Estimation of crack propagation in polymer electrolyte membrane fuel cell under vibration conditions

In transportation applications, the main reasons of mechanical damage in polymer electrolyte membrane fuel cell (PEMFC) are road-induced vibrations and impact loads. The most vulnerable place of these cells is the interface between membrane and catalyst layer in the membrane electrode assembly (MEA). Hence, studies on mechanical strength of PEMFC should focus on that interface. The objective of present study lies in the fact that employing a prediction method to investigate the damage propagation behavior of vibration applied PEMFC using artificial neural network (ANN). The data available in the literature are used to constitute an ANN model. Three-layer model; input, hidden and output, are used for construction of ANN structure. Initial delamination length (a), amplitude (A), frequency (ω) and time (t) are used as input neurons whereas delamination length is output. Levenberg–Marquardt algorithm is selected as learning algorithm. On the other hand, number of hidden layer neuron is decided with the use of different neuron numbers by trial and error method. It is concluded that prediction capability of ANN model is in allowable limits and model can be suggested as efficient way of delamination length estimation.     

Poly(3-hydroxyalkanoate)s: Diversification and biomedical applications: A state of the art review

Biomaterials have played an important role in the treatment of disease and the improvement of health care. Synthetic and naturally occurring biodegradable and biocompatible polymers have been used as biomaterials. Polyhydroxyalkanoates (PHAs) are promising materials for biomedical applications because they are biodegradable, non-toxic and biocompatible. We will shortly summarize the modification reactions, which include functionalization and grafting reactions, to improve the mechanical, thermal and hydrophilic properties of PHAs. The use of the modified PHAs in numerous biomedical applications, such as sutures, cardiovascular patches, wound dressings, scaffolds in tissue engineering, tissue repair/regeneration devices, drug carriers will be discussed in this review.     

Effect of nano-silica on the chemical durability and mechanical performance of fly ash based geopolymer concrete

In this study, the effect of nano silica on the short term severe durability performance of fly ash based geopolymer concrete (GPC) specimens was investigated. Four types of GPC were produced with two types of low calcium fly ashes (FAI and FAII) with and without nano silica, and ordinary Portland cement concrete (OPC) concrete was also cast for reference. For the geopolymerization process, the alkaline activator has selected a mixture of sodium silicate solution (Na₂SiO₃) and sodium hydroxide solution (NaOH) with a ratio (Na₂SiO₃/ NaOH) of 2.5. Main objectives of the study were to investigate the effect of usability or replaceability of nano silica-based low calcium fly ash based geopolymer concretes instead of OPC concrete in structural applications and make a contribution to standardization process of the fly ash based geopolymer concrete. To achieve the goals, four types of geopolymer and OPC concretes were subjected to sulfuric acid (H₂SO₄), magnesium sulfate (MgSO₄) and seawater (NaCl) solutions with concentrations of 5%, 5%, and 3.5%, respectively. Visual appearances and weight changes of the concretes under chemical environments were utilized for durability aspects. Compressive, splitting tensile and flexural strength tests were also performed on specimens to evaluate the mechanical performance under chemical environments. Results indicated that FAGPC concretes showed superior performance than OPC concrete under chemical attacks due to low calcium content. Amongst the chemical environments, sulfuric acid (H₂SO₄) was found to be the most dangerous environment for all concrete types. In addition, nano silica (NS) addition to FAGPC specimens improved both durability and residual mechanical strength due to the lower porosity and more dense structure. The FAIIGPC specimens including nano silica showed the superior mechanical performance under chemical environment.     

Ozonated Olive Oil with a High Peroxide Value for Topical Applications: In-Vitro Cytotoxicity Analysis with L929 Cells

Previous studies have shown that ozonated vegetable oils have been used topically for healing of cutenous wounds. The aim of this study is to evaluate the dose dependent use of ozonated olive oil with high peroxide value (OZ) on the viability of cells for preventing side effects in topical applications. To the best of our knowledge, there are no reports investigaing the effect of peroxide value of ozonated olive oil associated with its cytotoxic activity on mouse non-neoplastc fibroblast cell lines (L929). Therefore, the present study was carried out by using OZ alone and/or in combination with glycerol and olive oil. In our study OZ was prepared by using pure olive oil. Both olive oil and glycerol are non-toxic and can be mixed with OZ uniformly. The cytotoxic activity of samples against L929 fibroblasts was assessed using the tetrazolium salt 3-[4,5-dimethylthiazol-2-yl]-2,5 diphenyltetrazolium bromide (MTT) assay. The peroxide value of synthesized OZ was found to be in the range of 2700–2900 mEq O₂/kg oil. The OZ/olive oil group did not show any cell death at all concentrations tested (p > 0.05) however OZ/glycerol group showed statistically significant reductions in viability at higher concentrations (p = 0.004–0.006) compared to the control group. Conclusively, using OZ/olive oil with a peroxide value of 2700–2900 mEq O₂/kg oil for short-term incubation was non-cytotoxic to the L929 fibroblast cell line.     

Structural properties of boron carbide nanoparticles: Application of a new set of Stillinger–Weber parameters

A suitable Stillinger–Weber (SW) potential energy function parameter set is developed for finite boron structures by genetic algorithm and trial error techniques. Boron structure geometries in 7–24 atoms range, calculated by ab initio methods, are taken as the fitting criteria in the parameter set development. This parameter set is used together with another SW parameter set developed for carbon–carbon interactions in order to investigate boron carbide nanoparticles in the form of B_xC_x where 8 ? x ? 14. In addition, B₈₀C₁₂ nanoparticle structure is investigated using local optimization technique.     

Ecological materials and methods in the textile industry: Atmospheric‐plasma treatments of naturally colored cotton

Naturally colored cotton, in accordance with currently increasing interest in ecological textile products and methods, has increased in popularity. Commerce is another of the primary reasons along with interest in environmentally friendly and niche‐concept approaches. However, the color palette is limited; no bleaching or dyeing process is used. Instead, only a pretreatment to make the fibers hydrophilic is necessary. This can be induced with several different methods. In this respect, atmospheric‐plasma treatments have emerged as an alternative. In this study, knitted and naturally colored cotton fabrics were treated with argon and air atmospheric plasma. The hydrophilicity, wickability, surface friction coefficient, air permeability, water vapor permeability, thermal conductivity, thermal resistance, and fastness were investigated. The surfaces of untreated and plasma‐treated fabrics were analyzed with Fourier transform infrared/attenuated total reflectance and scanning electron microscopy to detect and compare the chemical and morphological modifications. The results revealed that atmospheric‐plasma treatments are capable of modifying the surface of naturally colored cotton fabrics without any important loss in the color strength or fastness and thermal properties. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

A novel strategy for cartilage tissue engineering: Collagenase-loaded cryogel scaffolds in a sheep model

In this study, we developed a novel strategy, through which cartilage tissue pieces were placed in a sheep cartilage defect model and covered with a collagenase incorporated cryogel scaffold (in vivo cartilage tissue engineering, IVCTE group). While applying this strategy, the chondrocytes could be isolated inside the body and the treatment could be accomplished in one session. To compare our strategy, to another group, in which we used cultured cells and Chondro-gide, standard matrix-induced autologous chondrocyte implantation (MACI) was applied. Although the MACI applied group demonstrated better healing than IVCTE, the type II collagen synthesis was better in the IVCTE group compared to MACI applied group. Collagenase did not have detrimental effect on surrounding cartilage in IVCTE group. The preliminary results of the novel strategy applied group (IVCTE) were promising.