位相调制三倍频激光束聚焦特性的衍射模型

基于三次谐波转换过程中位相扰动的传输变换 ,理论上研究了非线性晶体表面周期性纹波对三倍频激光束聚焦特性的影响 ,建立了多级衍射模型。该理论模型能解析地分析多级衍射峰的强度分布及角度分布 ,可为高功率激光驱动器三倍频器的设计提供理论依据     

三元混晶膜的表面声子极化激元

采用改进的无规元素孤立位移模型和波恩-黄近似,运用电磁场的麦克斯韦方程和边界条件,研究极性三元混晶膜中的表面声子极化激元.以AlxGa1-xAs,ZnxCd1-xS 和GaxIn1-xN 膜为例,获得了其中表面声子极化激元的频率作为波矢和膜厚之函数的数值结果并进行了讨论.结果表明:在三元混晶膜中有四支表面声子极化激元,不同材料的色散曲线分别显示了混晶电磁声子模的"双模"和"单模"特征.     

Advance in Using Plasma Technology for Modification or Fabrication of Carbon-Based Materials and Their Applications in Environmental,Material, and Energy Fields

Plasma technology is an eco-friendly way to modify or fabricate carbon-based materials (CBMs) due to plasmas’ distinctive abilities in tuning the surface physicochemical properties by implanting functional groups or incorporating heteroatoms into the surface without changing the bulk structure. However, the mechanisms of functional groups formation on the carbon surface are still not clearly explained because of the variety of different discharge conditions and the complexity of plasma chemistry. Consequently, this paper contains a comprehensive review of plasma-treated carbon-based materials and their applications in environmental, materials, and energy fields. Plasma-treated CBMs used in these fields have been significantly enhanced in recent years because these related materials possess unique features after plasma treatment, such as higher adsorption capacity, enhanced wettability, improved electrocatalytic activity, etc. Meanwhile, this paper also summarizes possible reaction routes for the generation of functional groups on CBMs. The outlook for future research is summarized, with suggestions that plasma technology research and development shall attempt to achieve precise control of plasmas to synthesize or to modify CBMs at the atomic level.     

Reconstructed Water Oxidation Electrocatalysts: The Impact of Surface Dynamics on Intrinsic Activities

Electroreduction of small molecules such as H₂O, CO₂, and N₂ for producing clean fuels or valuable chemicals provides a sustainable approach to meet the increasing global energy demands and to alleviate the concern on climate change resulting from fossil fuel consumption. On the path to implement this purpose, however, several scientific hurdles remain, one of which is the low energy efficiency due to the sluggish kinetics of the paired oxygen evolution reaction (OER). In response, it is highly desirable to synthesize high-performance and cost-effective OER electrocatalysts. Recent advances have witnessed surface reconstruction engineering as a salient tool to significantly improve the catalytic performance of OER electrocatalysts. In this review, recent progress on the reconstructed OER electrocatalysts and future opportunities are discussed. A brief introduction of the fundamentals of OER and the experimental approaches for generating and characterizing the reconstructed active sites in OER nanocatalysts are given first, followed by an expanded discussion of recent advances on the reconstructed OER electrocatalysts with improved activities, with a particular emphasis on understanding the correlation between surface dynamics and activities. Finally, a prospect for clean future energy communities harnessing surface reconstruction-promoted electrochemical water oxidation will be provided.     

Toward Flexible Embodied Energy: Scale-Inspired Overlapping Lithium-Ion Batteries with High-Energy-Density and Variable Stiffness

High performance flexible batteries are essential ingredients for flexible devices. However, general isolated flexible batteries face critical challenges in developing multifunctional embodied energy systems, owing to the lack of integrative design. Herein, inspired by scales in creatures, overlapping flexible lithium-ion batteries (FLIBs) consisting of energy storage scales and connections using LiNi_0.5Co_0.2Mn_0.3O₂ (NCM523) and graphite electrodes are presented. The scale-dermis structure ensures a high energy density of 374.4 Wh L⁻¹ as well as a high capacity retention of 93.2% after 200 charge/discharge cycles and 40 000 bending times. A variable stiffness property is revealed that can be controlled by battery configurations and deformation modes. Furthermore, the overlapping FLIBs can be housed directly into the architecture of several flexible devices, such as robots and grippers, allowing to create multifunctionalities that go far beyond energy storage and include load-bearing and variable flexibility. This study broadens the versatility of FLIBs toward energy storage structure engineering of flexible devices.     

Intrinsically Flexible and Aging Resistant Fluorene-Based Rod-Coil Copolymer for Bendable Deep-Blue PLEDs

In the field of flexible light-emitting display, goal-oriented intelligent molecular design is used to control various behaviors of molecules, which provides potential for the development of flexible light-emitting conjugated polymers (LCPs). The introduction of non-conjugated units into polymer molecules is a key prerequisite for realizing the intrinsic flexibility, but its easy interchain slip will also lead to the formation of interchain excited states, which is detrimental to the efficiency of light-emitting diodes. Herein, two kinds of fluorene-based rod-coil copolymer with stable deep blue emission characteristics is presented and with Commission Internationale de L'Eclairage (CIE) coordinates of (0.18, 0.14) and (0.15, 0.09), respectively. Surprisingly, the copolymer films show efficient blue emission even at 100% tension. Meanwhile, the rod-coil copolymer possesses better aging resistance compared to rigid π-conjugated counterparts. Finally, both rigid and flexible light-emitting diodes based on rod-coil copolymer exhibit stable deep blue emission, and the G2-based PLED with CIE coordinates of (0.16, 0.08), which approach National Television System Committee standard blue specification. These results confirm the validity of rod-coil copolymer design strategy in constructing inherently flexible polymers with deep blue emission, which have great application potential in flexible PLEDs.     

0.18μm CMOS工艺条件下的信号完整性分析

通过模拟分析了0 18μmCMOS工艺条件下的信号完整性问题.在进行串扰延迟和噪声分析中发现了一些规律,这些规律对以后的设计有一定的指导意义.     

基于安全即服务的网络安全智慧中台技术研究

在新兴互联网时代的推动下,云、大、物、移、智等相关技术在信息变革中起到关键作用。随着中台建设热浪翻涌、云计算落地疯狂扩张、安全自动化运维兴起及5G新技术试点应用,各类业务发展无不要求安全ISP能够快速应对多应用、多场景、多用户下的安全建设需求。单项或者多项安全能力的简单叠加已逐步被数字化市场所摈弃,安全逐步演变为一种可协同联动、相互供给、弹性伸缩、自由组合的数字化生态模式。在新技术、新应用、新需求驱动下,安全如何实现立体空间数字化建设,满足按需增长的动态安全需求,已成为当下研究的热点。     

乙炔气体浓度的TDLAS在线监测

介绍了利用可调谐半导体激光吸收光谱（TDLAS）技术实现乙炔浓度在线监测的研究。该系统通过复合调制信号调制近红外分布反馈式二极管激光器（DFB LD）作为光源,光纤耦合器将激光分为两束,分别通过0.5 m封闭短光程气体吸收池和参考光路,双路接收采集含有气体浓度信息的测量光信号和参考光信号送后级处理,应用快速傅里叶变换（FFT）得到含有气体浓度信号的各次谐波检测分量,实现乙炔浓度信息反演,其中多次平均、数字滤波及背景扣除等数字信号处理技术被用于提高系统信噪比。通过理论分析和试验系统实验证明,该系统在软、硬件上的设计可以满足乙炔气体的在线监测,且系统体积小,光路调试和标定简单,便于实际应用。     

A novel adaptive anti-interference algorithm based on negative diagonal loading for spoofing and jamming in Global Navigation Satellite System

Spoofing and jamming are two kinds of significant interferences in Global Navigation Satellite System (GNSS). When they coexist in GNSS propagation environment, interference suppression becomes more difficult. Conventional power inversion (PI) algorithm can reject jamming effectively, but has different influences on repeat spoofing when the different numbers of elements are used in an antenna array. Nevertheless, repeat spoofing still has the capability of deception after being processed by the PI algorithm. In the paper, different influences have been analyzed and a blind adaptive anti-interference algorithm is proposed based on negative diagonal loading technique. The proposed method can adaptively reject spoofing and jamming simultaneously without estimating the direction-of-arrivals (DOAs) of them, and ensure that authentic satellite signal can be acquired by the GNSS receiver without other treatment of repeat spoofing. Simulation results show the effectiveness of the new method.