Convenient method for preparation of a new absorbent based on biofunctionalized graphene oxide hydrogels using nitrene chemistry and click reaction

A new graphene oxide (GO)-based hydrogel was synthesized through cross-linking of biofunctionalized graphene oxide nanosheets by di-alkyne polyethylene glycol as cross-linking agent. In this respect, nitrene chemistry as a convenient and straightforward protocol was developed for biofunctionalization of GO using an azido-starch as an eco-friendly, biodegradable and cost-effective material. In the next step, 1,3-dipolar cycloaddition chemistry, a green and highly efficient approach was utilized in cross-linking of functionalized GO by PEG through click reaction between remaining azido groups of starch on the surface of GO sheets and terminal alkyne groups of polyethylene glycol. Formation of aziridine and triazole rings during functionalization and cross-linking in this method could evidently improve biological activities of the obtained hydrogel compared to the conventional methods. The antibacterial activity of the new compounds was explored. The synthesized hydrogel showed antibacterial properties against Gram-positive and Gram-negative bacteria due to the presence of triazole rings. Also, the resulting hydrogel exhibited high dye removal efficiency and it can be utilized in water treatment effectively. The adsorption kinetics was analyzed through the effects of adsorption time and the dye concentration on the adsorption capacity. Kinetic data were accurately described by a pseudo-second-order model.     

The off‐grid frequency selective millimeter wave channel estimation

Broadband millimeter wave (mmW) systems are a promising pioneer of cellular communication for next generation which is utilizing the hybrid baseband/analog beamforming structures along with the miniature massive antenna arrays at both sides of the communication link. mmW channel with an available unlicensed spread spectrum is frequency selective because the signal bandwidth can be larger than the coherence bandwidth. Due to the sparse nature of mmW channel, extracting compressive sensing model of the system is preferable. In fact, exploiting the sparse structure will lead to the reduction of the computational complexity, because there is a reduction in the channel training length compared with the conventional methods such as least square estimation. Most of the prior works have considered on‐grid quantized departure/arrival angles in the input/output antennas to obtain a sparse virtual channel model. However, the sparse angles in the physical channel model are continuous where this continuity indicates a mismatch between the physical angles and the on‐grid angles. Such a mismatch will contribute to unwanted components in the virtual channel model. Given these extra components, the conventional compressive sensing tools are unable to recover the channel. In this paper, we propose two solutions for overcoming the problem caused by off‐grid angle selection. The first is based on the vector shaping, and the second one is based on the sparse total least square concepts. Simulation results demonstrate that the proposed methods both could obtain an adequate channel recovery and are preferable regarding computational complexity concerning the newly developed surrogate method.     

Comparison of pH-dependent sonodisruption of re-assembled casein micelles by 35 and 130 kHz ultrasounds

Sonodisruption behavior of re-assembled casein micelles was compared at two ultrasound frequencies (35 and 130 kHz) by turbidity measurement and laser-diffraction based particle size analysis. Sonochemical ultrasound (130 kHz) was more effective than power ultrasound (35 kHz) in micelle disruption. This was attributed to the higher strain rates generated upon implosion of cavities, as well as the liberation of more free radicals to the surrounding medium. The higher the pH of solution, the more effective was the ultrasonic disruption due to a looser expanded assembly of particles at higher pH values. Sonochemical ultrasound decreased the consistency coefficient of casein solutions and increased their flow index except at a pH value of 6.35, while power ultrasound did not affect the flow behavior of solutions across the whole pH range.     

Compression and impact testing of two-layer composite pyramidal-core sandwich panels

Quasi-static uniform compression tests and low-velocity concentrated impact tests were conducted to reveal the failure mechanisms and energy absorption capacity of two-layer carbon fiber composite sandwich panels with pyramidal truss cores. Three different volume-fraction cores (i.e., with different relative densities) were fabricated: 1.25%, 1.81%, and 2.27%. Two-layer sandwich panels with identical volume-fraction cores (either 1.25% or 2.27%), and also stepwise graded panels consisting of one light and one heavy core, were investigated under uniform quasi-static compression. Under quasi-static compression, load peaks were identified with complete failure of individual truss layers due to strut buckling or strut crushing, and specific energy absorption was estimated for different core configurations. In the impact test, the damage resulting from low-velocity concentrated impact was investigated. Our results show that compared with glass fiber woven textile truss cores, two-layer carbon fiber composite pyramidal truss cores have comparable specific energy absorptions, and thus could be used in the development of novel light-weight multifunctional structures.     

Hydrothermal synthesis of Pt/MWCNTs nanocomposite electrocatalysts for proton exchange membrane fuel cell systems

A hydrothermal method for preparation of size-controlled Pt nanoparticles dispersed highly on multiwalled carbon nanotubes (Pt/MWCNTs) has been studied to optimize the effective parameters (temperature, time, pH and stirring rate) using Taguchi method. The synthesized Pt/MWCNTs nanocomposite samples were characterized through X-ray diffraction (XRD), transmission electron microscopy (TEM) and X-ray fluorescence (XRF) analyses to identify mean Pt nanoparticles size and Pt content. The analysis of the primary experimental data and demonstration of the main effect trend of each parameter showed that a reaction temperature of about 140 °C, a reaction period of 5 h, a slightly basic reaction pH (∼9) and a stirring rate of 500 rpm are the optimum process conditions which give a low mean Pt nanoparticles size (2.8 nm) and a high Pt content (19.4 wt.%) simultaneously. Cyclic voltammetry (CV) analysis showed that under optimum conditions the synthesized sample gives a specific surface area of 99 m² g⁻¹. Obtaining the polarization curves for the two fabricated membrane electrode assemblies (MEAs) using the optimized catalyst and a commercial Pt/C catalyst (10 wt.%, Aldrich) with Pt loading of 0.4 mg cm⁻² demonstrated that the catalyst prepared under optimum conditions shows a considerably better performance.     

Design,Construction, and Installation of Movable Electrode Biasing System on Tokamak

The first results of the movable electrode biasing experiments performed on the IR-T1 tokamak are presented. For this purpose, a movable electrode biasing system was designed, constructed, and installed on the IR-T1 tokamak, and then the positive voltage applied to an electrode inserted inside the tokamak limiter and the plasma current, poloidal and radial components of the magnetic fields, loop voltage, and diamagnetic flux in the absence and presence of the biased electrode were measured. Results compared and discussed.     

Isotropic-kinematic cyclic hardening characteristics of plate steels

Cyclic hardening of metals is considered as one of the most important features that affects extremely the hysteresis behavior of steel structures. One approach to study this characteristic is dividing it into two components, including isotropic hardening and kinematic hardening, and defining any of these components for any type of metals by calibrated data obtained from experiments. However, the lack of these calibrated data on metals, restricts this approach. Therefore, in this paper the isotropic and kinematic characteristics of five different steel grades from 100 to 485 MPa, under various strain ranges between ±1 and ±7% were proposed. Afterwards, four of these five grades were validated in order to find the appropriate combination of data for any of them, and to compare the result of this approach with those obtained from a well-known hardening model, Ramberg-Osgood. The results showed the high accuracy of the isotropic-kinematic hardening model in comparison to the Ramberg-Osgood method.     

Relationship Between the Electrostatic Sensitivity of Nitramines and Their Molecular Structure

In this paper, a new approach is introduced to predict the electrostatic sensitivity of nitramines on the basis of their molecular structure. The ratio of carbon to oxygen and the existence of two specific structural parameters can be used for the prediction of the electrostatic sensitivity of nitramines. The results are also compared with quantum mechanical computations from [9] so that the new method gives better predictions with respect to the measured data. Electrostatic sensitivities calculated by the new method for two new nitramines CL‐20 [2,4,6,8,10,12‐hexanitro‐2,4,6,8,10,12‐hexaazaisowurtzitane] and TNAZ [1,3,3‐trinitroazatidine] are also close to the experimental data.     

Middleware extensions that trade consistency for availability

Replicated distributed object systems are deployed to provide timely and reliable services to actors at distributed locations. This paper treats applications in which data updates are dependent on satisfaction of integrity constraints over multiple objects. Network partitions, caused by occasional link failures, overload or attacks create problems in keeping both consistency and availability in such networks. We propose a means of achieving higher availability by providing partition‐awareness in middleware. The general approach has been illustrated by implementing a number of CORBA extensions that trade consistency for availability during network partitions. This paper contains a thorough experimental evaluation that presents the gains and costs of our approach. The experiments clearly illustrate the benefit of our protocols in terms of significantly higher availability and the number of performed operations. Copyright © 2009 John Wiley & Sons, Ltd.