Improvement of PEEM images from thick inhomogeneous antiwear films using a thin Pt coating

Antiwear films formed from zinc dialkyl-dithiophosphate, in base oil, are known to create inhomogeneous agglomeration of patches on metallic surfaces up to 400 nm thick. It has been found that these patches (termed antiwear pads) are also non-conducting. These two features create difficulties in analyzing data obtained using X-ray photoelectron emission microscopy (X-PEEM). Topography and near-surface charging dominate images obtained using X-PEEM techniques, which can alter electron trajectories and lower signal-to-noise counts. It has been found that the application of a thin continuous platinum coating provides sufficient neutralization to eliminate the positive charge-buildup and improve signal-to-noise. This improves data analysis even with the thickest pads. Examples of charging alleviation and improved signal-to-noise ratios (obtained in the P L-edge spectroscopy) are shown. Furthermore, data analysis of the spectromicroscopy stacks show improved fitting and better polyphosphate distribution mapping for the films.     

Spatially resolved nanoscale chemical and mechanical characterization of ZDDP antiwear films on aluminum–silicon alloys under cylinder/bore wear conditions

summary  Understanding the lubrication of aluminum–silicon (Al–Si) alloys (>18 Si) under conditions similar to those in the cylinder/bore system is vital to determining their applicability to current engine designs. A novel investigation of the location of zinc-dialkyl-dithiophosphate (ZDDPs) antiwear (AW) film formation on an Al–Si alloy has been performed using X-ray absorption near edge structure (XANES) analysis, X-ray photoelectron emission spectroscopy (X-PEEM), and imaging nanoindentation techniques. A study of the initial stages of wear (10 min) to prolonged rubbing (60 min) was performed. The findings show that the film forms primarily on the raised silicon grains and is consistent with a zinc polyphosphate glass. The film has an elastic modulus of ~70 GPa and a similar elastic response to a ZDDP AW film formed on steel under the same conditions. This provides the first direct observation and characterization of a ZDDP antiwear film on Al–Si alloys using spatially resolved chemical and mechanical techniques at the nanoscale.     

Oxidation Behaviour of NiCrAl and NiCoCrAl Bond Coatings Under Industrial Gas Turbine Conditions

Model bond coatings were deposited with a wide range of compositions and their oxidation behaviour investigated at 900 °C. These Ni–Co–Cr–Al coatings were deposited using magnetron sputtering (a physical vapour deposition technique) onto 10 mm diameter sapphire substrates. A range of compositions was generated by co-sputtering from a combination of two or three sources: Ni–10 wt% Cr, Ni–20Cr, Ni–50Cr, Ni–20Co–40Cr and/or Ni–40Co–20Cr combined with pure Al. The coatings were oxidised at 900 °C and the scales formed characterised. These data have been summarised into oxide predominance diagrams to show the relationships between coating compositions and the formation of protective Cr₂O₃ or Al₂O₃ scales, or the formation of other, less protective oxides (or mixed oxides). Both coating composition and exposure temperature (by comparison with earlier published research) were found to influence the oxide scale growth rate and oxide type, and thus the resulting degree of protection.     

The effect of the third invariant on the strength and failure of boron carbide and silicon carbide

This article presents new test data to assess the effect the third invariant has on the strength and failure of two ceramic materials: boron carbide and silicon carbide. Two experimental techniques are used: the Brazilian test that produces a biaxial state of stress, and a new technique that uses a high-pressure confinement vessel to load a specially designed dumbbell specimen in triaxial extension. The dumbbell geometry provides two important advantages over the typically used cylindrical specimen: no adhesive is required to bond the specimen to the load cell because the dumbbell geometry naturally takes the specimen into tension, and any loading asymmetries are essentially eliminated due to the axisymmetric geometry. The results show that when the stress state is on the tensile meridian the equivalent stress at failure is constant, independent of the hydrostatic pressure. The average equivalent stress at failure is for boron carbide and for silicon carbide. The Brazilian test was only performed on boron carbide and failed at , much higher than when on the tensile meridian () indicating that the effect of the third invariant is significant (because of the difference in the failure strength) and must be accounted for to accurately predict when failure will occur.     

Differentiation of the concepts of luck and skill.

20 Ss from each grade level (kindergarten, Grades 2, 4, 6, and 8) were presented a luck (figures to be matched with a standard were not visible but were on the underside of cards) and a skill (figures were visible) version of a task using items from the Matching Familiar Figures Test. Questioning Ss about the performance of hypothetical others on these tasks revealed 4 levels of differentiation of luck and skill. The least mature Ss focused on the visual complexity of tasks rather than on the fact that the luck task permitted only guessing. On this basis, they expected luck outcomes to reflect effort and considered the luck task to require less effort than the skill task. Only the most mature Ss clearly understood that effort could not affect outcomes on the luck task and selectively attributed skill outcomes to effort and luck outcomes to luck. The most mature Ss also spent less time than did less mature Ss in the face of failure on luck tasks, but spent more time on skill tasks. Findings of age-related differences in the differentiation of skill (effort and ability) and luck and of associated differences in behavior make the analysis of the development of achievement-related cognition and behavior more complete. (13 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Shape deformations in rough-surface scattering: improved algorithms

We present new, stabilized shape-perturbation methods for calculations of scattering from rough surfaces. For practical purposes, we present new algorithms for both low- (first- and second-) and high-order implementations. The new schemes are designed with guidance from our previous results that uncovered the basic mechanism behind the instabilities that can arise in methods based on shape perturbations [D. P. Nicholls and F. Reitich, J. Opt. Soc. Am. A 21, 590 (2004)]. As was shown there, these instabilities stem from significant cancellations that are inevitably present in the recursions underlying these methods. This clear identification of the source of instabilities resulted also in a collection of guiding principles, which we now test and confirm. As predicted, improved low-order algorithms can be attained from an explicit consideration of the recurrence. At high orders, on the other hand, the complexity of the formulas precludes an explicit account of cancellations. In this case, however, the theory suggests a number of alternatives to implicitly mollify them. We show that two such alternatives, based on a change of independent variables and on Dirichlet-to-interior-derivative operators, respectively, successfully resolve the cancellations and thus allow for very-high-order calculations that can significantly expand the domain of applicability of shape-perturbation approaches.     

斯巴克 Cayin A-300B综合功放

即使是那些短视的批评家们现在也不得不承认,自十年前起重现美国国内音频市场的单端真空管功放,不仅仅代表了一股逝去的潮流.尽管这类同任何一款普通扬声器搭配都有问题的功放都决不会成为司空见惯的产品,但同为现实的是,SET(单端真空管功放)的魅力已让它在市场中永远占据着一席之地.总会有制造商想要生产SET,正如总有人想要扮演莎士比亚或蒸馏苦艾酒.     

HYDROGEN TRAIPB-NUUEAR MAGNETIC RESONANCE FOR INDUSTRIAL MOISTURE 8EN8MG

ABSTRACT

A procedure was developed based on a three-component physical model to simulate the drying characteristics of Laird lentils. In this model, the cotyledons were simplified as a homogeneous slab where moisture transfer was governed by a one-dimensional diffusion equation, and the hilum and seedcoat were considered as two parallel routes for moisture to escape from a seed. The simulation procedure was verified with the experimental data from thin-layer drying testing on samples of 19.0 to 24.5% initial moisture content at temperatures from 23 to 80°C and relative humidities from 5 to 70%. Using previously obtained information on the transport properties of the cotyledons, the seedcoat, and the hilum, the simulation followed the drying data closely over temperatures between 23 and 60°C.     

Wear Mechanisms of Chromia Refractories in Slagging Gasifiers

The hot-face refractory lining is a key component of gasification systems. The refractory liner protects the gasification system from the high-temperature corrosive gaseous and from the molten slag environment associated with the conversion of carbon feedstocks. This paper will discuss the effect of gasifier operating conditions and carbon feedstock slag/ash chemistry on the refractory service life. Particular attention is focused on the wear mechanism of chromia refractories, determined through postmortem analysis of spent refractory bricks from service in gasifiers. Also presented is the behavior of a phosphate-containing chromia refractory with improved resistance to structural spalling.