State-of-the-art technology: Recent investigations on laser-mediated synthesis of nanocomposites for environmental remediation

In both developing and industrialized/developed countries, various hazardous/toxic environmental pollutants are entering water bodies from organic and inorganic compounds (heavy metals and specifically dyes). The global population is growing whereas the accessibility of clean, potable and safe drinking water is decreasing, leading to world deterioration in human health and limitation of agricultural and/or economic development. Treatment of water/wastewater (mainly industrial water) via catalytic reduction/degradation of environmental pollutants is extremely critical and is a major concern/issue for public health. Light and/or laser ablation induced photocatalytic processes have attracted much attention during recent years for water treatment due to their good (photo)catalytic efficiencies in the reduction/degradation of organic/inorganic pollutants. Pulsed laser ablation (PLA) is a rather novel catalyst fabrication approach for the generation of nanostructures with special morphologies (nanoparticles (NPs), nanocrystals, nanocomposites, nanowires, etc.) and different compositions (metals, alloys, oxides, core-shell, etc.). Laser ablation in liquid (LAL) is generally considered a quickly growing approach for the synthesis and modification of nanomaterials for practical applications in diverse fields. LAL-synthesized nanomaterials have been identified as attractive nanocatalysts or valuable photocatalysts in (photo)catalytic reduction/degradation reactions. In this review, the laser ablation/irradiation strategies based on LAL are systematically described and the applications of LAL synthesized metal/metal oxide nanocatalysts with highly controlled nanostructures in the degradation/reduction of organic/inorganic water pollutants are highlighted along with their degradation/reduction mechanisms.     

Wear Resistance of Amorphous-Crystalline Coatings with Lubricants

The results of tests of a Zr–Al–B boundary friction detonation coating in a wide range of changes under friction conditions have been presented. A comparative analysis of the obtained characteristics of friction and wear in order to evaluate the tribotechnical properties of amorphous-crystalline coatings has been carried out. These results have been compared with parallel tests of coatings based on tungsten carbide, samples of hardened steel and bronze, and the bearing of the sliding layer. The formation of solid solutions has been established and the introduction of oxygen in zirconium that corresponds to the formation on the friction surfaces of the secondary structures of the first type, a characteristic feature of which is their surface localization, ultra-dispersed structure, and ability to minimize disruption and shield unacceptable adhesion phenomena. The use of the Auger electron microscope confirmed that oxygen completely replaces the sulfur in the surface structures.     

Structural Regeneration of Coatings in Friction

Materials Science - We propose a mechanism for increasing the durability of friction surfaces in the presence of in-service defects caused by the intrastructural regeneration. It is shown that, in...     

Optimization of Steam Reforming of Methane in a Hydrogen-Filtering Membrane Module with a Nickel Catalyst and a Palladium-Alloy Foil

Theoretical Foundations of Chemical Engineering - A model is proposed for steam reforming of methane in a catalytic reactor, the working section of which includes two cylindrical chambers separated...     

A note on multivariate non-normal process capability analysis using “mvtnorm” library in R

In this note we examine using Genzbretz and Miwa algorithms to improve estimation of proposition of non-conformance in multivariate normal distributions. This estimation is required in the procedure outlined in Abbasi and Niaki (Int J Adv Manuf Technol 50(5–8):823–830, 2010) to determine process capability index of multivariate non-normal processes.     

Joint routing and channel assignment using online learning in cognitive radio networks

Cognitive radio networks (CRNs) are the solution for the problem of underutilizing the licensed spectrum for which there are more requests in the last couple of decades. In CRNs, Secondary users (SUs) are permitted to access opportunistically the licensed spectrum owned by primary users (PUs). In this paper, we address the problem of joint routing and channel assignment for several flows generated by source SUs to a given destination. We consider a more realistic model based on Markov modulated Poisson process for modeling the PUs traffic at each channel and the SUs try to exploit short lived spectrum holes between the PUs packets at the selected channel. The SUs want to cooperatively minimize the end-to-end delay of source SUs flows meanwhile the quality of service requirements of the PUs would be met. To consider partial observation of SUs about PUs activity at all channels and quick adaptation of SUs decisions to environment changes and cooperative interaction of SUs, we use decentralized partially observable markov decision process for modeling the problem. Then, an online learning based scheme is proposed for solving the problem. Simulation results show that the performance of the proposed method and the optimal method is close to each other. Also, simulation results show that the proposed method greatly outperforms related works at control of interference to the PUs while maintains the end-to-end delay of SU flows in a low level.