Effect of Celestite-Calcite Mineralogy on Their Separation by Attrition Scrubbing

Celestite ore is one of the principle economic resources of strantium element. Naturally, it contains some impurities, with the main one being the calcite mineral. In this article, the separation of celestite from calcite was conducted using attrition scrubbing based on the difference in the hardness between the two minerals. Due to the friability of calcite, it was expected to be collected in fine fraction, however, this was not the case. The observed results showed the presence of calcite in both coarse and fine fractions. A high percentage of calcite was found in the coarse fraction and decreased as the size did as well. Yet, at certain sizes its behavior was changed in that the decrease in size increased the calcite percentage. This behavior was clarified using detailed characterization of the studied sample using size analysis, x-ray diffraction, chemical analysis, and microspcopisc investigation. In addition, a detailed microscopic analysis for the products of the attrition scrubbing was conducted to explain the observed behavior.     

Inactivation of pathogenic Klebsiella pneumoniae by CuO/TiO2 nanofibers: A multifunctional nanomaterial via one-step electrospinning

The fabrication and characterization of one-dimensional CuO/TiO₂ nanofibers with high photocatalytic and antibacterial activities are presented. The CuO/TiO₂ nanofibers were prepared by electrospinning of colloid composed of titanium isopropoxide, poly(vinylpyrroliodine) (PVP) and copper nanoparticles and calcination at 700 °C in air for 1 h. The antibacterial activity was tested using Klebsiella pneumoniae as model organism by calculation of the minimum inhibitory concentration (MIC). The obtained CuO/TiO₂ nanofibers showed prominent photocatalytic activity under visible light to degrade reactive black5 and reactive orange16 dyes in aqueous solutions and effectively catalyze K. pneumoniae inactivation. The decomposition process of the cell wall and cell membrane was directly observed by TEM analysis after the exposure of the K. pneumoniae to the nanofibers. Interestingly, the introduced photocatalyst can be reused with the same photocatalytic activity. Overall, the combination of CuO and TiO₂ can be synergistic and resulted in CuO/TiO₂ composite nanofibers having superior photocatalytic and antimicrobial potential to impede K. pneumoniae growth which causes bacterium to die ultimately.     

Photocatalytic activities of electrospun tin oxide doped titanium dioxide nanofibers

SnO₂ doped TiO₂ electropsun nanofiber photocatalysts were successfully prepared by means of electrospinning process. The surface morphology, structure and optical properties of the resultant products were characterized by field-emission electron microscopy (FE-SEM), X-ray diffraction (XRD), high-resolution transmission electron microscopy (HR-TEM), X-ray photoelectron spectroscopy (XPS), UV–vis spectroscopy, photoluminescence (PL) and cathodoluminescence (CL) techniques. The utilized physiochemical analyses indicated that the introduced SnO₂ doped TiO₂ nanofibers have a smooth surface and uniform diameters along their lengths. The photocatalytic performance of the composite nanofibers was tested for degradation of methylene blue (MB) and methyl orange (MO) dye solution under ultraviolet (UV) irradiation. Under the UV irradiation, the photocatalytic reaction rate in case of utilizing SnO₂-doped TiO₂ nanofibers was rapidly increased than that of the pristine TiO₂ nanofibers. Overall, this study demonstrates cheap, stable and effective material for photocatalytic degradation at room temperature.     

A flow cell for transient voltammetry and in situ grazing incidence X-ray diffraction characterization of electrocrystallized cadmium(II) tetracyanoquinodimethane

An easy to fabricate and versatile cell that can be used with a variety of electrochemical techniques, also meeting the stringent requirement for undertaking cyclic voltammetry under transient conditions in in situ electrocrystallization studies and total external reflection X-ray analysis, has been developed. Application is demonstrated through an in situ synchrotron radiation-grazing incidence X-ray diffraction (SR-GIXRD) characterization of electrocrystallized cadmium (II)-tetracyanoquinodimethane material, Cd(TCNQ)₂, from acetonitrile (0.1 mol dm⁻³ [NBu₄][PF₆]). Importantly, this versatile cell design makes SR-GIXRD suitable for almost any combination of total external reflection X-ray analysis (e.g., GIXRF and GIXRD) and electrochemical perturbation, also allowing its application in acidic, basic, aqueous, non-aqueous, low and high flow pressure conditions. Nevertheless, the cell design separates the functions of transient voltammetry and SR-GIXRD measurements, viz., voltammetry is performed at high flow rates with a substantially distended window to minimize the IR (Ohmic) drop of the electrolyte, while SR-GIXRD is undertaken using stop-flow conditions with a very thin layer of electrolyte to minimize X-ray absorption and scattering by the solution.     

Novel dispersed magnetite core–shell nanogel polymers as corrosion inhibitors for carbon steel in acidic medium

Novel core–shell preparing poly(2-acrylamido-2-methylpropane sulfonic acid) (PAMPS) and copolymers with acrylic acid (AA) or acrylamide (AM) magnetic nanogels with controllable particle size produced via free aqueous polymerization at room temperature have been developed for the first time. The crosslinking polymerization was carried out in the presence of N,N′-methylenebisacrylamide (MBA) as a crosslinker, N,N,N′,N′-tetramethylethylenediamine (TEMED) and potassium peroxydisulfate (KPS) as redox initiator system. The structure and morphology of the magnetic nanogels were characterized by Fourier transform infrared spectroscopy (FTIR), transmission and scanning electron microscopy (TEM and SEM). The effectiveness of the synthesized compounds as corrosion inhibitors for carbon steel in 1 M HCl was investigated by various electrochemical techniques such as potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). The results showed enhancement in inhibition efficiencies with increasing the inhibitor concentrations and temperatures. The results showed the nanogel particles act as mixed inhibitors. Adsorption of nanogel particles was found to fit the Langmuir isotherm and was chemisorption.     

Vector Control Scheme of Five-Phase Induction Machines under Open-Circuit Phase Faults

Multiphase induction machine is normally controlled using rotor field oriented vector control. Under phase（s） loss, the machine currents can be optimally controlled to satisfy certain optimization criteria. In this paper, a vector control scheme to a five-phase induction machine is introduced to ensure equal phase currents and minimum torque ripples under a phase open circuit. The controller idea can be extended to any number of phases with any number of open phases. The fundamental dq components of the stator voltage are obtained using only two PI controllers for the fundamental sequence plane, as in conventional vector control of three-phase machines. Based on steady state model, a simple expression is derived to estimate the required dq voltage components of other sequence planes to ensure equal stator phase currents and minimum torque ripple. A five-phase machine is simulated using MATLAB/Simulink to ensure controller validity.     

Inactivation of Foodborne Pathogens by NiO/TiO2 Composite Nanofibers: A Novel Biomaterial System

This study presents the fabrication and characterization of novel NiO/TiO₂ composite nanofibers and their antibacterial activity. The utilized NiO/TiO₂ composite nanofibers were prepared by electrospinning of a sol–gel composed of nickel nitrate hexahydrate, titanium isopropoxide and poly(vinyl acetate). The obtained electrospun nanofiberous mat was vacuum dried at 80 °C and then calcined at 600 °C in air for 2 h. The physicochemical properties of the synthesized nanofibers were determined by X-ray diffraction pattern, field emission scanning electron microscopy, energy-dispersive X-ray spectroscopy, electron probe microanalysis and transmission electron microscopy. The antibacterial activity was tested against four common foodborne pathogenic bacteria viz., Staphylococcus aureus, Escherichia coli, Salmonella typhimurium and Klebsiella pneumoniae by minimum inhibitory concentration (MIC) method taking five different concentrations (5–45 μg/ml). Our investigation reveals that the lowest concentration of NiO/TiO₂ composite solution inhibiting the growth of tested strains was found to be 5 μg/ml. TEM analysis demonstrated that the exposure of the selected microbial strains to the composite nanofibers led to disruption of cell membranes and depressed the activity of some membranous enzymes, which caused bacteria to die eventually. Furthermore, the results illustrate that the combination of NiO and TiO₂ can be synergistic and resulted in superior antimicrobial activity of NiO/TiO₂ composite nanofibers. To sum up, novel NiO/TiO₂ composite nanofibers that possess large surface-to-volume ratio with excellent antimicrobial activity were fabricated that can be used to inhibit the microbial growth associated with food stuff.     

Microstructures and mechanical responses of powder metallurgy non-combustive magnesium extruded alloy by rapid solidification process in mass production

Spinning Water Atomization Process (SWAP), which was one of the rapid solidification processes, promised to produce coarse non-combustible magnesium alloy powder with 1–4 mm length, having fine α-Mg grains and Al₂Ca intermetallic compounds. It had economical and safe benefits in producing coarse Mg alloy powders with very fine microstructures in the mass production process due to its extreme high solidification rate compared to the conventional atomization process. AMX602 (Mg–6%Al–0.5%Mn–2%Ca) powders were compacted at room temperature. Their green compacts with a relative density of about 85% were heated at 573–673 K for 300 s in Ar gas atmosphere, and immediately consolidated by hot extrusion. Microstructure observation and evaluation of mechanical properties of the extruded AMX602 alloys were carried out. The uniform and fine microstructures with grains less than 0.45–0.8 μm via dynamic recrystallization during hot extrusion were observed, and were much small compared to the extruded AMX602 alloy fabricated by using cast ingot. The extremely fine intermetallic compounds 200–500 nm diameter were uniformly distributed in the matrix of powder metallurgy (P/M) extruded alloys. These microstructures caused excellent mechanical properties of the wrought alloys. For example, in the case of AMX602 alloys extruded at 573 K, the tensile strength (TS) of 447 MPa, yield stress (YS) of 425 MPa and 9.6% elongation were obtained.     

Nonlinear transient analysis of reinforced concrete slabs subjected to blast loading and retrofitted with CFRP composites

Computational models using the finite element method for nonlinear transient analysis of reinforced concrete (RC) two-way slabs subjected to blast loading are presented. Both as-built and retrofitted slabs with carbon fiber reinforced polymer (CFRP) composite strips are analyzed. The models are used to investigate different parameters including (a) loading duration, and (b) effect of CFRP retrofit on damage accumulation. In this study, damage is globally quantified by the amount of reduction of the first two vibrational frequencies of the slabs. Local representation of damage in terms of reinforcing steel strains is also discussed. The computational models for both the as-built and the retrofitted slabs are verified using experimental results. In these experiments, a slowly increasing uniform pressure is applied to the bottom surface of large-scale RC slab specimens using high-pressure water bag. Experimental results showed that an increase up to 200% in the load carrying capacity is achieved when using the CFRP composite retrofit system. Transient nonlinear analysis results proved the efficiency of the CFRP composite retrofit in improving the slab behavior under blast loading for different loading durations, i.e. for small, medium, and large charge weights at the same applied maximum pressure. In particular, less than 50% reduction of the fundamental frequency due to concrete damage is obtained for the retrofitted slab compared to more than 85% reduction for the as-built slab. Moreover, the maximum displacement is reduced by 40–70% with the CFRP retrofit compared to the as-built slab. As for reinforcing steel strains, the application of CFRP retrofit significantly limited the spread of yielding in time and space. The improved slab behavior with CFRP is best when retrofitting is applied to both sides of the slab.     

FAK Shutdown: Consequences on Epithelial Morphogenesis and Biomarker Expression Involving an Innovative Biomaterial for Tissue Regeneration

By employing an innovative biohybrid membrane, the present study aimed at elucidating the mechanistic role of the focal adhesion kinase (FAK) in epithelial morphogenesis in vitro over 4, 7, and 10 days. The consequences of siRNA-mediated FAK knockdown on epithelial morphogenesis were monitored by quantifying cell layers and detecting the expression of biomarkers of epithelial differentiation and homeostasis. Histologic examination of FAK-depleted samples showed a significant increase in cell layers resembling epithelial hyperplasia. Semiquantitative fluorescence imaging (SQFI) revealed tissue homeostatic disturbances by significantly increased involucrin expression over time, persistence of yes-associated protein (YAP) and an increase of keratin (K) 1 at day 4. The dysbalanced involucrin pattern was underscored by ROCK-II^Ser1366 activity at day 7 and 10. SQFI data were confirmed by quantitative PCR and Western blot analysis, thereby corroborating the FAK shutdown-related expression changes. The artificial FAK shutdown was also associated with a significantly higher expression of filaggrin at day 10, sustained keratinocyte proliferation, and the dysregulated expression of K19 and vimentin. These siRNA-induced consequences indicate the mechanistic role of FAK in epithelial morphogenesis by simultaneously considering prospective biomaterial-based epithelial regenerative approaches.