A review on graphene and its derivatives as the forerunner of the two-dimensional material family for the future

Journal of Materials Science - In 2004, Geim and Novoselov discovered two-dimensional graphene comprised of sp2 carbon atoms. Graphene is a thin layer of carbon consisting of excellent surface...     

Top Indian scientists as public communicators: a survey of their perceptions,attitudes and communication behaviors

Scientometrics - Research on science communication, especially from scientists’ point of view, is rare in the Indian context. This first of its kind study in India explores the perceptions...     

Influence of growth parameters on the dopant configuration of nitrogen-doped graphene synthesized from phthalocyanine molecules

Synthesis of nitrogen-doped graphene (NDG) via chemical vapor deposition (CVD) using phthalocyanine, a solid precursor containing carbon and nitrogen, is reported. The effect of the growth parameters (temperature, time, and carrier gas) on the surface morphology, dopant configuration, and conductivity of the films was studied. The NDG films were synthesized at different substrate temperatures of 1050 °C, 950 °C, and 850 °C for different growth times of 5–15 min in the presence of an Ar?+?H₂ gas mixture. Significantly, pyrrolic-N type defects are observed predominantly after 5 min of growth time. At 1050 °C, pyrrolic N content is around 45.4% after 5 min of growth which decreased to 24.1% after 15 min of growth, while the graphitic-N content increased from 41.2 to 76% at the same time. It is demonstrated that the conversion of pyrrolic type of nitrogen to graphitic nitrogen defects can be arrested by changing the carrier gas from Ar?+?H₂ to Ar. The pyrrolic-N content increased to 64% by changing the gas from Ar?+?H₂ to Ar at 15 min. The electrolyte gated field-effect transistors were fabricated using the obtained films, and dopant-dependent mobility was observed. The mobility for pyrrolic-N-dominated film is 13.6 cm² V^?1 s^?1 increasing to 62.8 cm² V^?1 s^?1 for graphitic-N-dominated film.

     

An improved multimodal medical image fusion scheme based on hybrid combination of nonsubsampled contourlet transform and stationary wavelet transform

This research proposes an improved hybrid fusion scheme for non-subsampled contourlet transform (NSCT) and stationary wavelet transform (SWT). Initially, the source images are decomposed into different sub-bands using NSCT. The locally weighted sum of square of the coefficients based fusion rule with consistency verification is used to fuse the detailed coefficients of NSCT. The SWT is employed to decompose approximation coefficients of NSCT into different sub-bands. The entropy of square of the coefficients and weighted sum-modified Laplacian is employed as the fusion rules with SWT. The final output is obtained using inverse NSCT. The proposed research is compared with existing fusion schemes visually and quantitatively. From the visual analysis, it is observed that the proposed scheme retained important complementary information of source images in a better way. From the quantitative comparison, it is seen that this scheme gave improved edge information, clarity, contrast, texture, and brightness in the fused image.     

Metabolizable Semiconducting Polymer Nanoparticles for Second Near‐Infrared Photoacoustic Imaging

Photoacoustic (PA) imaging in the second near‐infrared (NIR‐II) window (1000–1700 nm) holds great promise for deep‐tissue diagnosis due to the reduced light scattering and minimized tissue absorption; however, exploration of such a noninvasive imaging technique is greatly constrained by the lack of biodegradable NIR‐II absorbing agents. Herein, the first series of metabolizable NIR‐II PA agents are reported based on semiconducting polymer nanoparticles (SPNs). Such completely organic nanoagents consist of π‐conjugated yet oxidizable optical polymer as PA generator and hydrolyzable amphiphilic polymer as particle matrix to provide water solubility. The obtained SPNs are readily degraded by myeloperoxidase and lipase abundant in phagocytes, transforming from nonfluorescent nanoparticles (30 nm) into NIR fluorescent ultrasmall metabolites (≈1 nm). As such, these nanoagents can be effectively cleared out via both hepatobiliary and renal excretions after systematic administration, leaving no toxicity to living mice. Particularly these nanoagents possess high photothermal conversion efficiencies and emit bright PA signals at 1064 nm, enabling sensitive NIR‐II PA imaging of both subcutaneous tumor and deep brain vasculature through intact skull in living animals at a low systematic dosage. This study thus provides a generalized molecular design toward organic metabolizable semiconducting materials for biophotonic applications in NIR‐II window.     

Angiotensin II induces hypertrophy of human airway smooth muscle cells: expression of transcription factors and transforming growth factor-beta1

The three-dimensional structure of the complex between a T cell receptor (TCR) beta chain (mouse Vbeta8.2Jbeta2.1Cbeta1) and the superantigen (SAG) staphylococcal enterotoxin C3 (SEC3) has been recently determined to 3.5 resolution. To evaluate the actual contribution of individual SAG residues to stabilizing the beta-SEC3 complex, as well as to investigate the relationship between the affinity of SAGs for TCR and MHC and their ability to activate T cells, we measured the binding of a set of SEC3 and staphylococcal enterotoxin B (SEB) mutants to soluble recombinant TCR beta chain and to the human MHC class II molecule HLA-DR1. Affinities were determined by sedimentation equilibrium and/or surface plasmon detection, while mitogenic potency was assessed using T cells from rearrangement-deficient TCR transgenic mice. We show that there is a clear and simple relationship between the affinity of SAGs for the TCR and their biological activity: the tighter the binding of a particular mutant of SEC3 or SEB to the TCR beta chain, the greater its ability to stimulate T cells. We also find that there is an interplay between TCR-SAG and SAG-MHC interactions in determining mitogenic potency, such that a small increase in the affinity of a SAG for MHC can overcome a large decrease in the SAG's affinity for the TCR. Finally, we observe that those SEC3 residues that make the greatest energetic contribution to stabilizing the beta-SEC3 complex ("hot spot" residues) are strictly conserved among enterotoxins reactive with mouse Vbeta8.2, thereby providing a basis for understanding why SAGs having other residues at these positions show different Vbeta-binding specificities.     

Short segment Barrett's esophagus--the need for standardization of the definition and of endoscopic criteria

There has been a recent increase in abstracts and publications reporting intestinal metaplasia in the distal esophagus and cardia. The terms "short segment Barrett's esophagus," "intestinal metaplasia of the esophagogastric junction," and "intestinal metaplasia of the cardia" are being used to describe either similar or different entities. This review article deals with the current data on these issues, the definition of short segment Barrett's esophagus including the endoscopic and histologic criteria, the rationale for separating short segment Barrett's esophagus from intestinal metaplasia of the cardia, and a simple classification of intestinal metaplasia.     

Design and development of enhanced bandwidth multi‐frequency slotted antenna for 4G‐LTE/WiMAX/WLAN and S/C/X‐band applications

A multi‐frequency rectangular slot antenna for 4G‐LTE/WiMAX/WLAN and S/C/X‐bands applications is presented. The proposed antenna is comprised of rectangular slot, a pair of E‐shaped stubs, and an inverted T‐shaped stub and excited using staircase feed line. These employed structures help to achieve multiband resonance at four different frequency bands. The proposed multiband slot antenna is simulated, fabricated and tested experimentally. The experimental results show that the antenna resonates at 2.24, 4.2, 5.25, and 9.3 GHz with impedance bandwidth of 640 MHz (2.17‐2.82 GHz) covering WiMAX (802.16e), Space to Earth communications, 4G‐LTE, IEEE 802.11b/g WLAN systems defined for S‐band applications. Also the proposed antenna exhibits bandwidth of 280 MHz (4.1‐4.38 GHz) for Aeronautical and Radio navigation applications, 80 MHz (4.2‐4.28 GHz) for uncoordinated indoor systems,1060 MHz (5.04‐6.1 GHz) for the IEEE 802.11a WLAN system defined for C‐band applications and 2380 MHz (7.9‐10.28 GHz) defined for X‐band applications. Further, the radiation patterns for the designed antenna are measured in anechoic chamber and are found to agree well with simulated results.     

Novel analysis of the size and orientation dependent resonance phenomenon of the microstrip line coupled complementary split‐ring resonator

The purpose of this article is to provide a comprehensive investigation on the resonance phenomenon of microstrip line coupled complementary split‐ring resonator (CSRR) with different orientation and relative size. It is shown that when the relative size of the CSRR is smaller than the host line, the CSRR with its slit oriented orthogonal to the line axis will not excite effectively and show weak resonance behavior. However, when the slit is positioned along the line axis, the cross‐polarization effect comes into play, which excites the CSRR through the mixed coupling. To ensure the correctness, several numerical simulations are carried out for different substrate height and relative permittivity. Finally, a prototype is fabricated and measured for the experimental validation.     

Linearly tapered meander line broadband monopole tag antenna with T‐match for Ultra High Frequency Radio Frequency Identification applications

In this paper, a compact, broadband linearly tapered meandered monopole tag antenna for UHF‐RFID is designed and optimized using particle swarm optimization (PSO) algorithm. An inductive T‐match network is utilized for impedance matching with capacitive Higgs‐4 chip. The optimization goal of PSO was conjugate matching and in consequence the maximization of read range. Equivalent circuit of the proposed tag antenna is derived using ADS software to validate its impedance characteristics. The performance of the proposed tag in terms of tag power sensitivity, read range, realized gain, and differential radar cross section has been experimentally characterized. To check the tolerance of the designed tag to various object platforms, its read range performance is also verified on objects like wood, fiber, plastic, and so forth. Furthermore, read pattern of the proposed tag has been measured and found to have figure of eight in E‐plane and omnidirectional in H‐plane. Experimental results reveal that the proposed tag covers 865‐867 MHz (ETSI band, Europe) and 902‐928 MHz (FCC band, United States) both major RFID bands with a read range of 10 and 12 m, respectively. The proposed tag has 2060 mm³ of volumetric size with maximum measured readable distance of 12 m with EIRP of 3.28 W.