Laser-assisted ablation and plasma formation of titanium explored by LIBS,QCM, optical microscopy and SEM analyses along with mechanical modifications under different pressures of Ar and Ne

This study deals with the investigation of Nd:YAG laser-assisted ablation and plasma formation of Ti at irradiance of 0.85 GW cm^-2 under Ar and Ne environment at various pressures ranging from 10-120 Torr.Laser-induced breakdown spectroscopy is used to evaluate plasma parameters,whereas quartz crystal microbalance is used for ablation yield measurements.The crater depth is evaluated by optical microscopy.The surface features are explored by scanning electron microscope(SEM) analysis a...     

Erucic acid ameliorates the lipopolysaccharide-induced memory deficit in rats through inhibited inflammation cytokines expression/caspase 3/NF-κB pathways

Erucic acid is a single unsaturated fatty acid that falls under the omega-9 fatty acid family. It was suggested to treat Wistar rats with lipopolysaccharide (LPS)-induced memory impairment and minimize cognitive impairment. A total of 30 animals were randomized: group I was normally treated group, group II was administered with LPS, group III was treated with LPS along with erucic acid at the dose of 10 mg kg^–1 p.o.^–1, group IV was treated with LPS along with erucic acid at 20 mg kg^–1 p.o.^–1 and group V was the erucic acid per se group provided at the dose of 20 mg kg^–1 p.o.^–1 per se. Behavioral tests were evaluated by using the Morris water maze and Y-maze. Biochemical analysis including acetylcholine esterase (AChE), choline acetyltransferase (ChAT), glutathione (GSH), catalase activity (CAT), superoxide dismutase (SOD), and nitric oxide (NO) along with proinflammatory mediators tumor necrosis factor-α (TNF-α), interleukin-1β (IL-1β), caspase 3, and neuroinflammatory biomarker (nuclear factor kappa B-NF-κB) were measured. Erucic acid produced substantial behavioral improvement in the Y-maze test, including spontaneous alterations and reduced latency time during acquisition, and a longer duration of time in the consolidation phase undergoing the MWM test. Furthermore, erucic acid improved the AChE, proinflammatory markers, and oxidative stress as well as restoring endogenous antioxidant levels, ChAT, caspase 3, and NF-κB levels. Erucic acid may be a therapeutic component for conditions related to memory disorders such as memory impairment, enhances memory functioning, and protects against neuronal damage.     

Facile Hydrothermal Synthesis of Copper Chromite Nanoparticles for Efficient Photocatalytic Degradation of Acid Orange 7 Dye

In this paper, the hydrothermal method was utilized for the facile synthesis of copper chromite nanoparticles in the absence (abbreviated as CC1) and presence of citric acid (abbreviated as CC2) and tartaric acid (abbreviated as CC3) as templates. The synthesized nanoparticles were characterized using different tools such as XRD, FT-IR, UV–Vis, FE-SEM, HR-TEM, and BET. The average crystallite size of the CC1, CC2, and CC3 samples is 25.45, 20.26, and 12.75 nm, respectively. The FT-IR spectra show two bands in the range 613–616 cm^?1 and 511–514 cm^?1, which are characteristic of the spinel copper chromite crystalline structure. The optical energy gaps of the CC1, CC2, and CC3 samples are 1.25, 1.88, and 1.92 eV, respectively. The synthesized nanoparticles were used for the degradation of the acid orange 7 dye under visible light irradiations. The highest % degradation was obtained at pH?2.5 and irradiation time?=?40 min. The % degradation of the acid orange 7 dye using CC1, CC2, and CC3 photocatalysts at pH?2.50 and time?=?40 min is 87.38, 96.52, and 98.81, respectively. The degradation of the acid orange 7 dye was markedly reduced with the addition of isopropyl alcohol or disodium ethylenediaminetetraacetate, confirming that the hydroxyl radicals and holes routes play a fundamental role in the degradation process of the acid orange 7 dye. The degradation of the acid orange 7 dye is slightly affected by the addition of ascorbic acid, confirming a minor concentration of oxygen anion radicals.

     

Application of Novel Modified Chitosan Hydrogel Composite for the Efficient Removal of Eriochrome Black T and Methylene Blue Dyes from Aqueous Media

Journal of Inorganic and Organometallic Polymers and Materials - In this paper, chitosan/Fe3O4/graphene oxide hydrogel was synthesized then modified with 2,6-pyridinedicarbonyl dichloride to obtain...