening interface connected to an elastic block is analysed. The elastic block, assumed to be infinite, is modelled as a two-dimensional continuum and the interface is one-dimensional with a constitutive response which follows a scalar damage model. The solution technique is based on the equilibrium of the interfacial forces resulting from the deformation of the elastic block and from the interface constitutive response. The interface failure process is compared to that of a hierarchical model which was obtained analytically (Delaplace et al., 1998). The two are found to be similar, without an internal length scaling the distribution of damage at the inception of macro-cracking. Finally, scale effects on the occurrence of bifurcation and instability are considered. It is shown that bifurcation may occur prior to or after the limit point under displacement control, depending on the elastic block height or stiffness. This revised version was published online in July 2006 with corrections to the Cover Date.     

Experimental investigation of a new type of interfacial instability in a reactive coextrusion process

This paper deals with the study of new interfacial instabilities, called “grainy” defects, in coextrusion process of reactive multilayer polymers. The main objective was to better understand this phenomenon since no help can be found in the literature. The fundamental approach from a micro‐scale to a macro‐scale involves the study of relationships between polymer structure, processing, and interfacial properties. The influence of these parameters on the generation of “grainy” defects during coextrusion has been assessed in correlation with physicochemical properties. Through this work, rheological properties and the interfacial morphology between tie and barrier layers have been investigated by shear stress relaxation experiments and transmission electronic microscopy, respectively. Depending on the reactive polymers, the interfacial coupling was found to significantly alter the stress relaxation behavior by extending the relaxation time and generating an interfacial roughness. Hence, relations between the copolymer architecture, the relaxation process, and the interfacial morphology were established in correlation with the generation of grainy defects in coextrusion process. POLYM. ENG. SCI., 55:2542–2552, 2015. © 2015 Society of Plastics Engineers     

Assessing the Antimicrobial Activity of Polyisoprene Based Surfaces

There has been an intense research effort in the last decades in the field of biofouling prevention as it concerns many aspects of everyday life and causes problems to devices, the environment, and human health. Many different antifouling and antimicrobial materials have been developed to struggle against bacteria and other micro- and macro-organism attachment to different surfaces. However the “miracle solution” has still to be found. The research presented here concerns the synthesis of bio-based polymeric materials and the biological tests that showed their antifouling and, at the same time, antibacterial activity. The raw material used for the coating synthesis was natural rubber. The polyisoprene chains were fragmented to obtain oligomers, which had reactive chemical groups at their chain ends, therefore they could be modified to insert polymerizable and biocidal groups. Films were obtained by radical photopolymerization of the natural rubber derived oligomers and their structure was altered, in order to understand the mechanism of attachment inhibition and to increase the efficiency of the anti-biofouling action. The adhesion of three species of pathogenic bacteria and six strains of marine bacteria was studied. The coatings were able to inhibit bacterial attachment by contact, as it was verified that no detectable leaching of toxic molecules occurred.