Preparation of an anion‐exchange adsorbent by the radiation‐induced grafting of vinylbenzyltrimethylammonium chloride onto cotton cellulose and its application for protein adsorption

Poly(vinylbenzyltrimethylammonium chloride)‐graft‐cotton cellulose, an anion‐exchange matrix, was synthesized by a mutual radiation‐induced grafting technique with a ⁶⁰Co γ‐radiation source. The grafted matrix was characterized by grafting yield estimation, elemental analysis, Fourier transform infrared spectroscopy, and scanning electron microscopy. The grafting yield decreased with the increase in the dose rate. However, the grafting yield and nitrogen content of grafted samples increased almost linearly with an increase in the total irradiation dose. To evaluate the performance of the grafted anion‐exchange matrix, the protein adsorption and elution behavior were investigated in a continuous column process under various experimental conditions, with bovine serum albumin used as a model protein. The binding and elution behavior of the anion‐exchange matrix depended on different experimental parameters, such as the grafting yield, ionic strength, pH of the medium, and amount of protein loaded. From a breakthrough curve, the equilibrium binding capacity and elution percentage of the grafted anion‐exchange matrix were estimated to be 40 mg/g and 94%, respectively. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 5512–5521, 2006     

Short fibre elastomer composites: effect of fibre length,orientation, loading and bonding agent

A series of short fibre reinforced styrene butadiene rubber (SBR) composites were prepared by incorporating sisal fibres of different lengths and different concentrations. The vulcanization behaviour and the properties of the vulcanizates were measured by the relevant ASTM procedures. The processing characteristics such as green strength and mill shrinkage were improved by the addition of fibres. The properties like tensile strength, tear strength, moduli at 10% and 20% elongations were found to be maximum for composites containing longitudinally oriented fibres of length 6 mm. Mixes containing 35 phr loading of fibres and bonding agent showed better mechanical performance than others. The failure behaviour of tensile and tear specimens have been analysed by scanning electron microscopy techniques. Paper presented at the poster session of MRSI AGM VI, Kharagpur, 1995     

Electrosynthesis and impedance studies on zinc selenide

Electrochemical impedance measurements have been used to characterize zinc selenide films prepared by electrochemical co-deposition at a platinum rotating disk electrode. Estimations of capacitance and polarization resistance of variously prepared electrodeposits have been carried out to determine charge carrier density and corrosion rates.     

Design Errors: Inefficiency or Carelessness of Designer?

Design defects are experienced in many projects; the difference is only in the extent of occurrence. This technical note discusses a design error case in a building project in Nepal, where the designer made the wrong assumptions in roof treatment work for waterproofing as well as for heat insulation purposes. From the investigation of the problem, it was found that the waterproofing polymer was not applied directly over concrete slab top. Use of heavy concrete block as a heat insulation material also helped to increase the leakage problem. The problem evoked loss of prestige for project officials, the design consortium, and the contractor.     

Improved accuracy and convergence of discretized population balance for aggregation: The cell average technique

A new discretization method for aggregation equations is developed. It is compared to the fixed pivot technique proposed by Kumar and Ramkrishna (1996a. On the solution of population balance equations by discretization—I. A fixed pivot technique. Chemical Engineering Science 51, 1311-1332). The numerical results for aggregation problems by discretized population balances are consistently overpredicting and diverge before the gelling point in the case of a gelling kernel. The present work establishes a new technique which assigns the particles within the cells more precisely. This is achieved by taking first the average of the newborn particles within the cell and then assigning them to the neighboring nodes such that pre-chosen properties are exactly preserved. The new technique preserves all the advantages of the conventional discretized methods and provides a significant improvement in predicting the particle size distribution (PSD). In addition, it is found that the technique is a powerful tool for the computation of gelling problems. The effectiveness of the technique is illustrated by application to several aggregation problems for suitably selected aggregation kernels including physically relevant kernels.     

Growth of ZnSe∶Mn Nanocrystals from Vapour Phase

ZnSe∶Mn nanocrystals were grown by chemical vapour transport method using the matrix of SiO2 aerogels. The cubic structure of the nanocrystals was confirmed by powder X-ray diffraction (XRD) and electron diffraction (ED) studies. The size of the crystals was observed using transmission electron microscope (TEM). The oxidation state of Mn in ZnSe nanocrystal was found using electron spin resonance (ESR) spectrum. The room temperature luminescence measurements show the peaks corresponding to both bandgap of the material and Mn in ZnSe.     

ShOC rectifier: a new metal-semiconductor device with excellent forward and reverse characteristics

We report a new structure, called the shielded ohmic contact (ShOC) rectifier which utilizes trenches filled with a high-barrier metal to shield an Ohmic contact during the reverse bias. When the device is forward biased, the ohmic contact conducts with a low forward drop. However, when reverse biased, the Ohmic contact is completely shielded by the high-barrier Schottky contact resulting in a low reverse leakage current. Two dimensional numerical simulation is used to evaluate and explain the superior performance of the proposed ShOC rectifier.     

Liquid phase epitaxial growth of pure and doped GaSb layers: morphological evolution and native defects

Undoped and Te-doped gallium antimonide (GaSb) layers have been grown on GaSb bulk substrates by the liquid phase epitaxial technique from Ga-rich and Sb-rich melts. The nucleation morphology of the grown layers has been studied as a function of growth temperature and substrate orientation. MOS structures have been fabricated on the epilayers to evaluate the native defect content in the grown layers from theC-V characteristics. Layers grown from antimony rich melts always exhibitp-type conductivity. In contrast, a type conversion fromp- ton- was observed in layers grown from gallium rich melts below 400 C. The electron mobility of undopedn-type layers grown from Ga-rich melts and tellurium doped layers grown from Sb- and Ga-rich solutions has been evaluated. Paper presented at the poster session of MRSI AGM VI. Kharagpur. 1995     

Estimation of wood char size at the end of devolatilization in a bubbling fluidized bed combustor

Two processes, namely shrinkage and primary fragmentation are known to be the major causes of size reduction of wood during its devolatilization in a fluidized bed combustor. A simple phenomenological model incorporating these effects to compute the average char size at the end of devolatilization is proposed. Experiments are conducted in a bubbling fluidized bed combustor using wood having three different shapes namely, cylinder, cuboid and sphere, to measure the average char size at the end of devolatilization. The model prediction of average char size agrees with the measured values within a deviation of 15%. An experimental correlation is derived to determine the number of fragments and is used to estimate the mean char size.