Design,manufacture and initial operation of the beryllium components of the JET ITER-like wall

The aim of the JET ITER-like wall project was to provide JET with the plasma facing material combination now selected for the DT phase of ITER (bulk beryllium main chamber limiters and a full tungsten divertor) and, in conjunction with the upgraded neutral beam heating system, to achieve ITER relevant conditions.The design of the bulk Be plasma facing components had to be compatible with increased heating power and pulse length, as well as to reuse the existing tile supports originally designed to cope with disruption loads from carbon based tiles and be installed by remote handling. Risk reduction measures (prototypes, jigs, etc.) were implemented to maximize efficiency during the shutdown. However, a large number of clashes with existing components not fully captured by the configuration model occurred.Restarting the plasma on the ITER-like Wall proved much easier than for the carbon wall and no deconditioning by disruptions was observed. Disruptions have been more threatening than expected due to the reduced radiative losses compared to carbon, leaving most of the plasma magnetic energy to be conducted to the wall and requiring routine disruption mitigation. The main chamber power handling has achieved and possibly exceeded the design targets.     

A Tetrahedral Boronic Acid Diester Formed by an Unnatural Amino Acid in the Ligand Pocket of an Engineered Lipocalin

Boronic acids have long been known to form cyclic diesters with cis-diol compounds, including many carbohydrates. This phenomenon was previously exploited to create an artificial lectin by incorporating p-borono-l -phenylalanine (Bpa) into the ligand pocket of an engineered lipocalin, resulting in a so-called Borocalin. Here we describe the X-ray analysis of its covalent complex with 4-nitrocatechol as a high-affinity model ligand. As expected, the crystal structure reveals the formation of a cyclic diester between the biosynthetic boronate side chain and the two ortho-hydroxy substituents of the benzene ring. Interestingly, the boron also has a hydroxide ion associated, despite an only moderately basic pH 8.5 in the crystallization buffer. The complex is stabilized by a polar contact to the side chain of Asn134 within the ligand pocket, thus validating the functional design of the Borocalin as an artificial sugar-binding protein. Our structural analysis demonstrates how a boronate can form a thermodynamically stable diester with a vicinal diol in a tetrahedral configuration in aqueous solution near physiological pH. Moreover, our data provide a basis for the further engineering of the Borocalin with the goal of specific recognition of biologically relevant glycans.     

Daily Intake of Cod or Salmon for 2?Weeks Decreases the 18:1n-9/18:0 Ratio and Serum Triacylglycerols in Healthy Subjects

Intake of fish and omega-3 (n-3) fatty acids is associated with a reduced concentration of plasma triacylglycerols (TAG) but the mechanisms are not fully clarified. Stearoyl-CoA desaturase-1 (SCD1) activity, governing TAG synthesis, is affected by n-3 fatty acids. Peripheral blood mononuclear cells (PBMC) display expression of genes involved in lipid metabolism. The aim of the present study was to estimate whether intake of lean and fatty fish would influence n-3 fatty acids composition in plasma phospholipids (PL), serum TAG, 18:1n-9/18:0 ratio in plasma PL, as well as PBMC gene expression of SCD1 and fatty acid synthase (FAS). Healthy males and females (n = 30), aged 20–40, consumed either 150 g of cod, salmon, or potato (control) daily for 15 days. During intervention docosahexaenoic acid (DHA, 22:6n-3) increased in the cod group (P < 0.05), while TAG concentration decreased (P < 0.05). In the salmon group both eicosapentaenoic acid (EPA, 20:5n-3) and DHA increased (P < 0.05) whereas TAG concentration and the 18:1n-9/18:0 ratio decreased (P < 0.05). Reduction of the 18:1n-9/18:0 ratio was associated with a corresponding lowering of TAG (P < 0.05) and an increase in EPA and DHA (P < 0.05). The mRNA levels of SCD1 and FAS in PBMC were not significantly altered after intake of cod or salmon when compared with the control group. In conclusion, both lean and fatty fish may lower TAG, possibly by reducing the 18:1n-9/18:0 ratio related to allosteric inhibition of SCD1 activity, rather than by influencing the synthesis of enzyme protein.     

Investigation into etching mechanism of polyethylene terephthalate (PET) films treated in helium and oxygenated‐helium atmospheric plasmas

This research makes an investigation into the etching mechanism of atmospheric plasma conditions on the surface of polyethylene terephthalate (PET) films. Two types of untreated PET films (S/200 and S/500) were exposed to plasma for 0 to 5.0 min in 30‐s increments. The first set of each film type was treated in helium plasma, while the second was treated in oxygenated‐helium plasma. Differential Scanning Calorimetry (DSC) was used to characterize pre‐ and post‐exposure films. Weight changes and the degree of solubility were also determined. Based on peak area results, the percent crystallinity of PET S/200 increased by an average of 4.57% (helium treated) and 13.56% (oxygenated‐helium treated), while the S/500 showed only a small increase. There was no significant change in the melting or crystallization temperatures of either film type, indicating a decrease in amorphous content versus an increase in crystalline material. Weight loss analysis supports this theory. Solubility testing revealed a continual decrease in swelling as exposure time was increased. A model was developed to predict the change in the degree of solubility for polyphase surfaces considering the etching rate per phase. The model was applied to PET with good correlation between the model and experimental data. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 2383–2389, 2004     

Radical styrene polymerization in the presence of trace levels of sulfonic acids

The bulk polymerization of styrene in the presence of the vinyl functional sulfonic acid 2‐sulfoethylmethacrylate (SEM) was found to have utility for making polystyrenes with narrow polydispersity, bimodal polydispersity, and ultrahigh molecular weight at fast polymerization rates. Narrow polydispersity polymers were made by the addition of SEM to nitroxide‐mediated polymerizations. Bimodal polydispersity polymers were made by the ultrahigh molecular weight component being made in the presence of SEM in the absence of an initiator and the low molecular weight component being made in the presence of an initiator and/or chain‐transfer agent. Ultrahigh molecular weight monomodal polystyrenes were prepared at much faster polymerization rates than possible via spontaneous polymerization in the absence of SEM. SEM was found to be more effective, by an order of magnitude, than camphor sulfonic acid on a weight basis and, because it is copolymerized into the polymer chain, should not lead to corrosion problems during fabrication of the polymer. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 869–875, 2003     

Liquid-Liquid Extraction of Caproic and Caprylic Acid: Solvent Properties and pH

Caproic acid (C6) and caprylic acid (C8) can be produced during anaerobic fermentation via chain elongation processes. This study focused on the selective recovery of C6 and C8 from a fermentation broth with liquid-liquid extraction. Eight solvents, including alcohols, esters, an organophosphorus compound, and an amine, were evaluated based on their extraction efficiency and selectivity for C6 and C8. The highest extraction efficiency of C6 (46 %) and C8 (93 %) at pH 6.0 was achieved by 1-octanol. Oleyl alcohol, 1-decanol, and 1-octanol had the highest selectivity for C6 and C8.     

Industrial Experience in Pressurized Steam Drying of Beet Pulp,Sewage Sludge and Wood Chips.

ABSTRACT

Drying in superheated steam under pressure gives possibilities for pollution free drying, energy recovery. reduced drying time and a very compact drying equipment.

Products are dried i n a pressurized cellular fluid bed by super heated steam blown through the cells. Above the fluid bed dust is separated before the steam is reheated and recirculated to the cells by a fan. The evaporated water leaves the dryer as usable steam at e.g. 3 bar g, and full energy recovery is obtained. Today 14 plants have been builtor are under construction, with capacities from 2 to 40t / h water evaporation.

This technology is suited for drying of beet pulp, residues from starch production of corn or wheat. sludge. spent grain. brown coal. wood chips and bark.

The technology shows great options for integration in steam systems in various industries, whereby drying is possible without using primary energy and pollution is avoided.     

A neurophysiologically‐based analysis of lightness and brightness perception

Psychophysical, achromatic luminance threshold, and scaling data have been analyzed and found to follow from nonlinear, hyperbolic responses of retinal cones. For short (0.1 s) stimulus duration, a stable state of visual adaptation could explain the threshold response, but for longer durations a change of adaptation had to be considered. This resulted in a contrast sensitivity that increased when the stimulus duration increased and became constant for higher test field luminances. Threshold and scaling data can thus be traced back to cone‐specific responses over a much larger range of stimulus intensity than has been anticipated earlier. The experimental results, including those for lightness and brightness scaling, have been compared with the CIELAB and the CIEDE2000 color formulas. The idea of combining cone responses with adaptive changes to describe luminance responses resulted in a common cone‐based response formula for describing both luminance thresholds and scaling data. Adaptive changes explain the reason why both Weber–Fechner and Stevens’ laws are valid. © 2015 Wiley Periodicals, Inc. Col Res Appl, 41, 339–351, 2016     

Porometry, porosimetry, image analysis and void network modelling in the study of the pore-level properties of filters

We present fundamental and quantitative comparisons between the techniques of porometry (or flow permporometry), porosimetry, image analysis and void network modelling for seven types of filter, chosen to encompass the range of simple to complex void structure. They were metal, cellulose and glass fibre macro- and meso-porous filters of various types. The comparisons allow a general re-appraisal of the limitations of each technique for measuring void structures. Porometry is shown to give unrealistically narrow void size distributions, but the correct filtration characteristic when calibrated. Shielded mercury porosimetry can give the quaternary (sample-level anisotropic) characteristics of the void structure. The first derivative of a mercury porosimetry intrusion curve is shown to underestimate the large number of voids, but this error can be largely corrected by the use of a void network model. The model was also used to simulate the full filtration characteristic of each sample, which agreed with the manufacturer's filtration ratings. The model was validated through its correct a priori simulation of absolute gas permeabilities for track etch, cellulose nitrate and sintered powder filters.