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排序方式: 共有648条查询结果,搜索用时 31 毫秒
61.
Modulation of stability properties of bovine trypsin after in vitro structural changes with a variety of chemical modifiers 总被引:4,自引:0,他引:4
Controlled chemical modification of enzymes, targeting groups not involved
in the active site, can lead to modified catalysts that are intrinsically
more efficient and resistant to heat and denaturing agents. Bovine
pancreatic trypsin was covalently modified up to 75-85% with monomeric
glutaraldehyde (MGA), polymeric glutaraldehyde (PGA), oxidized sucrose and
oxidized sucrose polymers (OSP 70 and OSP 400). Virtually no loss in
activity occurred upon modification. Temperature optima of trypsin shifts
from 45-76 degrees C and T50 from 54-76 degrees C for the best modified
sample made with OSP. The efficiency of the modifiers in stabilization was
ranked in the order: OSP 400-T > OSP 70-T > PGA-T > MGA-T >
Sucrose-T. Half-life of modified enzymes also followed the same trend. Both
stabilization factor and t1/2 decreased with increasing temperatures. The
free energy of activation for inactivation delta(deltaG*) varies from 12-20
kJ/mol and the activation enthalpy delta(deltaH*) of the modified trypsin
by 80-120 kJ/mol indicating stabilization. Inactivation of modified trypsin
by urea is less noticeable. The character of the two-step inactivation
process of trypsin changes with the degree of stabilization in that the
duration of phase I one increased noticeably as stabilization increases.
Native trypsin fluoresces less intensely showing a red shift under the
influence of denaturation. Such a fluorescence change is not so obvious for
the modified enzymes indicating conformational stability acquired by
modification.
相似文献
62.
John S. McCloy Jarrod V. Crum S. K. Sundaram Ryan Slaugh Paul P. Woskov 《Journal of Infrared, Millimeter and Terahertz Waves》2011,32(11):1337-1349
Millimeter wave (MMW) radiometry can be used for simultaneous measurement of emissivity and temperature of materials under
extreme environments such as in slagging coal gasifiers, where sensors have been identified as a key enabling technology need
for process optimization. We present a dual-channel MMW heterodyne radiometer with active interferometric capability that
allows simultaneous measurements of sample temperature, emissivity, and flow dynamics. Interferometric capability at 137 GHz
is supplied via a probe signal originating from a local oscillator allowing monitoring of sample dynamics such as volume expansion
and thickness change. This capability has been used to monitor characteristic behavior between refractories and slag such
as slag infiltration, slag melting, viscous flow, foaming, and crucible corrosion by the molten slag. These results show the
promise of the MMW system for extracting process parameters from operating slagging coal gasifiers, providing valuable information
for process efficiency, control, and increased productivity. 相似文献
63.
P. Bhama Iyer S. Sreenivasan P. K. Chidambareswaran N. B. Patil V. Sundaram 《应用聚合物科学杂志》1991,42(6):1751-1757
In the present investigation, we have made a systematic study of the induced crystallization in never-dried cotton fiber, by allowing it to desiccate under different conditions of humidity and temperature. The resulting structural changes have been followed using x-ray diffraction and infrared absorption techniques. A slow rate of drying coupled with a high temperature was more conducive for maximum crystallization. Analysis of the effect of temperature on the induced crystallization showed possible existence of a thermal transition in cellulose around 30°C. The induced crystallization brought about by slow drying as well as those produced using intercrystalline swelling agents, have been shown to be resulting from a proper channelization of the interfibrillar mobility existing in the never-dried fibers. 相似文献
64.
K. B. Sundaram S. S. Seshan V. H. Desai S. M. Arora 《Journal of Materials Science: Materials in Electronics》1992,3(1):26-28
HighT
c superconductor materials of yttrium barium copper oxide (YBCO) have been etched by a new electrochemical technique. In this technique, acids like hydrochloric, nitric and phosphoric have been used as an electrolyte and etching has been achieved with acid dilutions as high as 1:200 with water. It is observed that rapid and controlled etching is possible by this technique. 相似文献
65.
In this study influence of compaction pressure, sintering temperature, and sintering time on mechanical and wear behavior of the fly ash reinforced copper-based composites are analyzed. The composites were prepared by powder metallurgy (P/M) technique with copper as matrix, 5 and 10 wt% of fly ash as reinforcement. The green compacts were prepared at three different pressures such as 350, 400, and 450 MPa. The prepared green composites were sintered at 700, 800, and 900 °C for the time period of 30, 60, and 90 min, respectively. From the results it is observed that when the process parameter increases the density, hardness, compression strength, and wear resistance increases. 相似文献
66.
Tulyaganov DU Agathopoulos S Valerio P Balamurugan A Saranti A Karakassides MA Ferreira JM 《Journal of materials science. Materials in medicine》2011,22(2):217-227
New compositions of bioactive glasses are proposed in the CaO–MgO–SiO2–Na2O–P2O5–CaF2 system. Mineralization tests with immersion of the investigated glasses in simulated body fluid (SBF) at 37°C showed that
the glasses favour the surface formation of hydroxyapatite (HA) from the early stages of the experiments. In the case of daily
renewable SBF, monetite (CaHPO4) formation competed with the formation of HA. The influence of structural features of the glasses on their mineralization
(bioactivity) performance is discussed. Preliminary in vitro experiments with osteoblasts’ cell-cultures showed that the glasses
are biocompatible and there is no evidence of toxicity. Sintering and devitrification studies of glass powder compacts were
also performed. Glass-ceramics with attractive properties were obtained after heat treatment of the glasses at relatively
low temperatures (up to 850°C). 相似文献
67.
S. Theodore Chandr N. B. Balamurugan G. Subalakshmi T. Shalini G. Lakshmi Priya 《半导体学报》2014,35(11):114003-5
We have developed a 2D analytical model for the single gate Al In Sb/In Sb HEMT device by solving the Poisson equation using the parabolic approximation method.The developed model analyses the device performance by calculating the parameters such as surface potential,electric field distribution and drain current.The high mobility of the Al In Sb/In Sb quantum makes this HEMT ideal for high frequency,high power applications.The working of the single gate Al In Sb/In Sb HEMT device is studied by considering the variation of gate source voltage,drain source voltage,and channel length under the gate region and temperature.The carrier transport efficiency is improved by uniform electric field along the channel and the peak values near the source and drain regions.The results from the analytical model are compared with that of numerical simulations(TCAD) and a good agreement between them is achieved. 相似文献
68.
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